形状记忆叠层复合材料的制备与性能

高军鹏, 蒋诗才, 王婷婷, 许虎, 张宝艳

PDF(1315 KB)
PDF(1315 KB)
材料工程 ›› 2025, Vol. 53 ›› Issue (4) : 163-168. DOI: 10.11868/j.issn.1001-4381.2023.000711
研究论文

形状记忆叠层复合材料的制备与性能

作者信息 +

Fabrication and characterization of shape memory composite with layer by layer method

Author information +
History +

摘要

根据玻璃化转变温度匹配的原则,制备了一种层状复合、周期调制的形状记忆叠层复合材料。热塑性树脂层作为材料的可逆相,具有较低的玻璃化转变温度;纤维增强树脂层作为材料的固定相,具有较高的玻璃化转变温度,通过层层叠合的方式,采用热压罐成型工艺进行了形状记忆复合材料的制备。结果表明,材料具有较好的形状记忆性质,其形状固定率为90%~95%,形状回复率为95%左右。利用了复合材料可设计性强的特点,使材料之间进行复合或交叉结合,制造出了单一材料所不具备的形状记忆材料。

Abstract

Due to the its appropriate glass transition temperature(T g), a kind of carbon reinforced carbon-reinforced composite with exhibiting a shape memory effect is successfully fabricated using a layer-by-layer method. A thermoplastic polymer with a relatively low T g served as the switching phase, while a cured epoxy with a relatively high T g functioned as the permanent phase. The shape memory composite is then molded using an autoclave. The results demonstrate that the composites exhibit a high shape memory effect, with shape retention rates ranging from 90% to 95% and a shape recovery rate of 95%. By leveraging the high design properties of composites, two types of materials are combined to create a novel composite with a shape memory effect.

关键词

形状记忆 / 复合材料 / 玻璃化转变温度 / 变形 / 回复

Key words

shape memory / composite / glass transition temperature / deformation / recovery

中图分类号

TB332 / V258

引用本文

导出引用
高军鹏 , 蒋诗才 , 王婷婷 , . 形状记忆叠层复合材料的制备与性能. 材料工程. 2025, 53(4): 163-168 https://doi.org/10.11868/j.issn.1001-4381.2023.000711
Junpeng GAO, Shicai JIANG, Tingting WANG, et al. Fabrication and characterization of shape memory composite with layer by layer method[J]. Journal of Materials Engineering. 2025, 53(4): 163-168 https://doi.org/10.11868/j.issn.1001-4381.2023.000711

参考文献

[1]
OHKI T NI Q OHSAKO N. Mechanical and shape memory behavior of composites with shape memory polymer [J]. Composites Part A200435 (9):1065-1073.
[2]
GALL K DUNN M LIU Y. Shape memory polymer nanocomposites [J]. Acta Materialia200250(20):5115-5126.
[3]
LIU Y, KEN G, DUNN M. Thermomechanics of shape memory polymer nanocomposites [J]. Mechanics of Materials200436 (10): 929-940.
[4]
CHO M KIM M H CHUNG C H, et al. A study on the room-temperature curvature shapes of unsymmetrical laminates including slippage effects[J]. Journal of Composite Materials198832, 460-483.
[5]
王鸿雁, 李岩, 付昆昆, 等. 电驱动连续碳纤维增强形状记忆复合材料镂空结构设计[J]. 航空材料学报202242(5): 100-108.
WANG H Y LI Y FU K K, et al.Hollow structure design of electrically driven continuous carbon fiber reinforced shape memory composite[J]. Journal of Aeronautical Materials202242(5): 100-108.
[6]
韩超越, 候冰娜, 郑泽邻, 等. 功能高分子材料的研究进展[J]. 材料工程202149(6): 55-65.
HAN C Y HOU B N ZHENG Z L, et al. Research progress in functional polymer materials[J]. Journal of Materials Engineering202149(6): 55-65.
[7]
任天宁, 朱光明, 聂晶. 形状记忆聚合物复合材料可展开结构的研究进展[J]. 航空材料学报201838(4): 47-55.
REN T N ZHU G M NIE J. Research progress on deployable structures of shape memory polymer composites[J]. Journal of Aeronautical Materials201838(4): 47-55.
[8]
何先成, 高军鹏, 安学锋, 等. 环氧树脂基形状记忆复合材料的制备与性能[J]. 航空材料学报201434(6): 62-66.
HE X C GAO J P AN X F, et al. Fabrication and performance of shape memory epoxy resin composite[J]. Journal of Aeronautical Materials201434(6): 62-66.
[9]
逄见光,王刚,曲明,等.形状记忆聚合物机理、表征与多形状记忆效应的研究进展[J].材料工程201846(5):64-71.
PANG J G WANG G QU M, et al. Progress on mechanism, characterization and multiple shape memory effect of shape memory polymer[J]. Journal of Materials Engineering201846(5): 64-71.
[10]
ZARE M PRABHAKARAN M P PARVIN N, et al. Thermally-induced two-way shape memory polymers: Mechanisms, structures, and applications[J]. Chemical Engineering Journal2019374: 706-720.
[11]
赵伟,刘立武,孙健,等.基于形状记忆聚合物复合材料航天航空可变形结构技术研究进展[J].宇航材料工艺202151(4):73-83.
ZHAO W LIU L W SUN J, et al. Progress of aerospace deformable structures based on shape memory polymer composites[J]. Aerospace Materials & Technology202151(4):73-83.
[12]
ROUSSEAU I A.Challenges of shape memory polymers: a review of the progress toward overcoming SMP’s limitations[J]. Polymer Engineering & Science201048(11):2075-2089.
[13]
SUN J DU L SCARPA F, et al. Morphing wingtip structure based on active inflatable honeycomb and shape memory polymer composite skin: a conceptual work[J]. Aerospace Science and Technology2021111: 106541.
[14]
张涛,梁玉蓉,王龙,等.TPI/NR复合材料的制备及形状记忆性能[J]. 弹性体202333(5):8-13.
ZHANG T LIANG Y R WANG L, et al. Preparation and shape memory properties of TPI/NR composite materials [J]. China Elastomerics202333(5):8-13.
[15]
张盼盼,兰中旭,俞燕蕾,等.透明耐高温聚酰亚胺薄膜的制备及形状记忆性能的研究[J].复旦学报(自然科学版)202059(1):109-115.
ZHANG P P LAN Z X YU Y L, et al. Study on preparation and shape memory properties of high temperature-resistant transparent polyimide film [J]. Journal of Fudan University (Natural Science)202059(1):109-115.
[16]
高军鹏,何先成,安学峰, 等.含氟聚醚醚酮改性环氧树脂形状记忆性质的动态热力学机理研究[J].航空材料学报201131(4):69-73.
GAO J P HE X C AN X F, et al. Thermodynamic property of shape memory epoxy resin modified with 6F-PEEK[J]. Journal of Aeronautical Materials201131(4): 69-73.

基金

国家重点研发计划项目(2022YFC2406103)

评论

PDF(1315 KB)

Accesses

Citation

Detail

段落导航
相关文章

/