Thermal decomposition behavior of ammonium perchlorate catalyzed by cobalt-based complexes

Peng ZHOU, Siwei ZHANG, Zhuoqun REN, Xiaolin TANG, Kuan ZHANG, Yifu ZHANG, Chi HUANG

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Journal of Materials Engineering ›› 2025, Vol. 53 ›› Issue (4) : 107-113. DOI: 10.11868/j.issn.1001-4381.2022.000488
RESEARCH ARTICLE

Thermal decomposition behavior of ammonium perchlorate catalyzed by cobalt-based complexes

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Abstract

The addition of a burning rate catalyst can affect the decomposition of oxidants and effectively regulate the burning rate of solid propellants. MOFs have aroused attentions due to their excellent properties in catalyzing the thermal decomposition of ammonium perchlorate （AP）， and existing research has mainly focused on changes in metal centers， without discussing the influence of ligands on the catalytic process. We prepare three types of Co-based complexes （Co-CP） catalysts using three different ligands （2-methylimidazole， terephthalic acid， and 1，2，4，5-phenylenetetramine） and discuss their effects on the thermal decomposition behavior of AP. The results indicate significant differences in the decomposition behavior of the three Co-CPs in AP due to differences in ligands. Co-ZIF can significantly reduce the decomposition temperature of AP while enhancing the heat release of the system. The relatively high thermal stability of Co-BDC affects the catalytic effect of AP thermal decomposition. Co-BTA can delay the low-temperature decomposition of AP by releasing NH3 through ligand decomposition. The gas-phase products during the reaction process are captured through thermogravimetric infrared spectroscopy （TG-IR） testing， and the possible mechanisms of AP decomposition catalyzed by different Co-CPs are further explored and discussed. This study provides a design approach for a metal complex-based combustion rate catalyst.

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solid propellant / ammonium perchlorate / combustion catalyst / MOF / thermal decomposition

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Peng ZHOU , Siwei ZHANG , Zhuoqun REN , et al . Thermal decomposition behavior of ammonium perchlorate catalyzed by cobalt-based complexes. Journal of Materials Engineering. 2025, 53(4): 107-113 https://doi.org/10.11868/j.issn.1001-4381.2022.000488

