聚乳酸耐热改性的研究进展

陈中碧, 郭盛, 张秀刚, 俞森龙, 相恒学, 周哲, 朱美芳

PDF(1562 KB)
PDF(1562 KB)
塑料科技 ›› 2024, Vol. 52 ›› Issue (06) : 138-143. DOI: 10.15925/j.cnki.issn1005-3360.2024.06.026
综述

聚乳酸耐热改性的研究进展

作者信息 +

Research Progress on Heat Resistant Modification of Polylactic Acid

Author information +
History +

摘要

聚乳酸(PLA)具有良好的降解性能、力学性能与加工性能,是当前有发展前景的生物基可降解材料。然而PLA仍存在耐热性能差等问题,限制其在耐热要求较高领域的应用与发展。PLA耐热改性已成为学术界与产业界共同关注的热点。文章介绍了PLA热变形过程与改性机理,系统阐述了PLA耐热改性的研究进展,包括物理共混改性、加工外场调控、成核结晶优化、化学长链支化等方法,重点论述了通过成核结晶优化提升PLA耐热性能的研究现状,同时总结了不同耐热改性方法的利弊。针对PLA材料的属性及其在实际使用中的需求,预测其未来发展方向将聚焦于高效环保、长效稳定、复合功能等方面。

Abstract

Polylactic acid (PLA) is a biodegradable material with good degradability, mechanical properties and processing properties. However, PLA still has some problems such as poor heat resistance, which limits its application and development in the fields with high heat resistance requirements. Heat resistant modification of PLA has become a hot topic in academia and industry. In this paper, the thermal deformation process and modification mechanism of PLA were introduced, and the research progress of thermal modification of PLA was systematically described, including physical blending modification, processing field control, nucleation crystallization optimization, chemical long chain branching and other methods. The current research status of improving thermal resistance of PLA through nucleation crystallization optimization was emphatically discussed, and the advantages and disadvantages of different thermal modification methods were summarized. According to the properties of PLA material and its needs in actual use, it is predicted that its future development direction will focus on high efficiency and environmental protection, long-term stability, composite function and so on.

关键词

聚乳酸 / 耐热性能 / 物理共混 / 晶体结构 / 长链支化

Key words

Polylactic acid / Heat resistance / Physical blending / Crystal structure / Long chain branching

中图分类号

TQ323.4

引用本文

导出引用
陈中碧 , 郭盛 , 张秀刚 , . 聚乳酸耐热改性的研究进展. 塑料科技. 2024, 52(06): 138-143 https://doi.org/10.15925/j.cnki.issn1005-3360.2024.06.026
CHEN Zhong-bi, GUO Sheng, ZHANG Xiu-gang, et al. Research Progress on Heat Resistant Modification of Polylactic Acid[J]. Plastics Science and Technology. 2024, 52(06): 138-143 https://doi.org/10.15925/j.cnki.issn1005-3360.2024.06.026

