PDF(1644 KB)
The Morphological Distribution and Geochemical Genesis of Antimony in Typical High-Temperature Hot Springs
Song Hongyu, Guo Qinghai
PDF(1644 KB)
PDF(1644 KB)
The Morphological Distribution and Geochemical Genesis of Antimony in Typical High-Temperature Hot Springs
,
Antimony is a typical harmful element, and the negative environmental effects of antimony-rich hot springs discharge can not be neglected since geothermal genesis of antimony is an important source of antimony in the natural water environments. In this paper, the morphological distribution of antimony in hot springs and its geochemical genesis were analyzed in selected typical geothermal areas in southern Tibet and western Yunnan. In general, the antimony of geothermal water discharged from the study area can be up to 2 128.7 μg/L, which is much higher than the background values in the natural water environments. Hydrogeochemical calculations indicate that the main forms of antimony present in the hot springs are antimonate and antimonite, however, the percentage of thioantimony in some hot spring samples can be as high as 35% of the total antimony. Sulfide concentration, S(-II)/Sb molar ratio, and competitive thiolation between arsenic and antimony are the key factors affecting the content of thioantimony in hot springs. Among the geothermal systems involved in this study, the Tibetan MapamYumco, Moincer, and Moluojiang are magma-heat geothermal systems, and the antimony in the geothermal water originates from the input of fluids released from the hot storage surrounding rocks leaching and magma house as the heat source under high temperature conditions, while the Tibetan Quzuomu, Langjiu and Yunnan Banglazhang are non-magma-heat geothermal systems, and the main source of antimony in their thermal springs is geothermal water-peripheral rock mineral interaction.
hot springs / antimony / thioantimony / water-rock interactions / magmatic fluid input / geochemistry
|
Aksoy, N., Şimşek, C., Gunduz, O., 2009. Groundwater Contamination Mechanism in a Geothermal Field: A Case Study of Balcova, Turkey. Journal of Contaminant Hydrology, 103(1-2): 13-28. https://doi.org/10.1016/j.jconhyd.2008.08.006
|
|
Boreiko, C. J., Rossman, T. G., 2020. Antimony and Its Compounds: Health Impacts Related to Pulmonary Toxicity, Cancer, and Genotoxicity. Toxicology and Applied Pharmacology, 403: 115156. https://doi.org/10.1016/j.taap.2020.115156
|
|
Cavallo, D., Iavicoli, I., Setini, A., et al., 2002. Genotoxic Risk and Oxidative DNA Damage in Workers Exposed to Antimony Trioxide. Environmental and Molecular Mutagenesis, 40(3): 184-189. https://doi.org/10.1002/em.10102
|
|
Dong, S. L., Zhang, Z., Zhang, L. K., et al., 2018. Geochemistry, Hf-Sr-Nd Isotopes and Petrogenesis of Acidic Volcanic Rocks in Quzhuomu Region of Southern Tibet. Earth Science, 43(8):2701-2714 (in Chinese with English abstract).
|
|
Filella, M., Belzile, N., Chen, Y. W., 2002. Antimony in the Environment: A Review Focused on Natural Waters. Earth-Science Reviews, 59(1-4): 265-285. https://doi.org/10.1016/S0012-8252(02)00089-2
|
|
Giggenbach, W. F., 1988. Geothermal Solute Equilibria. Derivation of Na-K-Mg-Ca Geoindicators. Geochimica et Cosmochimica Acta, 52(12): 2749-2765. https://doi.org/10.1016/0016-7037(88)90143-3
|
|
Giggenbach, W. F., Soto, R. C., 1992. Isotopic and Chemical Composition of Water and Steam Discharges from Volcanic-Magmatic-Hydrothermal Systems of the Guanacaste Geothermal Province, Costa Rica. Applied Geochemistry, 7(4): 309-332. https://doi.org/10.1016/0883-2927(92)90022-U
|
|
Guo, Q. H., 2020. Magma-Heated Geothermal Systems and Hydrogeochemical Evidence of Their Occurrence. Acta Geologica Sinica, 94(12): 3544-3554 (in Chinese with English abstract).