References

List( Publishing order | Descend order by publishing year | Descend order by cited within ) Chart analysis
[1]
TRACHE D， KLAPOETKE T M， MAIZ L， et al. Recent advances in new oxidizers for solid rocket propulsion［J］. Green Chemistry， 2017，19（20）：4711-4736.
本文引用 [1]
[2]
YUAN W， ZHANG L， TAO G， et al. Designing high-performance hypergolic propellants based on materials genome［J］. Science Advances， 2020，6（49）： eabb1899.
[3]
JOFRE L， URZAY J. Transcritical diffuse-interface hydrodynamics of propellants in high-pressure combustors of chemical propulsion systems［J］. Progress in Energy and Combustion Science， 2021，82：100877.
[4]
DALINGER I L， SUPONITSKY K Y， SHKINEVA T K， et al. Bipyrazole bearing ten nitro groups-a novel highly dense oxidizer for forward-looking rocket propulsions［J］. Journal of Materials Chemistry A， 2018，6（30）：14780-14786.
本文引用 [1]
[5]
ZHANG J， JIN B， LI X， et al. Study of H2AzTO-based energetic metal-organic frameworks for catalyzing the thermal decomposition of ammonium perchlorate［J］. Chemical Engineering Journal， 2021，404：126287.
本文引用 [1]
[6]
TSUCHIYA H， TOGASHI R， KOHGA M. Burning characteristics of ammonium nitrate propellant containing fine ammonium perchlorate-influence of porosity of ammonium perchlorate［J］. Propellants Explosives Pyrotechnics， 2023，48（6）：e202300027.
本文引用 [1]
[7]
HU Y， TAO B， SHANG F， et al. Thermal decomposition of ammonium perchlorate over perovskite catalysts： catalytic decomposition behavior， mechanism and application［J］. Applied Surface Science， 2020，513（30）：145849.
本文引用 [1]
[8]
ZHOU L， CAO S， ZHANG L， et al. Facet effect of Co3O4 nanocatalysts on the catalytic decomposition of ammonium perchlorate［J］. Journal of Hazardous Materials， 2020，392（15）： 122358.
本文引用 [2]
[9]
CHEN J， ZHANG L， SUN J， et al. The construction of hierarchical hollow double-shelled Co3O4 for the enhanced thermal decomposition of ammonium perchlorate［J］. Applied Surface Science， 2022，571（1）：151342.
本文引用 [1]
[10]
QU W， NIU S， SUN D， et al. Pb single atoms enable unprecedented catalytic behavior for the combustion of energetic materials［J］. Advanced Science， 2021，8（5）：2002889.
本文引用 [1]
[11]
JIN H， YOON S G， LEE W H， et al. Identification of water-infiltration-induced electrical energy generation by ionovoltaic effect in porous CuO nanowire films［J］. Energy & Environmental Science， 2020，13（10）：3432-3438.
本文引用 [1]
[12]
WU L， HU J， YANG X， et al. Synergistic effect of adsorption and electrocatalysis of CoO/NiO heterostructure nanosheet assembled nanocages for high-performance lithium-sulfur batteries［J］. Journal of Materials Chemistry A， 2022，10（44）：23811-23822.
[13]
SHU Y， CHEN H， CHEN N， et al. A principle for highly active metal oxide catalysts via NaCl-based solid solution［J］. Chem， 2020，6（7）：1723-1741.
[14]
HU Q， WANG Z， HUANG X， et al. A unique space confined strategy to construct defective metal oxides within porous nanofibers for electrocatalysis［J］. Energy & Environmental Science， 2020，13（12）：5097-5103.
本文引用 [1]
[15]
MIAO Q， ZHANG S. In situ self-assembly-generated 3D hierarchical Co3O4 micro/nanomaterial series： selective synthesis， morphological control， and energy applications［J］. ACS Applied Materials & Interfaces， 2017，9（50）：44199-44213.
本文引用 [1]
[16]
REID D L， DRAPER R， RICHARDSON D， et al. In situ synthesis of polyurethane-TiO2 nanocomposite and performance in solid propellants［J］. Journal of Materials Chemistry A， 2014，2（7）：2313-2322.
本文引用 [1]
[17]
CHEN J， HE S， HUANG B， et al. Highly space-confined ammonium perchlorate in three-dimensional hierarchically ordered porous carbon with improved thermal decomposition properties［J］. Applied Surface Science， 2018，457：508-515.
