玄武岩纤维增强环氧树脂复合材料性能研究

张奇, 于人同

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塑料科技 ›› 2025, Vol. 53 ›› Issue (02) : 64-70. DOI: 10.15925/j.cnki.issn1005-3360.2025.02.012
加工与应用

玄武岩纤维增强环氧树脂复合材料性能研究

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Properties Study of Basalt Fiber Reinforced Epoxy Resin Composites

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摘要

为提升玄武岩纤维增强环氧树脂复合材料的性能,以聚多巴胺(PDA)为活性位点,将聚苯胺(PANI)修饰于玄武岩纤维(BF)表面,并与环氧树脂(EP)复合,制备BF-PDA-PANI/EP复合材料。结果显示:在不同种类及浓度的无机酸条件下,利用扫描电子显微镜(SEM)观察PANI在BF-PDA表面的包覆情况,发现0.2 mol/L HCl条件下包覆效果最佳,同时通过傅里叶变换红外光谱仪(FTIR)和X射线光电子能谱分析仪(XPS)进一步验证了PANI在BF表面的包覆。在0.2 mol/L HNO3条件下合成的BF-PDA-PANI/EP复合材料的拉伸强度和弯曲强度分别为7.24 MPa和23.48 MPa;在0.2 mol/L HCl条件下合成的BF-PDA-PANI/EP复合材料的悬臂梁冲击强度为27.55 MPa。与BF/EP复合材料相比,BF-PDA-PANI/EP复合材料的力学性能得到显著提升。

Abstract

To enhance the properties of basalt fiber reinforced epoxy resin composites, polyaniline (PANI) was modified on the surface of basalt fiber (BF) using polydopamine (PDA) as the active site, and then combined with epoxy resin (EP) to prepare BF-PDA-PANI/EP composites. The results show that under different types and concentrations of inorganic acid conditions, the coating of PANI on the surface of BF-PDA was observed using scanning electron microscopy (SEM), and the best coating effect was found under 0.2 mol/L HCl condition. Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) were further used to verify the coating of PANI on the surface of BF. The tensile strength and flexural strength of BF-PDA-PANI/EP composites synthesized under 0.2 mol/L HNO3 condition were 7.24 MPa and 23.48 MPa, respectively; while the cantilever beam impact strength of BF-PDA-PANI/EP composites synthesized under 0.2 mol/L HCl condition was 27.55 MPa. Compared with BF/EP composites, the mechanical properties of BF-PDA-PANI/EP composites were significantly improved.

关键词

玄武岩纤维 / 环氧树脂 / 力学性能 / 聚苯胺

Key words

Basalt fiber / Epoxy resin / Mechanical properties / Polyaniline

中图分类号

TB332 / TQ323.5

引用本文

导出引用
张奇 , 于人同. 玄武岩纤维增强环氧树脂复合材料性能研究. 塑料科技. 2025, 53(02): 64-70 https://doi.org/10.15925/j.cnki.issn1005-3360.2025.02.012
ZHANG Qi, YU Rentong. Properties Study of Basalt Fiber Reinforced Epoxy Resin Composites[J]. Plastics Science and Technology. 2025, 53(02): 64-70 https://doi.org/10.15925/j.cnki.issn1005-3360.2025.02.012