|
|
Guo, Q. H., Liu, M. L., Li, J. X., et al., 2017a. Fluid Geochemical Constraints on the Heat Source and Reservoir Temperature of the Banglazhang Hydrothermal System, Yunnan-Tibet Geothermal Province, China. Journal of Geochemical Exploration, 172: 109-119. https://doi.org/10.1016/j.gexplo.2016.10.012
|
|
Guo, Q. H., Planer-Friedrich, B., Liu, M. L., et al., 2017b. Arsenic and Thioarsenic Species in the Hot Springs of the Rehai Magmatic Geothermal System, Tengchong Volcanic Region, China. Chemical Geology, 453: 12-20. https://doi.org/10.1016/j.chemgeo.2017.02.010
|
|
Guo, Q. H., Planer-Friedrich, B., Liu, M. L., et al., 2019. Magmatic Fluid Input Explaining the Geochemical Anomaly of very High Arsenic in some Southern Tibetan Geothermal Waters. Chemical Geology, 513: 32-43. https://doi.org/10.1016/j.chemgeo.2019.03.008
|
|
Guo, Q. H., Yang, C., 2021. Tungsten Anomaly of the High-Temperature Hot Springs in the Daggyai Hydrothermal Area, Tibet, China. Earth Science, 46(7): 2544-2554 (in Chinese with English abstract).
|
|
He, M. C., Wan, H. Y., 2004. Distribution, Speciation, Toxicity and Bioavailability of Antimony in the Environment. Progress in Chemistry, 16(1): 131-135 (in Chinese with English abstract).
|
|
Hoke, L., Lamb, S., Hilton, D. R., et al., 2000. Southern Limit of Mantle-Derived Geothermal Helium Emissions in Tibet: Implications for Lithospheric Structure. Earth and Planetary Science Letters, 180(3-4): 297-308. https://doi.org/10.1016/S0012-821X(00)00174-6
|
|
Hou, Z. Q., Li, Z. Q., 2004. Possible Location for Underthrusting Front of the Indus Continent: Constraints from Helium Isotope of the Geothermal Gas in Southern Tibet and Eastern Tibet. Acta Geologica Sinica, 78(4): 482-493 (in Chinese with English abstract).
|
|
Liao, Z. L., Liao, G. Y., Pan, G. T., et al., 2005. Distribution and Utilization of Geothermal Resources in Tibet Ngari. China Mining Magazine, 14(8): 43-46 (in Chinese with English abstract).
|
|
Lima, A., Cicchella, D., Di Francia, S., 2003. Natural Contribution of Harmful Elements in Thermal Groundwaters of Ischia Island (Southern Italy).Environmental Geology, 43(8): 930-940. https://doi.org/10.1007/s00254-002-0715-8
|
|
Liu, M. L., Guo, Q. H., Wu, G., et al., 2019. Boron Geochemistry of the Geothermal Waters from Two Typical Hydrothermal Systems in Southern Tibet (China): Daggyai and Quzhuomu. Geothermics, 82: 190-202. https://doi.org/10.1016/j.geothermics.2019.06.009
|
|
Liu, M. L., Cao, Y. W., Wang, M. D., et al., 2014. Source of Hydrochemical Composition and Formation Mechanism of Rehai Geothermal Water in Tengchong. Safety and Environmental Engineering, 21(6): 1-7 (in Chinese with English abstract).
|
|
Lou, H., Wang, C. Y., Huangfu, G., et al., 2002. Three-Demensional Seismic Velocity Tomography of the Upper Crust in Tengchong Volcanic Area, Yunnan Province. Acta Seismologica Sinica, 24(3): 243-251 (in Chinese with English abstract).
|
|
McCleskey, R. B., Nordstrom, D. K., Susong, D. D., et al., 2010. Source and Fate of Inorganic Solutes in the Gibbon River, Yellowstone National Park, Wyoming, USA. Journal of Volcanology and Geothermal Research, 193(3/4): 189-202. https://doi.org/10.1016/j.jvolgeores.2010.03.014
|
|
Planer-Friedrich, B., Wilson, N., 2012. The Stability of Tetrathioantimonate in the Presence of Oxygen, Light, High Temperature and Arsenic. Chemical Geology, 322-323: 1-10. https://doi.org/10.1016/j.chemgeo.2012.06.010
|
|
Poon, R., Chu, I., Lecavalier, P., et al., 1998. Effects of Antimony on Rats Following 90-Day Exposure via Drinking Water. Food and Chemical Toxicology, 36(1): 21-35. https://doi.org/10.1016/S0278-6915(97)80120-2
|
|
Shen, L. C., Wu, K. Y., Xiao, Q., et al., 2011. Study on CO2 Degassing in Geothermal Anomaly Areas in Tibet: A Case Study of Langjiu and Tagejia Geothermal Areas. Chinese Science Bulletin, 56(26): 2198-2208 (in Chinese).
