
MoSi2含量对Ta0.8Hf0.2C-SiC-MoSi2涂层抗烧蚀性能的影响
刘莹, 李红, 姚彧敏, 杨敏, 陶银萍, 任慕苏, 孙晋良
MoSi2含量对Ta0.8Hf0.2C-SiC-MoSi2涂层抗烧蚀性能的影响
Effect of MoSi2 addition for ablation resistance of Ta0.8Hf0.2C-SiC-MoSi2 coating
Ta0.8Hf0.2C具有良好的热防护性能,适合在高温烧蚀环境中使用,MoSi2是一种优异的烧结助剂且常用于抗烧蚀涂层中。为了研究MoSi2含量对Ta0.8Hf0.2C-SiC-MoSi2涂层抗烧蚀性能的影响,本研究采用料浆刷涂法在含有SiC过渡涂层的C/C复合材料上制备了不同MoSi2含量的Ta0.8Hf0.2C-SiC-MoSi2涂层,并研究了不同涂层的相组成、微观形貌和烧蚀行为。结果表明,当MoSi2质量分数为10%时,涂层的质量烧蚀率和线烧蚀率分别为1.24 mg·s-1、0.02 μm·s-1,表现出较好的抗烧蚀性能。这是因为涂层中MoSi2的存在抑制了SiC的主动氧化,减少了SiC的消耗,在烧蚀过程中形成的液相层黏度较高,抵抗高温火焰的冲蚀的能力较强,有效地阻止了氧的扩散。
Ta0.8Hf0.2C exhibits excellent thermal protection properties, making it well-suited for high-temperature ablation environments. MoSi2, an outstanding sintering agent, is frequently employed in anti-ablation coatings. To investigate the impact of MoSi2 content on the ablative performance of Ta0.8Hf0.2C-SiC-MoSi2 coatings, we employ the slurry-sintering method to prepare coatings with varying MoSi2 concentrations on C/C composites, which are pre-coated with SiC transition layers. We conduct a comprehensive analysis of the phase composition, micromorphology, and ablation behavior of these coatings. The findings reveal that, at a MoSi2 content of 10% (mass fraction), the coating exhibits optimal ablative properties, with a mass ablation rate of 1.24 mg·s-1 and a line ablation rate of 0.02 μm·s-1. This superior performance is attributed to MoSi2 ability to hinder the active oxidation of SiC, thereby reducing its consumption. Additionally, the high-viscosity liquid layer formed during ablation effectively resists the erosion of high-temperature flames, further preventing the diffusion of oxygen.
C/C复合材料 / Ta0.8Hf0.2C-SiC-MoSi2涂层 / 料浆刷涂 / 烧蚀
C/C composite / Ta0.8Hf0.2C-SiC-MoSi2 coating / slurry method / ablation
TB332
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解齐颖,张祎,朱阳,等 .超高温陶瓷改性碳/碳复合材料[J].材料工程,2021,49(7):46-55.
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