定向凝固DSM11合金亚固溶恢复热处理工艺

周强, 华小雨, 黄春蓉, 郑为为

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材料工程 ›› 2025, Vol. 53 ›› Issue (6) : 12-23. DOI: 10.11868/j.issn.1001-4381.2025.000056
航空发动机及燃气轮机涡轮叶片修复技术专栏

定向凝固DSM11合金亚固溶恢复热处理工艺

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Partial-solution rejuvenation heat treatment of directionally solidified DSM11 superalloy

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摘要

针对定向凝固DSM11服役涡轮叶片显微组织损伤和性能退化问题,亟需开展亚固溶恢复热处理工艺研究。本研究参考真实服役DSM11叶片的损伤组织,以980 ℃热暴露500 h定向凝固DSM11合金为研究对象,研究不同亚固溶恢复热处理工艺对损伤组织和性能的影响。结果表明:采用1180 ℃/2 h固溶结合1120 ℃/2 h/AC+850 ℃/24 h/AC恢复热处理制度时,可以获得约23%、尺寸为270 nm左右的二次γ′相和约17%粗大γ′相的双态组织。同时,热暴露过程形成的晶界M 23C6型碳化物全部回溶,晶界γ′膜厚度降低。若直接进行1120 ℃时效处理,晶界M 23C6型碳化物也能发生溶解,但晶界γ′膜厚度几乎不发生变化。二次γ′相的尺寸和体积分数与固溶温度和固溶后冷却速度密切相关。炉冷得到的二次γ′相尺寸大于空冷,1160 ℃固溶时得到的二次γ′相在随后的时效过程中全部溶解,不会被保留。经过1180 ℃/2 h/AC+1120 ℃/2 h/AC+850℃/24 h/AC恢复热处理后,热暴露损伤DSM11合金980 ℃/220 MPa的持久寿命由18 h恢复至24 h,达到标准热处理态的86%。一定含量重新析出的二次γ′相对合金力学性能的恢复起主要作用。

Abstract

In view of the microstructure damage and property degradation of directionally solidified DSM11 service turbine blades, it is urgent to study the partial-solution rejuvenation heat treatment. In this study, the effects of different recovery heat treatments on the microstructure and mechanical properties of DSM11 superalloy are studied by using alloys after thermal exposure at 980 ℃ for 500 h with reference to the microstructure of DSM11 blade in real service condition. The results show that bimodal microstructures of 23% secondary γ' phase with the size of approximately 270 nm and 17% coarse degraded γ' phase can be obtained by 1180 ℃/2 h solution combined with 1120 ℃/2 h/AC+850 ℃/24 h/AC recovery heat treatment. Meanwhile, the M 23C6 carbides at the grain boundary, which are formed during the thermal exposure, are also dissolved. And γ' films on the grain boundary are also partially dissolved. Although the M 23C6 carbides at the grain boundary can also be dissolved by direct aging at 1120 ℃ without solution heat treatment, the γ' film on the grain boundary changes slightly. The size and volume fraction of the secondary γ' phase are closely related to the solution temperature and the cooling rate after the solution. The secondary γ' phase size obtained by furnace cooling is larger than that obtained by air cooling. The secondary γ' phase obtained at 1160 ℃ solution treatment is completely dissolved in the subsequent aging process and will not be retained in the final. After 1180 ℃/2 h/AC+1120 ℃/2 h/AC+850 ℃/24 h/AC rejuvenation heat treatment, the creep life of degraded DSM11 superalloy is recovered from 18 h to 24 h, which is about 86% of that in standard heat treatment. A certain amount of the reprecipitated secondary γ' phases play an important role in the recovery of mechanical properties.

关键词

亚固溶恢复热处理 / 定向凝固DSM11合金 / 双态组织 / 力学性能

Key words

partial-solution rejuvenation heat treatment / directionally solidified DSM11 superalloy / bimodal microstructure / mechanical property

中图分类号

TG156 / TB31

引用本文

导出引用
周强 , 华小雨 , 黄春蓉 , . 定向凝固DSM11合金亚固溶恢复热处理工艺. 材料工程. 2025, 53(6): 12-23 https://doi.org/10.11868/j.issn.1001-4381.2025.000056
Qiang ZHOU, Xiaoyu HUA, Chunrong HUANG, et al. Partial-solution rejuvenation heat treatment of directionally solidified DSM11 superalloy[J]. Journal of Materials Engineering. 2025, 53(6): 12-23 https://doi.org/10.11868/j.issn.1001-4381.2025.000056