参考文献

1
LOPRESTO V, LEONE C, DE IORIO I. Mechanical characterisation of basalt fibre reinforced plastic[J]. Composites Part B: Engineering, 2011, 42(4): 717-723.
2
VINAY S S, SANJAY M R, SIENGCHIN S, et al. Basalt fiber reinforced polymer composites filled with nano fillers: A short review[J]. Materials Today: Proceedings, 2021, 52: 2460-2466.
3
MANIKANDAN V, WINOWLIN JAPPES J T, SURESH KUMAR S M, et al. Investigation of the effect of surface modifications on the mechanical properties of basalt fibre reinforced polymer composites[J]. Composites Part B: Engineering, 2012, 43(2): 812-818.
4
VIRK A, HALL W, SUMMERSCALES J. Modulus and strength prediction for natural fibre composites[J]. Materials Science and Technology, 2013, 28(7): 864-871.
5
SARASINI F, TIRILLÒ J, VALENTE M, et al. Effect of basalt fiber hybridization on the impact behavior under low impact velocity of glass/basalt woven fabric/epoxy resin composites[J]. Composites Part A: Applied Science and Manufacturing, 2013, 47(1): 109-123.
6
CHOWDHURY I R, O'DOWD N P, COMER A J. Failure prediction in a non-crimp basalt fibre reinforced epoxy composite[J]. Composite Structures, 2023, 322: 117413.
7
SHI C C, JIN S J, JIN B, et al. Enhancing bonding behavior between basalt fiber-reinforced polymer sheets and concrete using resin pre-coating method and multi-wall carbon nanotubes[J]. Journal of Building Engineering, 2024, 84: 108695.
8
AHMED T, BEDIWY A, AZZAM A, et al. Utilization of novel basalt fiber pellets from micro- to macro-scale, and from basic to applied fields: A review on recent contributions[J]. Fibers, 2024, 12(2): 17.
9
KUANG C, RAO M M, ZOU X B, et al. Synergetic analysis between polyvinyl chloride (PVC) and coal in chemical looping combustion (CLC)[J]. Applications in Energy and Combustion Science, 2023, 14: 100121.
10
FIORE V, SCALICI T, DI BELLA G, et al. A review on basalt fibre and its composites[J]. Composites Part B: Engineering, 2015, 74: 74-94.
11
PLAPPERT D, GANZENMÜLLER G C, MAY M, et al. Mechanical properties of a unidirectional basalt-fiber/epoxy composite[J]. Journal of Composites Science, 2020, 4(3): 101.
12
MIRZAMOHAMMADI S, ESLAMI-FARSANI R, EBRAHIMNEZHAD-KHALJIRI H. The characterization of the flexural and shear performances of laminated aluminum/jute-basalt fibers epoxy composites containing carbon nanotubes: As multi-scale hybrid structures[J]. Thin-Walled Structures, 2022, 179: 109690.
13
LI R, GU Y Z, YANG Z J, et al. Effect of γ irradiation on the properties of basalt fiber reinforced epoxy resin matrix composite[J]. Journal of Nuclear Materials, 2015, 466: 100-107.
14
ZHU H B, WEN S Y, LI X, et al. Damage evolution of polypropylene-basalt hybrid fiber ceramsite concrete under chloride erosion and dry-wet cycle[J]. Polymers, 2023, 15(20): 4179.
15
LI B, LIU M H, KANG A H, et al. Effect of basalt fiber diameter on the properties of asphalt mastic and asphalt mixture[J]. Materials, 2023, 16(20): 6711.
16
PREDA N, COSTAS A, LILLI M, et al. Functionalization of basalt fibers with ZnO nanostructures by electroless deposition for improving the interfacial adhesion of basalt fibers/epoxy resin composites[J]. Composites Part A: Applied Science and Manufacturing, 2021, 149: 1-7.
17
ZHANG S C, ZHONG T H Y, XU Q B, et al. The effects of chemical grafting 1,6-hexanediol diglycidyl ether on the interfacial adhesion between continuous basalt fibers and epoxy resin as well as the tensile strength of composites[J]. Construction and Building Materials, 2022, 323: 126563.
18
YANG L, PHUA S L, TEO J K H, et al. A biomimetic approach to enhancing interfacial interactions: Polydopamine-coated clay as reinforcement for epoxy resin[J]. ACS Applied Materials and Interfaces, 2011, 3(8): 3026-3032.
19
YANG W M, WU S Y, YANG W, et al. Nanoparticles of polydopamine for improving mechanical and flame-retardant properties of an epoxy resin[J]. Composites Part B: Engineering, 2020, 186: 107828.
20
WAN X Y, XIA X J, CHEN Y X, et al. Bioinspired thermal conductive cellulose nanofibers/boron nitride coating enabled by co-exfoliation and interfacial engineering[J]. Polymers (Basel), 2024, 16(6): 805.
21
LEO DE V, MARRAS E, MAURELLI A M, et al. Polydopamine-coated liposomes for methylene blue delivery in anticancer photodynamic therapy: Effects in 2D and 3D Cellular Models[J]. International Journal of Molecular Sciences, 2024, 25(6): 3392.
22
LU Y, LIU X L, ZHAO T, et al. Synthesis of taxifolin-loaded polydopamine for chemo-photothermal-synergistic therapy of ovarian cancer[J]. Molecules, 2024, 29(5): 1-14.
23
ALSAAD A M, AL-HMOUD M, RABABAH T M, et al. Synthesized PANI/CeO2 nanocomposite films for enhanced anti-corrosion performance[J]. Nanomaterials (Basel), 2024, 14(6): 526.
24
LIN H T, CHUANG E, LIN S C. Advancing lithium battery performance through porous conductive polyaniline-modified graphene composites additive[J]. Nanomaterials, 2024, 14(6): 509.
25
YUAN J H, HU X F, ZHAO X P, et al. Electrorheological effect of suspensions of polyaniline nanoparticles with different morphologies[J]. Polymers, 2023, 15(23): 4568.
26
ATIR S, ALI S H, NIMRA S S, et al. Achieving enhanced EMI shielding with novel non-woven fabric using nylon fiber coated with polyaniline via in situ polymerization[J]. Synthetic Metals, 2023, 293: 117250.
27
ELANTHAMILAN E, GANESHKUMAR A, WANG S F, et al. Fabrication of polydopamine/polyaniline decorated multiwalled carbon nanotube composite as multifunctional electrode material for supercapacitor applications[J]. Synthetic Metals, 2023, 298: 117423.
28
LI X J, LI L, ZHANG W Q, et al. Grafting of polyaniline onto polydopamine-wrapped carbon nanotubes to enhance corrosion protection properties of epoxy coating[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2023, 670: 131548.

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