MoSi2含量对Ta0.8Hf0.2C-SiC-MoSi2涂层抗烧蚀性能的影响

刘莹, 李红, 姚彧敏, 杨敏, 陶银萍, 任慕苏, 孙晋良

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材料工程 ›› 2025, Vol. 53 ›› Issue (6) : 235-243. DOI: 10.11868/j.issn.1001-4381.2023.000347
研究论文

MoSi2含量对Ta0.8Hf0.2C-SiC-MoSi2涂层抗烧蚀性能的影响

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Effect of MoSi2 addition for ablation resistance of Ta0.8Hf0.2C-SiC-MoSi2 coating

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摘要

Ta0.8Hf0.2C具有良好的热防护性能,适合在高温烧蚀环境中使用,MoSi2是一种优异的烧结助剂且常用于抗烧蚀涂层中。为了研究MoSi2含量对Ta0.8Hf0.2C-SiC-MoSi2涂层抗烧蚀性能的影响,本研究采用料浆刷涂法在含有SiC过渡涂层的C/C复合材料上制备了不同MoSi2含量的Ta0.8Hf0.2C-SiC-MoSi2涂层,并研究了不同涂层的相组成、微观形貌和烧蚀行为。结果表明,当MoSi2质量分数为10%时,涂层的质量烧蚀率和线烧蚀率分别为1.24 mg·s-1、0.02 μm·s-1,表现出较好的抗烧蚀性能。这是因为涂层中MoSi2的存在抑制了SiC的主动氧化,减少了SiC的消耗,在烧蚀过程中形成的液相层黏度较高,抵抗高温火焰的冲蚀的能力较强,有效地阻止了氧的扩散。

Abstract

Ta0.8Hf0.2C exhibits excellent thermal protection properties, making it well-suited for high-temperature ablation environments. MoSi2, an outstanding sintering agent, is frequently employed in anti-ablation coatings. To investigate the impact of MoSi2 content on the ablative performance of Ta0.8Hf0.2C-SiC-MoSi2 coatings, we employ the slurry-sintering method to prepare coatings with varying MoSi2 concentrations on C/C composites, which are pre-coated with SiC transition layers. We conduct a comprehensive analysis of the phase composition, micromorphology, and ablation behavior of these coatings. The findings reveal that, at a MoSi2 content of 10% (mass fraction), the coating exhibits optimal ablative properties, with a mass ablation rate of 1.24 mg·s-1 and a line ablation rate of 0.02 μm·s-1. This superior performance is attributed to MoSi2 ability to hinder the active oxidation of SiC, thereby reducing its consumption. Additionally, the high-viscosity liquid layer formed during ablation effectively resists the erosion of high-temperature flames, further preventing the diffusion of oxygen.

关键词

C/C复合材料 / Ta0.8Hf0.2C-SiC-MoSi2涂层 / 料浆刷涂 / 烧蚀

Key words

C/C composite / Ta0.8Hf0.2C-SiC-MoSi2 coating / slurry method / ablation

中图分类号

TB332

引用本文

导出引用
刘莹 , 李红 , 姚彧敏 , . MoSi2含量对Ta0.8Hf0.2C-SiC-MoSi2涂层抗烧蚀性能的影响. 材料工程. 2025, 53(6): 235-243 https://doi.org/10.11868/j.issn.1001-4381.2023.000347
Ying LIU, Hong LI, Yumin YAO, et al. Effect of MoSi2 addition for ablation resistance of Ta0.8Hf0.2C-SiC-MoSi2 coating[J]. Journal of Materials Engineering. 2025, 53(6): 235-243 https://doi.org/10.11868/j.issn.1001-4381.2023.000347

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基金

上海市教育发展基金会和上海市教育委员会“曙光计划”项目(18SG34)

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