MMT/PLA/PBAT复合材料的制备与性能研究

徐淑伟, 陈玉, 杨科, 卢伟东, 洪有针, 吴强

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塑料科技 ›› 2025, Vol. 53 ›› Issue (03) : 82-87. DOI: 10.15925/j.cnki.issn1005-3360.2025.03.015
生物与降解材料

MMT/PLA/PBAT复合材料的制备与性能研究

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Preparation and Properties Study of MMT/PLA/PBAT Composites

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摘要

采用转矩流变仪制备纳米蒙脱土/聚乳酸/聚己二酸-对苯二甲酸丁二醇酯(MMT/PLA/PBAT)复合材料,考察MMT含量对PLA/PBAT复合材料力学性能、薄膜水蒸气阻隔性能、结晶行为、流变行为及断面微观结构的影响。结果表明:MMT的加入提升了PLA/PBAT材料的弹性模量,强度和断裂伸长率略有下降,但显著提升了PLA/PBAT薄膜的水蒸气阻隔性能。当MMT质量分数为8%时,水蒸气透过率降低了43.7%。热力学研究表明,MMT的加入提高了PBAT的结晶温度和结晶度,表明MMT在PBAT中起到成核剂的作用。流变行为研究表明,MMT在PLA/PBAT基体中形成网络结构,提升熔体强度。研究结果可为开发具有高水蒸气阻隔的PLA/PBAT薄膜提供参考。

Abstract

Nano-montmorillonite/polylactic acid/polybutylene adipate terephthalate(MMT/PLA/PBAT) composites were prepared by torque rheometer. The influence of MMT content on the mechanical properties, water vapor barrier properties, crystallization behavior, and rheological behavior of PLA/PBAT composites were investigated. The results showed that the incorporation of MMT enhanced the elastic modulus of PLA/PBAT materials, with a slight decrease in tensile strength and elongation at break. The addition of MMT significantly improved the water vapor barrier performance of PLA/PBAT films, the water vapor transmittance decreased by 43.7% when the MMT mass fraction was 8%. Thermodynamic studies demonstrated that the incorporation of MMT elevated the crystallisation temperature and crystallinity of PBAT, thereby indicating that MMT acted as a nucleating agent for PBAT. Rheological behavior studies showed that MMT formed a network in PLA/PBAT matrix which can improve the melt strength. The study provided references for the development of high-performance PLA/PBAT films with enhanced water vapor barrier properties.

关键词

聚己二酸-对苯二甲酸丁二醇酯 / 聚乳酸 / 纳米蒙脱土 / 水蒸气阻隔性 / 流变行为

Key words

Polybutylene adipate terephthalate / Polylactic acid / Nano-montmorillonite / Water vapor barrier / Rheological behavior

中图分类号

TB332

引用本文

导出引用
徐淑伟 , 陈玉 , 杨科 , . MMT/PLA/PBAT复合材料的制备与性能研究. 塑料科技. 2025, 53(03): 82-87 https://doi.org/10.15925/j.cnki.issn1005-3360.2025.03.015
XU Shuwei, CHEN Yu, YANG Ke, et al. Preparation and Properties Study of MMT/PLA/PBAT Composites[J]. Plastics Science and Technology. 2025, 53(03): 82-87 https://doi.org/10.15925/j.cnki.issn1005-3360.2025.03.015

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基金

2024年度临安区-浙江农林大学区校合作项目

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