无导线起搏器锂氟化碳电池材料和工艺的研究进展

周强, 袁坤山, 赵彦伟, 张海军

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中国高校科技期刊信息汇聚平台
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材料工程 ›› 2025, Vol. 53 ›› Issue (7) : 142-152. DOI: 10.11868/j.issn.1001-4381.2024.000685
综述

无导线起搏器锂氟化碳电池材料和工艺的研究进展

作者信息 +

Research progress in materials and technology of lithium fluorocarbon battery for leadless pacemaker

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History +

摘要

锂氟化碳电池因其高能量密度、卓越的安全性能及低自放电率等优势，在植入式医疗设备、军事领域、传感器、无线设备以及航空航天领域得到广泛应用，尤其在延长无导线起搏器使用寿命方面，锂氟化碳电池的性能表现至关重要。本文综述了提升锂氟化碳电池容量与电压的策略，重点讨论了以下3个方面：（1）高比容和高电压氟化碳的研发，涉及碳源结构的优化、氟化前后处理以及氟化方法的控制；（2）高性能电解液的开发，包括采用低浓度锂盐与高供体数溶剂，以及可参与反应的锂盐和溶剂；（3）电池工艺的优化，特别是厚电极和注液工艺。综合分析指出，通过精细调控碳源结构、优化氟碳键比例、改进电解液配方以及创新工艺技术有望研制出更高容量和电压的锂氟化碳电池，从而有效增强无导线起搏器的使用寿命。

Abstract

Lithium fluorocarbon batteries have gained widespread application in areas such as implantable medical devices， military application， sensors， wireless devices， and aerospace due to their high energy density， excellent safety performance， and low self-discharge rates. The performance of lithium fluorocarbon batteries is particularly critical in extending the service life of leadless pacemakers. This article reviews the strategies for enhancing the capacity and voltage of lithium fluorocarbon batteries. The following three aspects are mainly discussed：firstly， the advancement of high specific capacity and high voltage fluorocarbon， involving the optimization of carbon source structure， pre- and post-fluorination treatment， and control of fluorination methods； secondly， the development of high-performance electrolytes， including the use of low concentration lithium salts with solvents processing high donor number， as well as reactive lithium salts and solvents； lastly， the optimization of battery manufacturing processes， particularly focusing on thick electrode and electrolyte injection processes. A comprehensive analysis indicates that by meticulously modulating the structure of carbon sources， optimizing the proportion of fluorocarbon bonds， improving electrolyte formulations， and innovating process technologies， it is possible to develop lithium fluorocarbon batteries with higher capacity and voltage， thereby effectively enhancing the service life of leadless pacemakers.

关键词

无导线起搏器 / 氟化碳 / 高容量 / 高电压 / 电解液

Key words

leadless pacemaker / fluorinated carbon / high capacity / high voltage / electrolyte

中图分类号

TM911

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导出引用
周强 , 袁坤山 , 赵彦伟 , 等. 无导线起搏器锂氟化碳电池材料和工艺的研究进展. 材料工程. 2025, 53(7): 142-152 https://doi.org/10.11868/j.issn.1001-4381.2024.000685
Qiang ZHOU, Kunshan YUAN, Yanwei ZHAO, et al. Research progress in materials and technology of lithium fluorocarbon battery for leadless pacemaker[J]. Journal of Materials Engineering. 2025, 53(7): 142-152 https://doi.org/10.11868/j.issn.1001-4381.2024.000685

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植入式无导线微型心脏起搏器研发及产业化项目(2023YFC2411900)

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