
不同成核剂对聚丙烯性能影响研究
李春晖, 郝春波, 姚秀超, 翟旭蓬, 庄松, 于洪洋, 刘全中
不同成核剂对聚丙烯性能影响研究
Study on Effect of Different Nucleating Agents on Properties of Polypropylene
文章研究了α成核剂CH-6N、HPN-715、TMP-7与β成核剂TMB-5四种不同类型成核剂以及不同类型成核剂复配对聚丙烯力学性能、光学性能及结晶性能的影响。结果表明:成核剂均能有效提高结晶温度与结晶度。α成核剂CH-6N增刚改性效果最好,CH-6N添加量0.2%,聚丙烯的弯曲模量为2 390 MPa,弯曲强度为60.6 MPa。α成核剂会降低聚丙烯韧性,添加0.2% CH-6N,聚丙烯的冲击强度仅为2.7 kJ/m2。β成核剂TMB-5可有效提高聚丙烯韧性,但会降低刚性。0.1% TMB-5增韧效果最好,聚丙烯的冲击强度为20.7 kJ/m2,拉伸断裂伸长率为530%。光学性能方面,α成核剂CH-6N改性效果最好,0.1% CH-6N加入后聚丙烯黄色指数仅为0.46。α成核剂与β成核剂复配改性聚丙烯,既能有效提高聚丙烯的韧性,又能改善其刚性,可达到刚韧平衡。0.1% CH-6N与0.1% TMB-5复配改性效果较好,聚丙烯的冲击强度达5.5 kJ/m2,弯曲模量为2 140 MPa,拉伸强度为41.1 MPa。
In this paper, the effects of four different types of nucleating agents, namely, α-nucleating agent CH-6N, HPN-715, TMP-7 and β-nucleating agent TMB-5, as well as the effects of compounding of different types of nucleating agents on the mechanical, optical and crystalline properties of polypropylene were investigated. The results show that the nucleating agent can effectively increase the crystallization temperature and crystallinity. α-nucleating agent CH-6N has the best rigidity effect. The bending modulus and bending strength of polypropylene are 2 390 MPa and 60.6 MPa respectively with the addition of 0.2% CH-6N. The α nucleating agent can reduce the toughness of polypropylene. Adding 0.2% CH-6N, the impact strength of polypropylene is only 2.7 kJ/m2. The β-nucleating agent TMB-5 can effectively improve the toughness of polypropylene, but reduce the rigidity. The toughening effect of 0.1 % TMB-5 is the best. The impact strength of polypropylene is 20.7 kJ/m2, and the elongation at break is 530%. In terms of optical properties, α nucleating agent CH-6N has the best modification effect, and after the addition of 0.1% CH-6N, the yellow index of polypropylene is only 0.46. The combination of α nucleating agent and β nucleating agent can not only improve the toughness of polypropylene, but also improve its rigidity, and achieve the balance of rigidity-toughness. The compound modification effect of 0.1% CH-6N and 0.1% TMB-5 is good, and the impact strength of polypropylene is 5.5 kJ/m2, the bending modulus is 2 140 MPa, and the tensile strength is 41.1 MPa.
Nucleating agents / Polypropylene / Crystallinity / Mechanical properties
TQ325.1+4
1 |
姜泽钰,李鹤廷,吴双,等.无规共聚聚丙烯注塑专用树脂的结构与性能[J].塑料科技,2023,51(9):27-30.
|
2 |
李泽芾,杨世元,陈振斌.PP树脂的加工流变行为研究进展[J].塑料科技,2023,51(7):104-109.
|
3 |
胡全超,辛超,黄丽辉,等.加工与老化对等规聚丙烯结构与性能的影响[J].塑料科技,2022,50(11):55-60.
|
4 |
李丽,庄光山,陈子鹏,等.聚丙烯成核剂的制备和性能[J].工程塑料应用,2022,50(12):131-135.
|
5 |
周群华,杨立群,时惠敏,等.聚丙烯β晶成核剂及其对iPP结晶行为的影响[J].高分子通报,2021(8):9-18.
