绿色低温法制备Fe3O4及其复合材料吸波性能

潘虹, 胡磊, 徐丽慧, 王以红, 李凯, 沈勇, 王黎明, 丁颖

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材料工程 ›› 2025, Vol. 53 ›› Issue (4) : 150-162. DOI: 10.11868/j.issn.1001-4381.2023.000610
研究论文

绿色低温法制备Fe3O4及其复合材料吸波性能

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Fe3O4 prepared by green low temperature method and its composites absorbing property

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摘要

铁氧体作为常见的磁损耗型吸波材料，制备方法对其结构以及吸波性能的影响至关重要。传统的铁氧体制备多采用高温高压的溶剂热或者水热法制备，耗能大，材料后续复合时兼容性差。以氯化亚铁作为铁源，利用硝酸钾对亚铁离子进行可控的氧化反应，采用低温（50 ℃）共沉淀法制备了正八面体结构的Fe3O4，研究了不同反应条件制备产物的吸波效果，并将其与介电材料NiCo2O4复合，制备的复合材料具有较好的吸波性能。低温法降低了对生产设备的要求，减小了耗能，提高了材料复合的兼容性，大大拓宽了铁氧体材料的应用范围。

Abstract

Ferrite， a prevalent magnetic loss absorbing material， underscores the significance of its preparation method in determining both its structure and absorbing properties. Traditionally， ferrites are predominantly synthesized through solvothermal or hydrothermal methods， which entail substantial energy consumption and exhibit limited compatibility with other materials. Octahedral Fe3O4 is successfully synthesized via a low-temperature （50 ℃） co-precipitation process， utilizing ferrous chloride as the iron source. The oxidation reaction is meticulously controlled using potassium nitrate. Furthermore， the absorption effectiveness of the resultant product under various reaction conditions is thoroughly examined. Notably， the composite material formed by combining NiCo2O4 and Fe3O4 exhibits superior absorbing properties. This low-temperature approach not only mitigates the demands on equipment and energy consumption but also enhances material compatibility， thereby significantly expanding the application scope of ferrite materials.

关键词

铁氧体 / 电磁吸波材料 / 低温制备 / 复合材料

Key words

ferrite / electromagnetic wave absorbing material / low temperature preparation / composite material

中图分类号

TB331

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潘虹 , 胡磊 , 徐丽慧 , 等. 绿色低温法制备Fe3O4及其复合材料吸波性能. 材料工程. 2025, 53(4): 150-162 https://doi.org/10.11868/j.issn.1001-4381.2023.000610
Hong PAN, Lei HU, Lihui XU, et al. Fe3O4 prepared by green low temperature method and its composites absorbing property[J]. Journal of Materials Engineering. 2025, 53(4): 150-162 https://doi.org/10.11868/j.issn.1001-4381.2023.000610

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基金

上海自然科学基金项目(21ZR1426200)

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