参考文献

[1]
冯强, 童锦艳, 郑运荣, 等. 燃气涡轮叶片的服役损伤与修复 [J]. 中国材料进展201231(12): 21-34.
FENG Q TONG J Y ZHENG Y R, et al. Service induced degradation and rejuvenation of gas turbine blades [J]. Materials China201231(12): 21-34.
[2]
SUN F TONG J Y FENG Q, et al. Microstructural evolution and deformation features in gas turbine blades operated in-service [J]. Journal of Alloys and Compounds2015618: 728-733.
[3]
TAWANCY H M AL-HADHRAMI L M. Comparative performance of turbine blades used in power generation damage vs microstructure and superalloy composition selected for the application [J]. Engineering Failure Analysis201446: 76-91.
[4]
陈亚东, 郑运荣, 冯强. 基于微观组织演变的 DZ125 定向凝固高压涡轮叶片服役温度场的评估方法研究 [J]. 金属学报201652(12): 1545-1556.
CHEN Y D ZHENG Y R FENG Q. Evaluation service temperature field of high pressure blades made of directionally solidified DZ125 superalloy based on microstructural evolution [J]. Acta Metallurgica Sinica201652(12): 1545-1556.
[5]
李辉, 楼琅洪, 史学军, 等. GTD111 ( DSM11 )合金γ′粗化与持久性能 [C] ∥ 动力与能源用高温结构材料-第十一届中国高温合金年会论文集. 北京: 冶金工业出版社, 2012.
LI H LOU L H SHI X J, et al. γ′ coarsening and creep rupture property of GTD111( DSM11 ) superalloy [C] ∥ High Temperature Structure Material for Power and Energy: the Proceedings of 11th China Superalloy. Beijing: Metallurgical Industry Press, 2012.
[6]
HOSSEINI S S NATEGH S EKRAMI A A. Microstructural evolution in damaged IN738LC alloy during various steps of rejuvenation heat treatments [J]. Journal of Alloys and Compounds2012512: 340-350.
[7]
LEE H S KIM D H KIM D S. Microstructural changes by heat treatment for single crystal superalloy exposed at high temperature [J]. Journal of Alloys and Compounds2013561: 135-141.
[8]
陈凯, 任沛然, 朱文欣. 一种镍基单晶高温合金性能恢复热处理方法: CN116219337A[P]. 2023-06-06.
CHEN K REN P R ZHU W X. A rejuvenation heat treatment for recovering the properties of nickel based single crystal superalloy: CN116219337A[P]. 2023-06-06.
[9]
张京, 郑运荣, 冯强. 基于蠕变损伤的定向凝固DZ125合金恢复热处理研究 [J]. 金属学报201652(6): 717-726.
ZHANG J ZHENG Y R FENG Q. Study on rejuvenation heat treatment of a directionally-solidified superalloy DZ125 damaged by creep [J]. Acta Metallurgica Sinica201652(6): 717-726.
[10]
唐文书, 肖俊峰, 高斯峰, 等. 蠕变损伤 GTD111 合金恢复热处理组织演化研究 [J]. 航空材料学报201939(1): 70-78.
TANG W S XIAO J F GAO S F, et al. Microstructure evolution of creep damaged GTD111 superalloy during rejuvenation heat treatment [J]. Journal of Aeronautical Materials201939(1): 70-78.
[11]
WANG X M ZHOU Y WANG T Y. Morphological evolution of γ′ precipitate under various rejuvenation heat treatment cycles in a damaged nickel-based superalloy [J]. Rare Metals202343(2): 634-650.
[12]
TURAZI A OLIVEIRA C A S. Study of GTD111 superalloy microstructural evolution during high-temperature aging and after rejuvenation treatments [J]. Metallography Microstructure and Analysis201524(4): 3-12.
[13]
唐文书, 肖俊峰, 高斯峰, 等. 恢复热处理对定向合金γ′相再服役稳定性的影响 [J]. 航空材料学报202141(4): 109-118.
TANG W S XIAO J F GAO S F, et al. Effect of rejuvenation heat treatment on re-service aging stability of γ′ phase in directionally solidified superalloy [J]. Journal of Aeronautical Materials202141(4): 109-118.
[14]
SUN Z S JIANG X W QIU C B, et al. The investigations of rejuvenation heat treatment on the structure and mechanical properties of a serviced gas turbine blade [J]. Journal of Alloys and Compounds2023948: 169759.
[15]
KRONGTONG V TUENGSOOK P HOMKRAJAI W, et al. The effect of reheat treatments on microstructural restoration in cast nickel superalloy turbine blade GTD-111[J]. Acta Metallurgica Sinica200511(2): 171-182.
[16]
RETTBERG L H CALLAHAN P G GOODLET B R, et al. Rejuvenation of directionally solidified and single-crystal nickel-base superalloys [J]. Metallurgical and Materials Transactions A202152(3): 1609-1631.
[17]
JIANG X W WANG D XIE G . et al .The effect of long-term thermal exposure on the microstructure and stress rupture property of a directionally solidified Ni-based superalloy [J]. Metallurgical and Materials Transactions A201445(9): 6016-6026
[18]
HE L Z ZHENG Q SUN X F, et al. M 23C6 precipitation behavior in a Ni-base superalloy M963 [J]. Journal of Materials Science200540(11): 2959-2964.
[19]
HE L Z ZHENG Q SUN X F, et al. Effect of carbides on the creep properties of a Ni-base superalloy M963 [J]. Materials Science and Engineering: A2005397(1): 297-304.
[20]
ROY I BALIKCI E IBEKWE S, et al. Precipitate growth activation energy requirements in the duplex size γ′ distribution in the superalloy IN738LC [J]. Journal of Materials Science200540(23): 6207-6215.
[21]
BYUNG-HOON K BYENOG-OOK K YUN-KON J, et al. The influence of γ′ morphology and size on stress rupture properties in Ni-base superalloy IN738LC [J]. Journal of Materials Research and Technology202430: 2029-2040.
[22]
ZHANG J X MURAKUMO T KOIZUMI Y, et al. Interfacial dislocation networks strengthening a fourth-generation single-crystal TMS-138 superalloy [J]. Metallurgical and Materials Transactions A200233(12): 3741-3746.

基金

国家科技重大专项项目(J2019-Ⅶ-0010-0150)

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