High temperature absorption properties of SiOC ceramic matrix composite reinforced by continuous microwave- absorbing SiC fibers

Qiaoying SHI, Jingdan LI, Nianyu GAN, Siwei LI

PDF(3474 KB)
PDF(3474 KB)
Journal of Materials Engineering ›› 2025, Vol. 53 ›› Issue (1) : 81-90. DOI: 10.11868/j.issn.1001-4381.2024.000140
RESEARCH ARTICLE

High temperature absorption properties of SiOC ceramic matrix composite reinforced by continuous microwave- absorbing SiC fibers

Author information +
History +

Abstract

The SiC-BN/SiOC ceramic matrix composites are prepared through the precursor infiltration pyrolysis(PIP) process, using wave-absorbing SiC fibers with in-situ BN coatings as reinforcements and SiOC ceramic as the matrix. After 7 PIP preparation cycles, the composite achieves densification with density of 2.05 g/cm³ and porosity of 4.28%. The dielectric constants are tested with vector network analyzer. Using transmission line theory, the microwave-absorbing properties of the composites from room temperature to 800 ℃ at 8.2-18 GHz are optimized. The results show that the dielectric constants of the SiC-BN/SiOC composites exhibits significant frequency dispersion effects, leading to broadband microwave-absorbing properties. When the thickness of the composites is 2.1 mm, the maximum bandwidth of the reflection loss better than -10 dB in the X band and the Ku band is 5.7 GHz. As the ambient temperature increases, the real and imaginary parts of the complex permittivity of the composites both increase. For reflection loss better than -5 dB in a wide bandwidth, the optimum thicknesses decrease from 2.3 mm (200 ℃) to 1.1 mm (800 ℃).

Key words

SiC fiber / SiOC ceramic / composite / dielectric constant / microwave absorption

Cite this article

Download Citations
Qiaoying SHI , Jingdan LI , Nianyu GAN , et al. High temperature absorption properties of SiOC ceramic matrix composite reinforced by continuous microwave- absorbing SiC fibers. Journal of Materials Engineering. 2025, 53(1): 81-90 https://doi.org/10.11868/j.issn.1001-4381.2024.000140

