
轻量化PP/MCHGB/POE复合材料的制备与性能研究
李依鹏, 董庭轩, 李快, 张栋, 郭生伟, 李丹, 王固霞
轻量化PP/MCHGB/POE复合材料的制备与性能研究
Preparation and Performance Research of Lightweight PP/MCHGB/POE Composites
文章采用多种硅烷偶联剂对空心玻璃微珠(HGB)进行改性,改善HGB与聚丙烯(PP)的界面相容性,并探究了改性HGB的最大添加量,同时引入低密度聚烯烃弹性体(POE)对PP进行增韧。结果表明:经过偶联剂改性后的HGB与PP相容性好,且提升了复合材料的热稳定性,其中以乙烯基三甲氧基硅烷(A-171)改性效果最佳。与未改性的PP/HGB复合材料相比,PP/A-171-HGB的拉伸强度和弯曲强度分别提升了4.02 MPa和9.28 MPa,密度下降至0.902 g/cm3。当添加10%的改性HGB和15%的POE时,可保证复合材料刚性和韧性的平衡,相比未改性的PP/HGB复合材料,其断裂伸长率提升了73.4%,且密度可降至0.864 g/cm3。
A variety of silane coupling agents were used to modify hollow glass beads (HGB) to improve the interface compatibility between HGB and polypropylene (PP), and the maximum addition amount of modified HGB was explored. At the same time, low density polyolefin elastomer (POE) was introduced to toughen PP. The results show that the HGB modified by coupling agents has good compatibility with PP and improves the thermal stability of the composites, among which vinyl trimethoxysilane (A-171) has the best modification effect. Compared with the unmodified PP/HGB composites, the tensile strength and bending strength of PP/A-171-HGB are increased by 4.02 MPa and 9.28 MPa, respectively, and the density decreases to 0.902 g/cm3. When 10% modified HGB and 15% POE are added, the balance of rigidity and toughness of the composite can be ensured. Compared with the unmodified PP/HGB composites, the elongation at break of the composite is increased by 73.4%, and the density decreases to 0.864 g/cm3.
Lightweight / Polypropylene / Hollow glass beads / POE
TB332
1 |
|
2 |
|
3 |
张垚,张世双,姜曙,等.利用发动机余热驱动的汽车制冷空调系统[J].节能,2022,41(9):30-32.
|
4 |
|
5 |
|
6 |
|
7 |
赵体鹏,莫荣强,万虎.空心玻璃微珠改性低密度PA6材料研究[J].广东化工,2021,48(20):91-93, 90.
|
8 |
|
9 |
|
10 |
穆洪帅,宋大龙,肖同亮,等.硅烷偶联剂对炭黑补强IR性能的影响[J].特种橡胶制品,2022,43(6):23-26, 43.
|
11 |
黄虹,李道喜,明浩,等.空心玻璃微珠对碳纤维增强聚丙烯性能的影响研究[J].工程塑料应用,2012,40(4):80-83.
|
12 |
孙佳丽,杨琴,邱小魁,等.硅烷偶联剂在玻纤复合材料中的应用及发展[J].有机硅材料,2022,36(4):55-59.
|
13 |
王海燕,党智敏,武晋萍,等.KH550硅烷偶联剂对复合材料结构和介电性能影响[J].功能材料,2006(7):1091-1093, 1097.
|
14 |
吉祥波,鲜晓斌,唐贤臣,等.硅烷偶联剂KH550对Parylene C膜与金属铝基体结合强度的影响[J].高分子材料科学与工程,2012,28(3):57-59.
|
15 |
傅强,钱之杨,赵梅.硅烷偶联剂KH-550的GC/MS研究[J].现代科学仪器,2000(2):13-14.
|
16 |
彭丽芬,柳雷,陈伟,等.空心玻璃微珠表面改性对环氧树脂复合材料性能影响研究[J].化学工程与装备,2020(2):41-43.
|
17 |
|
18 |
王浩博,李传强.玻璃表面功能化改性技术的现状与发展[J].中国材料进展,2022,41(8):635-644.
|
19 |
王宁,汪光辉,柳雷,等.空心玻璃微珠表面改性及其应用研究进展[J].当代化工,2023,52(6):1436-1441.
|
20 |
刘浩,聂晨晨,谢贵明,等.聚合物从表面接枝改性无机粒子的进展[J].塑料,2022,51(3):66-72.
|
21 |
|
22 |
|
23 |
高翔.空心玻璃微珠对膨胀阻燃聚丙烯材料的阻燃协效研究[J].塑料科技,2021,49(9):43-46.
|
24 |
|
25 |
|
26 |
岳振,郑明东,毛立睿,等.PP/气化飞灰复合材料力学性能研究[J].塑料科技,2022,50(6):23-27.
|
27 |
周颖,王蒙,何玮由,等.动态硫化三元乙丙橡胶/聚丙烯橡胶:流变,结晶和动态力学性能[J].高分子材料科学与工程,2020,36(2):32-39.
|
28 |
|
/
〈 |
|
〉 |