|
6 |
王文超,王艳芝,张振刚,等.基于滤板应用的β成核剂增韧改性聚丙烯研究[J].中国塑料,2021,35(12):102-107.
|
7 |
王琛.高分子材料改性技术[M].北京:中国纺织出版社,2007.
|
8 |
张伟娇.成核剂改性无规共聚聚丙烯的结晶行为及性能研究[D].杭州:浙江大学,2020.
|
9 |
刘亮,周雪飞,张学俊.四羧酸酞菁成核剂对聚丙烯性能的影响[J].塑料工业,2020,48(6):135-138.
|
10 |
李安琪.高弹透明聚丙烯的制备与性能研究[D].北京:北京化工大学,2020.
|
11 |
曾书龙,李怡俊,吴磊.α成核剂与增刚剂对不同相对分子质量聚丙烯的影响[J].塑料,2022,51(2):23-28, 33.
|
12 |
刘亮,周雪飞,张学俊.四羧酸酞菁成核剂对聚丙烯性能的影响[J].塑料工业,2020,48(6):135-138.
|
13 |
向星宇,蓝滨,杨其.玻璃纤维静电吸附β成核剂增强PP的结构与性能[J].塑料工业,2021,49(4):38-41, 10.
|
14 |
娜迪热·加沙热提,王益龙,王志高.POE和成核剂协同增韧聚丙烯的研究[J].塑料科技,2020,48(5):117-120.
|
15 |
石行波,王艳芳,陈商涛,等.不同形貌CaCO3负载β成核剂对PP性能的影响[J].中国塑料,2018,32(10):113-116.
|
16 |
祁蓉,铁文安,田小艳,等.β成核剂在聚丙烯材料中的改性研究与应用[J].塑料工业,2021,49(10):9-12.
|
17 |
马丽,王文燕,金毅,等.β成核剂与无机填料对聚丙烯力学性能的影响[J].工业催化,2017,25(7):73-76.
|
18 |
欧阳锐,叶炜婷,林渊智,等.复配稳定剂对废旧聚丙烯再生料抗老化性能的影响[J].塑料科技,2022,50(8):1-5.
|
19 |
康文倩,王雄,程鹏飞,等.聚丙烯成核剂的研究进展[J].合成树脂及塑料,2022,39(4):82-87.
|
20 |
杨世元,邸麟婷,伍剑,等.增刚成核剂对高熔体流动速率聚丙烯性能的影响[J].工程塑料应用,2023,51(1):123-127, 138.
|
21 |
宋程鹏,张守玉,焦旗,等.α/β复合成核剂协同增强煤基均聚聚丙烯力学性能[J].高分子材料科学与工程,2022,38(10):56-65.
|
22 |
张荣,罗发亮,路宝翠,等.NX8000K/HPN-68L成核剂复配对等规聚丙烯性能改性的影响[J].合成材料老化与应用,2021,50(6):19-21.
|
23 |
苏小琴,龙伟,刘秀兰,等.差示扫描量热仪的影响因素及测试技术[J].分析仪器,2019(4):74-79.
|
24 |
郝春波,郑树松,肖大君,等.不同受阻胺光稳定剂与成核剂对聚丙烯光老化性能影响[J].工程塑料应用,2023,51(2):106-112.
|
25 |
张耀月,陈宏愿,陈敏剑,等.热塑性塑料熔体流动速率试验方法国家标准精密度研究[J].塑料工业,2017,45(10):117-121, 82.
|
26 |
冉崇文,谌基国,杨帆,等.成核剂对中MFR无规共聚聚丙烯性能的影响[J].合成树脂及塑料,2018,35(1):30-32.
|
27 |
蒋新坡.透明聚丙烯的制备及应用性能研究[D].上海:华东理工大学,2011.
|
28 |
董莉,李丽,段宏义,等.α成核剂对聚丙烯力学性能与结晶性能的影响[J].合成树脂及塑料,2019,36(2):53-56.
|
/
〈 |
|
〉 |