本文引用 [1]
[18]
曾凡达， 李纲. 花状CdO微球的制备及其对高氯酸铵热分解的催化性能［J］. 材料工程， 2020，48（6）：91-97.
ZENG F D， LI G. Preparation of flower-like CdO microspheres and its catalytic performances towards thermal decomposition of ammonium perchlorate［J］. Journal of Materials Engineering， 2020， 48（6）： 91-97.
[19]
LI N， GENG Z， CAO M， et al. Well-dispersed ultrafine Mn3O4 nanoparticles on graphene as a promising catalyst for the thermal decomposition of ammonium perchlorate［J］. Carbon， 2013，54：124-132.
本文引用 [1]
[20]
李思骏， 邵兰兴， 冯丽， 等. 二维Ce-MOFs纳米片的合成及可见光介导脱羧氧化性能［J］. 材料工程， 2022，50（9）：89-96.
LI S J， SHAO L X， FENG L， et al. Synthesis of 2D Ce-MOFs nanosheets and visiblelight-mediated decarboxylation performance［J］. Journal of Materials Engineering， 2022， 50（9）： 89-96.
本文引用 [2]
[21]
霍晓文， 于守武， 肖淑娟， 等. 金属有机框架材料在吸附分离领域的研究进展［J］. 材料工程， 2021，49（7）：10-20.
HUO X W， YU S W， XIAO S J， et al. Research progress of metal-organic framework materials in adsorption separation［J］. Journal of Materials Engineering， 2021， 49（7）： 10-20.
本文引用 [1]
[22]
田甜. Ag/ZnO复合材料制备及其对高氯酸铵热分解催化性能研究［D］.哈尔滨：哈尔滨工业大学， 2017.
TIAN T. Preparation of Ag/ZnO composite materials and reserching its catalytic effect on ammonium perchlorates thermal decomposition ［D］.Harbin：Harbin Institute of Technology， 2017.
本文引用 [2]
[23]
王爽. MOFs基复合粒子的构筑及其对AP热分解催化研究［D］. 太原：中北大学， 2020.
WANG S. Study on the construction of MOFs-based composites and their thermal decomposition catalysis of AP［D］.Taiyuan：North University of China， 2020.
本文引用 [1]
[24]
李丽， 柯香， 安亭， 等. 多孔核壳结构Ni@C纳米棒的制备及其对高氯酸铵热分解催化性能的影响［J］. 含能材料， 2019，27（10）：867-874.
LI L， KE X， AN T， et al. Preparation of porous core-shell structural Ni@C nanorods and their catalytic properties for thermal decomposition of ammonium perchlorate［J］. Chinese Journal of Energetic Materials，2019，27（10）：867-874.
本文引用 [1]
[25]
李海涛， 徐爽， 宋柳芳， 等. 纳米ZnO立方体催化AP热分解及其在HTPE推进剂中的应用［J］. 火炸药学报， 2021，44（1）：89-95.
LI H T， XU S， SONG L F，et al ．Thermal decomposition of AP catalyzed by nano ZnO cube and its application in HTPE propellants［J］．Chinese Journal of Explosives & Propellants， 2021，44（1）：89-95 ．
[26]
李丹扬， 曾大文， 李海涛. AP/Co-MOF核壳型纳米复合材料对AP热分解的自催化性能［J］. 化学与生物工程， 2016（7）：15-18.
LI D Y， ZENG D W， LI H T. Self-catalytical performance for ammonium perchlorate thermal decomposition by AP/Co-MOF core-shell nanocomposites［J］. Chemistry & Bioengineering，2016（7）：15-18.
本文引用 [1]
[27]
WU G， LIU S， CHENG G， et al. Ni-Co@carbon nanosheet derived from nickelocene doped Co-BDC for efficient oxygen evolution reaction［J］. Applied Surface Science， 2021，545（15）： 148975.
本文引用 [2]
[28]
邹雷， 刘国强， 江苗苗， 等. ZIF-67衍生Co/NC多孔碳材料的改性及其电催化水氧化性能［J］. 化工学报， 2020，71（6）：2821-2829.
ZOU L， LIU G Q， JIANG M M， et al. Preparation and modification of ZIF-67 derived Co/NC porous carbon composite for electrocatalytic oxygen evolution reaction［J］. CIESC Journal， 2020， 71（6）： 2821-2829.
[29]
SANAD M F， SANTIAGO A R P， TOLBA S A， et al. Co-Cu bimetallic metal organic framework catalyst outperforms the Pt/C Benchmark for oxygen reduction［J］. Journal of the American Society， 2021，143（10）：4064-4073.
本文引用 [2]
[30]
王建国， 任硕， 邵明虎， 等. 不同形貌Co3O4制备及对高氯酸铵催化性能研究［J］. 长春师范大学学报， 2023，42（12）：87-92.
WANG J G， REN S， SHAO M H， et.al. Preparation of nano-Co3O4 with different morphologies and its catalytic performance for thermal decomposition of ammoniam perchlorate［J］. Journal of Changchun Normal University， 2023， 42（12）：87-92.
本文引用 [1]
[31]
陈永， 赵凤起， 李辉， 等. 固体推进剂降速剂研究现状及发展趋势［J］. 火炸药学报， 2021，44（5）：567-577.
CHEN Y， ZHAO F Q， LI H， et.al. Research status and progress of burning-rate inhibitor in solid propellants［J］. Chinese Journal of Explosives & Propellants， 2021， 44（5）：567-577.
本文引用 [1]

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