基于二维相关红外光谱的超支化聚合物修饰碳纳米管/环氧树脂复合材料固化机理研究

张可峰, 李璐, 段佳琦, 梁景元, 杨梦骄

PDF(4707 KB)
中国高校科技期刊信息汇聚平台
PDF(4707 KB)
塑料科技 ›› 2025, Vol. 53 ›› Issue (01) : 68-75. DOI: 10.15925/j.cnki.issn1005-3360.2025.01.012
理论与研究

基于二维相关红外光谱的超支化聚合物修饰碳纳米管/环氧树脂复合材料固化机理研究

作者信息 +

Study on Curing Mechanism of Hyperbranched Polymer Modified Carbon Nanotube/Epoxy Resin Composites Based on Two-dimensional Correlation Infrared Spectroscopy

Author information +
History +

摘要

为明确超支化聚合物修饰碳纳米管/环氧树脂复合材料的固化机理以及不同超支化聚合物的引入对环氧树脂基体固化行为的影响机制，利用移动窗口二维相关红外分析方法，对比分析超支化聚酯修饰碳纳米管/环氧树脂复合材料（EP/MWCNTs-H204）和超支化聚酰胺修饰碳纳米管/环氧树脂复合材料（EP/MWCNTs-N103）两个体系在升温固化过程中特征官能团的变化规律，并利用广义二维相关红外分析详细探讨各官能团发生变化的先后次序，合理解释了不同超支化聚合物的引入对环氧树脂复合材料固化行为的影响规律。

Abstract

To clarify the curing mechanism of hyperbranched polymer modified carbon nanotubes/epoxy resin composite materials and the influence mechanism of different hyperbranched polymers on the curing behavior of epoxy resin matrix, a moving window two-dimensional correlation infrared analysis method was used, and a comparative analysis was conducted on the changes in characteristic functional groups of hyperbranched polyester modified carbon nanotubes/epoxy resin composite material (EP/MWCNTs H204) and hyperbranched polyamide modified carbon nanotubes/epoxy resin composite material (EP/MWCNTs N103) during the heating and curing process. The sequence of changes in each functional group was discussed in detail using generalized two-dimensional correlated infrared analysis. The influence of the introduction of different hyperbranched polymers on the curing behavior of epoxy resin composites was reasonably explained.

关键词

超支化聚合物 / 碳纳米管 / 环氧树脂 / 二维相关红外分析 / 固化机理

Key words

Hyperbranched polymer / Carbon nanotubes / Epoxy resin / Two-dimensional correlation infrared analysis / Curing mechanism

中图分类号

TQ323.5 / TB332

引用本文

EndNote

Ris (Procite)

Bibtex

导出引用
张可峰 , 李璐 , 段佳琦 , 等. 基于二维相关红外光谱的超支化聚合物修饰碳纳米管/环氧树脂复合材料固化机理研究. 塑料科技. 2025, 53(01): 68-75 https://doi.org/10.15925/j.cnki.issn1005-3360.2025.01.012
ZHANG Kefeng, LI Lu, DUAN Jiaqi, et al. Study on Curing Mechanism of Hyperbranched Polymer Modified Carbon Nanotube/Epoxy Resin Composites Based on Two-dimensional Correlation Infrared Spectroscopy[J]. Plastics Science and Technology. 2025, 53(01): 68-75 https://doi.org/10.15925/j.cnki.issn1005-3360.2025.01.012