|
|
Smichowski, P., 2008. Antimony in the Environment as a Global Pollutant: A Review on Analytical Methodologies for Its Determination in Atmospheric Aerosols. Talanta, 75(1): 2-14. https://doi.org/10.1016/j.talanta.2007.11.005
|
|
Wang, X. W., Wang, T. H., Gao, N. A., et al., 2022. Formation Mechanism and Development Potential of Geothermal Resources along the Sichuan-Tibet Railway. Earth Science, 47(3): 995-1011 (in Chinese with English abstract).
|
|
Wang, Y. Y., Zeng, L. S., Hou, K. J., et al., 2022. Mantle Source Components and Magmatic Evolution for the Comei Large Igneous Province: Evidence from the Early Cretaceous Niangzhong Mafic Magmatism in Tethyan Himalaya. Journal of Earth Science, 33(1): 133-149. https://doi.org/10.1007/s12583-021-1464-5
|
|
Wilson, N., Webster-Brown, J., Brown, K., 2012. The Behaviour of Antimony Released from Surface Geothermal Features in New Zealand. Journal of Volcanology and Geothermal Research, 247-248: 158-167. https://doi.org/10.1016/j.jvolgeores.2012.08.009
|
|
Yan, K. T., Guo, Q. H., Liu, M. L., 2019. Geochemical Anomalies of Arsenic and Its Speciation in Daggyai Geothermal Springs, Tibet. Journal of Jilin University (Earth Science Edition), 49(2): 548-558 (in Chinese with English abstract).
|
|
Zhao, C. P., 2008. Mantle-Derived Helium Release Characteristics and Deep Magma Chamber Activities of Present Day in the Tengchong Volcanic Area (Dissertation). Institute of Geology, China Earthquake Administration, Beijing (in Chinese with English abstract).
|
|
董随亮, 张志, 张林奎, 等, 2018. 藏南曲卓木地区酸性火山岩地球化学、Hf-Sr-Nd同位素特征及其成因. 地球科学, 43(8): 2701-2714.
|
|
郭清海, 2020. 岩浆热源型地热系统及其水文地球化学判据. 地质学报, 94(12): 3544-3554.
|
|
郭清海, 杨晨, 2021. 西藏搭格架高温热泉中钨的水文地球化学异常. 地球科学, 46(7): 2544-2554.
|
|
何孟常, 万红艳, 2004. 环境中锑的分布、存在形态及毒性和生物有效性. 化学进展, 16(1): 131-135.
|
|
侯增谦, 李振清, 2004. 印度大陆俯冲前缘的可能位置: 来自藏南和藏东活动热泉气体He同位素约束. 地质学报, 78(4): 482-493.
|
|
廖忠礼, 廖光宇, 潘桂棠, 等, 2005. 西藏阿里地热资源的分布特点及开发利用. 中国矿业, 14(8): 43-46.
|
|
刘明亮, 曹耀武, 王敏黛, 等, 2014. 腾冲热海热泉水化学组分来源及其形成机制探讨. 安全与环境工程, 21(6): 1-7.
|
|
楼海, 王椿镛, 皇甫岗, 等, 2002. 云南腾冲火山区上部地壳三维地震速度层析成像. 地震学报, 24(3): 243-251.
|
|
沈立成, 伍坤宇, 肖琼, 等, 2011. 西藏地热异常区CO2脱气研究: 以朗久和搭格架地热区为例. 科学通报, 56(26): 2198-2208.
|
|
汪新伟, 王婷灏, 高楠安, 等. 2022. 川藏铁路沿线地热资源形成机理与开发潜力. 地球科学, 47(3): 995-1011.
|
|
严克涛, 郭清海, 刘明亮, 2019. 西藏搭格架高温热泉中砷的地球化学异常及其存在形态. 吉林大学学报(地球科学版), 49(2): 548-558.
|
|
赵慈平, 2008. 腾冲火山区现代幔源氦释放特征及深部岩浆活动研究（博士学位论文）. 北京：中国地震局地质研究所.
|
/
| 〈 |
|
〉 |
AI Summary