参考文献

1
俞森龙,相恒学,周家良,等.典型高分子纤维发展回顾与未来展望[J].高分子学报,2020,51(1):39-54.
2
SUN C, WEI S Y, TAN H Y, et al. Progress in upcycling polylactic acid waste as an alternative carbon source: A review[J]. Chemical Engineering Journal, 2022, 446: 136881-136902.
3
NAGARAJAN V, MOHANTY A K, MISRA M. Perspective on polylactic acid (PLA) based sustainable materials for durable applications: Focus on toughness and heat resistance[J]. ACS Sustainable Chemistry & Engineering, 2016, 4(6): 2899-2916.
4
YANG Y, ZHANG L S, XIONG Z, et al. Research progress in the heat resistance, toughening and filling modification of PLA[J]. Science China Chemistry, 2016, 59(11): 1355-1368.
5
JIN F L, HU R R, PARK S J. Improvement of thermal behaviors of biodegradable poly(lactic acid) polymer: A review[J]. Composites Part B: Engineering, 2019, 164: 287-296.
6
BEHERA K, CHANG Y H, LIU C Y, et al. PMMA-driven morphology modification and dramatic improvement in ductility for PVDF/PLA blends[J]. Polymer, 2022, 252: 124930-124942.
7
HUANG Y, MÜLLER M T, BOLDT R, et al. Improved rheology, crystallization, and mechanical performance of PLA/mPCL blends prepared by electron-induced reactive processing[J]. ACS Sustainable Chemistry & Engineering, 2021, 9(9): 3478-3489.
8
SANG Z H, CHEN Y, LI Y, et al. Simultaneously improving stiffness, toughness, and heat deflection resistance of polylactide using the strategy of orientation crystallization amplified by interfacial interactions[J]. Polymer Crystallization, 2018, 1(1): 10004-10016.
9
XIONG Z, ZHANG L S, MA S Q, et al. Effect of castor oil enrichment layer produced by reaction on the properties of PLA/HDI-g-starch blends[J]. Carbohydrate Polymers, 2013, 94(1): 235-243.
10
ZHENG Y, PAN P J. Crystallization of biodegradable and biobased polyesters: Polymorphism, cocrystallization, and structure-property relationship[J]. Progress in Polymer Science, 2020, 109: 101291-101332.
11
MA B M, WANG X L, HE Y, et al. Effect of poly(lactic acid) crystallization on its mechanical and heat resistance performances[J]. Polymer, 2021, 212: 123280-123289.
12
RAZAVI M, WANG S Q. Why is crystalline poly(lactic acid) brittle at room temperature?[J]. Macromolecules, 2019, 52(14): 5429-5441.
13
LIN H, CHEN Y, GAO X R, et al. Transparent, heat-resistant, ductile, and self-reinforced polylactide through simultaneous formation of nanocrystals and an oriented amorphous phase[J]. Macromolecules, 2023, 56(6): 2454-2464.
14
MONNIER X, CAVALLO D, RIGHETTI M C, et al. Physical aging and glass transition of the rigid amorphous fraction in poly(l-lactic acid)[J]. Macromolecules, 2020, 53(20): 8741-8750.
15
黄威.聚乳酸亚稳相的形成与调控对纤维性能的影响研究[D].宁波:中国科学院宁波材料技术与工程研究所,2019.
16
SHIM E, POURDEYHIMI B, SHIFFLER D. Process-structure-property relationship of melt spun poly(lactic acid) fibers produced in the spunbond process[J]. Journal of Applied Polymer Science, 2016, 133(47): 44225-44235.
17
ZUO Y F, CHEN K, LI P, et al. Effect of nano-SiO2 on the compatibility interface and properties of polylactic acid-grafted-bamboo fiber/polylactic acid composite[J]. International Journal of Biological Macromolecules, 2020, 157: 177-186.
18
ZHANG Z, WANG Y, LI T, et al. High-performance polylactic acid materials enabled by TiO2-polydopamine hybrid nanoparticles[J]. Industrial & Engineering Chemistry Research, 2021, 60(10): 3999-4008.
19
BARCZEWSKI M, MYSIUKIEWICZ O, MATYKIEWICZ D, et al. Synergistic effect of different basalt fillers and annealing on the structure and properties of polylactide composites[J]. Polymer Testing, 2020, 89: 106628-106640.
20
SPINELLI G, GUARINI R, KOTSILKOVA R, et al. Experimental and simulation studies of temperature effect on thermophysical properties of graphene-based polylactic acid[J]. Materials, 2022, 15(3): 986-1009.
21
XIE Q, HAN L L, SHAN G R, et al. Polymorphic crystalline structure and crystal morphology of enantiomeric poly(lactic acid) blends tailored by a self-assemblable aryl amide nucleator[J]. ACS Sustainable Chemistry & Engineering, 2016, 4(5): 2680-2688.
22
BAI H W, HUANG C M, XIU H, et al. Enhancing mechanical performance of polylactide by tailoring crystal morphology and lamellae orientation with the aid of nucleating agent[J]. Polymer, 2014, 55(26): 6924-6934.
23