参考文献

列表( 原文顺序 | 文献年度倒序 | 文中引用次数倒序 ) 可视化分析
1
孙曼宁.环氧树脂应用原理与技术[M].北京:机械工业出版社,2001.
本文引用 [1]
2
陈平,刘胜平.环氧树脂[M].北京:化学工业出版社,1999.
3
谢志鹏,张会旗,原续波,等.环氧树脂增韧改性的研究进展[J].高分子通报,2018(11):1-16.
本文引用 [1]
4
赵阳,张永明,贺泽明,等.羧基化碳纳米管/环氧树脂复合材料的制备及其性能研究[J].化工新型材料,2023,51(6):90-93.
本文引用 [1]
5
LI L, LIAO X, SHENG X Y, et al. Effect of structure regulation of hyper-branched polyester modified carbon nanotubes on toughening performance of epoxy/carbon nanotube nanocomposites[J]. RSC Advances, 2019, 9(23): 12864-12876.
6
李璐,张贤明,盛兴跃,等.超支化聚酰胺修饰碳纳米管/环氧树脂复合材料的制备及性能[J].高分子材料科学与工程,2022,38(10):81-89.
本文引用 [1]
7
Noda I. Two-Dimensional Infrared(2D IR) spectroscopy of synthetic and biopolymers[J]. Bulletin of American Physical Society, 1986, 31(3): 520-527.
本文引用 [1]
8
NODA I. Determination of two-dimensional correlation spectra using the Hilbert transform[J]. Applied Spectroscopy, 2000, 54(7): 994-999.
9
宦佳琪,樊万鑫,孙昊,等.咪唑羧酸盐固化环氧树脂的机理及动力学研究[J].热固性树脂,2022,37(3):6-12.
本文引用 [1]
10
WU Z J, YI X S, WILKINSON A. Interlaminar fracture toughness of carbon fibre/RTM6-2 composites toughened with thermoplastic-coated fabric reinforcement[J]. Composites Part B-Engineering, 2017, 130: 192-199.
本文引用 [1]
11
郝增恒,李璐,王民,等.基于FT-IR及二维相关分析的SBS超热老化机理[J].高分子材料科学与工程,2015,31(7):119-123.
本文引用 [1]
12
Noda I. 2-Dimensional infrared (2D IR) spectroscopy-theory and applications[J]. Applied Spectroscopy, 1990, 44(4): 550-561.
本文引用 [1]
13
谢林萍,晏石林,何旭,等.碳纳米管改性泡沫镍/环氧树脂复合材料阻尼性能[J].复合材料学报,2017,34(6):1325-1333.
14
徐鑫,王超,陈泽明.碳纳米管和石墨烯基纳米填料在环氧树脂体系导电和导热性能中的应用[J].化学与粘合,2024,46(2):179-183.
本文引用 [1]
15
LIU X H, XU C H, SUN S Q, et al. Discrimination of different genuine Danshen and their extracts by Fourier transform infrared spectroscopy combined with two-dimensional correlation infrared spectroscopy[J]. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2012, 97: 290-296.
本文引用 [1]
16
李璐,张贤明.环氧树脂/超支化聚合物修饰碳纳米管复合材料的固化反应动力学研究[J].塑料科技,2023,51(11):20-26.
17
徐朝华,李珩.超支化聚合物/碳纳米管复合物的制备及流变性能研究进展[J].化工新型材料,2013,41(4):167-168, 171.
本文引用 [1]
18
MAITY T, SAMANTA B C, DALAI S. Curing study of epoxy resin by new aromatic amine functional curing agents along with mechanical and thermal evaluation[J]. Materials Science and Engineering A, 2007, 464: 38-46.
本文引用 [1]
19
蒋玉梅,陆绍荣,张晨曦,等.环氧树脂/超支化聚酯/纳米SiO2复合材料的制备及性能[J].高分子材料科学与工程,2010,26(3):134-137.
20
孙瑞敏,郝延蔚,周永恒,等.端羟基超支化聚(胺-酯)接枝氧化石墨烯及在环氧树脂中的应用[J].高分子材料科学与工程,2021,37(11):69-76.
本文引用 [1]
21
DOMUN N, HADAVINIA H, ZHANG T, et al. Improving the fracture toughness and the strength of epoxy using nanomaterials—A review of the current status[J]. Nanoscale, 2015, 7: 10294-10329.
本文引用 [1]
22
HOU L, WU P Y. Exploring the hydrogen-bond structures in sodium alginate through two-dimensional correlation infrared spectroscopy[J]. Carbohydrate Polymers, 2019, 205(1): 420-426.
本文引用 [1]
23
文放,孙玉昭,赵微,等.不同功能化碳纳米管对环氧树脂复合材料性能的影响[J].塑料,2020,49(6):42-49.
本文引用 [1]
24
周洋龙,邹滨泽,魏玮,等.聚(苯乙烯-alt-马来酸酐)修饰碳纳米管改性环氧树脂[J].热固性树脂,2020,35(1):32-38.
25
Zhang H H, Wu Y Q, Bai B L, et al. Classification of the hydrogen-bonding species in a series of novel hydrazide based azobenzene derivatives investigated by two-dimensional correlation infrared spectroscopy and molecular modeling[J]. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2006, 63(1): 117-125.
本文引用 [1]
26
CHEN Y P, ZHANG H H, WANG X Z, et al. Structure and two-dimensional correlation infrared spectroscopy study of two isomeric forms of the octamolybdate cluster[J]. Journal of Solid State Chemistry, 2006, 179(6): 1674-1680.
本文引用 [1]
27
KINLOCH I, SHAFFER M, LAM Y, et al. High-throughput screening for carbon nanotube production[J]. Carbon, 2004, 42: 101-110.
28
丁盛.PVP表面修饰碳纳米管在环氧树脂中的应用[J].塑料科技,2021,49(9):56-60.
本文引用 [1]
29
张明艳,王登辉,吴子剑,等.改性碳纳米管/环氧树脂复合材料的介电性能[J].复合材料学报,2020,37(6):1285-1294.
本文引用 [1]
30
李璐,张贤明,周丽洁.基于二维相关红外的环氧树脂/多壁碳纳米管复合材料固化机理研究[J].塑料科技,2024,52(2):13-19.
本文引用 [1]

基金

重庆市教委科学技术研究计划重大项目(KJZD-M202403801)
重庆市教委科学技术研究计划项目(KJKD-K202303802)
重庆市永川区自然科学基金项目(2023yc-jckx20078)

评论

PDF(4707 KB)

Accesses

Citation

Detail
段落导航
相关文章
Copyright 中国高校科技期刊信息汇聚平台 2024-2025
技术支持：北京玛格泰克科技发展有限公司
京ICP备05021913号-19

/

〈 〉