References

[1]
VIAU G RAVEL F ACHER O,et al.Preparation and microwave characterization of spherical and monodisperse Co-Ni particles[J].Journal of Magnetism and Magnetic Materials1995140:377-378.
[2]
陈珂,曾海兵,胡辉.雷达隐身材料技术研究[J].现代防御技术200533(1):58-61.
CHEN K ZENG H B HU H.Radar stealth material study[J].Modern Defence Technology200533(1):58-61.
[3]
贺媛媛,周超.飞行器隐身技术研究及发展[J].飞航导弹2012(1):84-91.
HE Y Y ZHOU C.Research and development of aircraft stealth technology[J].Aerospace Technology2012(1):84-91.
[4]
李雅茹,卫海鹏,高学斌,等.结构型微波吸收复合材料的研究进展[J].山西化工201939(3):22-25.
LI Y R WEI H P GAO X B,et al.Recent developments in the study on structural microwave absorbing composites[J].Shanxi Chemical Industry201939(3):22-25.
[5]
OHNABE H MASAKI S ONOZUKA M,et al.Potential application of ceramic matrix composites to aero-engine components[J].Composites Part A199930(4):489-496.
[6]
莫美芳.国外结构隐身材料的研制和发展概况[J].材料工程1991(5):46-49.
MO M F.Overview of the research and development of structural stealth materials abroad[J].Journal of Materials Engineering1991(5):46-49.
[7]
高晓菊,王红洁.高温微波功能复合材料研究进展[J].硅酸盐通报200726(5):975-979.
GAO X J WANG H J.Research progress of high temperature microwave function composite[J].Bulletin of the Chinese Ceramic Society200726(5):975-979.
[8]
YANG X Z LIN Y Y HUANG Y X,et al.Mechanical reinforced lightweight multifunctional metastructure with ultrabroadband microwave absorption[J].IEEE Antennas and Wireless Propagation Letters202120(6):1023-1027.
[9]
LIU Y ZHANG Z Q XIAO S T,et al.Preparation and properties of cobalt oxides coated carbon fibers as microwave-absorbing materials[J].Applied Surface Science2011257(17):7678-7683.
[10]
QU Z L,KAI W, DONG T,et al.Mechanical behavior of anti-oxidation coatings on C/C composites at elevated temperature: an in-situ indentation study[J].Ceramics International202046(5):6628-6633.
[11]
ZHANG Y L HU H REN J C,et al.Effect of the surface microstructure of SiC inner coating on the bonding strength and ablation resistance of ZrB2-SiC coating for C/C composites[J].Ceramics International201642(16):18657-18665.
[12]
YAJIMA S HAYASHI J OMORI M,et al.Development of a silicon carbide fibre with high tensile strength[J].Nature1976261(5562):683-685.
[13]
FU Z Y PANG A M LUO H,et al.Research progress of ceramic matrix composites for high temperature stealth technology based on multi-scale collaborative design[J].Journal of Materials Research and Technology202218:2770-2783.
[14]
LIU H T TIAN H CHENG H F.Dielectric properties of SiC fiber-reinforced SiC matrix composites in the temperature range from 25 to 700 ℃ at frequencies between 8.2 and 18 GHz[J].Journal of Nuclear Materials2013432(1/3):57-60.
[15]
ZHOU Q YIN X W YE F,et al.High temperature electromagnetic wave absorption properties of SiCf/Si3N4 composite induced by different SiC fibers[J].Ceramics International201945(5):6514-6522.
[16]
ZHOU Q YIN X W YE F,et al.Multiscale designed SiCf/Si3N4 composite for low and high frequency cooperative electromagnetic absorption[J].Journal of the American Ceramic Society2018101(12):5552-5563.
[17]
MO R YE F LIU X F,et al.A high-temperature structural and wave-absorbing SiC fiber reinforced Si3N4 matrix composites[J].Ceramics International202147(6):8191-8199.
[18]
SONG H H ZHOU W C LUO F,et al.Temperature dependence of dielectric properties of SiCf/PyC/SiC composites[J].Materials Science and Engineering:B2015195:12-19.
[19]
PANTANO C G SINGH A K ZHANG H.Silicon oxycarbide glasses[J].Journal of Sol-Gel Science and Technology199914:7-25.
[20]
YUAN M J ZHOU T HE J,et al.Formation of boron nitride coatings on silicon carbide fibers using trimethylborate vapor[J].Applied Surface Science2016382:27-33.
[21]
WU Q Q WANG Z DING Q,et al.C/SiOC composites by a modified PIP using solid polysiloxane:fabrication,microstructure and mechanical properties[J].Journal of Inorganic Materials201934(12):1349-1356.
[22]
ZHANG G J SHI Q Y ZHANG W X,et al.High performance SiC/SiOC composites with in situ carbon interface[J].Ceramics International202349(14):23011-23019.
[23]
GUO K S ZHANG W X ZHANG S N,et al.Optimization of the microwave absorptivity of SiCf/resin composites in the GHz range[J].Ceramics International202147(13):18262-18273.
[24]
REN Z W ZHOU W C QING Y C,et al.Microwave absorption and mechanical properties of SiCf/SiOC composites with SiO2 fillers[J].Ceramics International202147(6):8478-8485.
[25]
REN Z W ZHOU W C QING Y C,et al.Simultaneously improving mechanical and microwave absorption properties of a novel SiCf/SiOC & mullite hybrid ceramic matrix composite[J].Journal of the European Ceramic Society202141(15):7560-7571.
[26]
YANG F XUE J M MA Y J,et al.Impedance matching optimization of SiCf/Si3N4-SiOC composites for excellent microwave absorption properties[J].Ceramics International202248(2):1889-1897.
[27]
REN Z W ZHOU W C QING Y C,et al.Simultaneous enhancement of mechanical and microwave absorption properties with a novel in-situ synthesis α-Al2O3 fillers for SiCf/SiC composites[J].Journal of the European Ceramic Society202242(12):4723-4734.
[28]
YANG F XUE J M MA Y J,et al.Sandwich structure SiCf/Si3N4-SiOC-Si3N4 composites for high-temperature oxidation resistance and microwave absorption[J].Ceramics International202248(17):24803-24810.
[29]
HAN T LUO R Y CUI G Y,et al.Effect of SiC nanowires on the high-temperature microwave absorption properties of SiCf/SiC composites[J].Journal of the European Ceramic Society201939(5):1743-1756.
[30]
丁世敬,葛德彪,黄刘宏.电磁吸波材料中的阻抗匹配条件[J].电波科学学报200924(6):1104-1108.
DING S J GE D B HUANG L H.Impedance matching condition of electromagnetic absorbing material[J].Chinese Journal of Radio Science200924(6):1104-1108.

Comments

PDF(3474 KB)

Accesses

Citation

Detail

Sections
Recommended

/