LIU Y F, JIANG S Y, YAN W, et al. Crystallization morphology regulation on enhancing heat resistance of polylactic acid[J]. Polymers (Basel), 2020, 12(7): 1563-1574.
24
SONG P, CHEN G Y, WEI Z Y, et al. Rapid crystallization of poly(l-lactic acid) induced by a nanoscaled zinc citrate complex as nucleating agent[J]. Polymer, 2012, 53(19): 4300-4309.
25
SINGH A A, GENOVESE M E, MANCINI G, et al. Green processing route for polylactic acid-cellulose fiber biocomposites[J]. ACS Sustainable Chemistry & Engineering, 2020, 8(10): 4128-4136.
26
ZHANG C N, WANG S N, ZHANG H B, et al. Direct preparation of high thermal stable PLA‐based nanocomposite via extra‐low loading of in situ exfoliated ultrathin MWW zeolite nanosheets[J]. Macromolecular Materials and Engineering, 2020, 305(12): 2000406-2000411.
27
LI F F, ZHANG C L, WENG Y X. Improvement of the gas barrier properties of PLA/OMMT films by regulating the interlayer spacing of OMMT and the crystallinity of PLA[J]. ACS Omega, 2020, 5(30): 18675-18684.
28
BAI H W, ZHANG W Y, DENG H, et al. Control of crystal morphology in poly(L-lactide) by adding nucleating agent[J]. Macromolecules, 2011, 44(6): 1233-1237.
29
SHEN T F, XU Y S, MA P M, et al. High-performance poly(lactide) composites by construction of network-like shish-kebab crystals[J]. RSC Advances, 2016, 6(75): 71046-71051.
30
WANG Y, ZOU F F, LIN M J, et al. Bio-based poly(lactic acid) foams with enhanced mechanical and heat-resistant properties obtained by facilitating stereocomplex crystallization with addition of D-sorbitol[J]. International Journal of Biological Macromolecules, 2024, 265: 130902-130911.
31
YOO Y, YOUNGBLOOD J P. Green one-pot synthesis of surface hydrophobized cellulose nanocrystals in aqueous medium[J]. ACS Sustainable Chemistry & Engineering, 2016, 4(7): 3927-3938.
32
PAN G W, XU H L, MA B M, et al. Polylactide fibers with enhanced hydrolytic and thermal stability via complete stereo-complexation of poly(L-lactide) with high molecular weight of 600 000 and lower-molecular-weight poly(D-lactide)[J]. Journal of Materials Science, 2018, 53(7): 5490-5500.
33
ZHANG H X, BAI H W, DENG S H, et al. Achieving all-polylactide fibers with significantly enhanced heat resistance and tensile strength via in situ formation of nanofibrilized stereocomplex polylactide[J]. Polymer, 2019, 166: 13-20.
34
DENG S H, YAO J, BAI H W, et al. A generalizable strategy toward highly tough and heat-resistant stereocomplex-type polylactide/elastomer blends with substantially enhanced melt processability[J]. Polymer, 2021, 224: 123736-123747.
35
LIU J Y, LOU L J, YU W, et al. Long chain branching polylactide: Structures and properties[J]. Polymer, 2010, 51(22): 5186-5197.
36
BAI J, FANG H G, ZHANG Y Q, et al. Studies on crystallization kinetics of bimodal long chain branched polylactides[J]. Crystengcomm, 2014, 16(12): 2452-2461.
37
CHEN C Q, KE D M, ZHENG T T, et al. An ultraviolet-induced reactive extrusion to control chain scission and long-chain branching reactions of polylactide[J]. Industrial & Engineering Chemistry Research, 2016, 55(3): 597-605.
38
LI J F, LI Z Q, YE L, et al. Structure evolution and orientation mechanism of long-chain-branched poly (lactic acid) in the process of solid die drawing[J]. European Polymer Journal, 2017, 90: 54-65.
39
GROSS I P, SCHNEIDER F S S, CARO M L S B, et al. Polylactic acid, maleic anhydride and dicumyl peroxide: NMR study of the free-radical melt reaction product[J]. Polymer Degradation and Stability, 2018, 155: 1-8.
40
YOU J X, LOU L J, YU W, et al. The preparation and crystallization of long chain branching polylactide made by melt radicals reaction[J]. Journal of Applied Polymer Science, 2013, 129(4): 1959-1970.
41
LI P, ZHANG W, ZHU X Y, et al. Simultaneous improvement of the foaming property and heat resistance in polylactide via one-step branching reaction initiated by cyclic organic peroxide[J]. Industrial & Engineering Chemistry Research, 2020, 59(7): 2934-2945.
42
CLARKSON C M, AWAD A S MEL, CHOWDHURY R, et al. Melt spinning of cellulose nanofibril/polylactic acid (CNF/PLA) composite fibers for high stiffness[J]. ACS Applied Polymer Materials, 2018, 1(2): 160-168.

基金

中央高校基本科研业务费专项资金资助(2232021D-03)
山东省重点研发计划(重大科技创新工程)项目(2023CXGC010611)
河南省重大科技专项(231100320200)

评论

PDF(1562 KB)

Accesses

Citation

Detail

段落导航
相关文章

/