Research Progress on Preparation Technology of Ultra-high Molecular Weight Polyethylene Fibers

HUANG Wei, DING Jinyou, CHEN Gonglin, CHENG Chunzu, ZHANG Dong, LI Ting, HUANG Qing

PDF(680 KB)
PDF(680 KB)
Plastics Science and Technology ›› 2025, Vol. 53 ›› Issue (03) : 161-167. DOI: 10.15925/j.cnki.issn1005-3360.2025.03.029
Review

Research Progress on Preparation Technology of Ultra-high Molecular Weight Polyethylene Fibers

Author information +
History +

Abstract

Ultra-high molecular weight polyethylene (UHMWPE) fibers are indispensable fiber materials for the development of national defense, military industry, aerospace, and high-tech industries. In order to deeply analyze the issues faced by domestic UHMWPE fibers in the production process, further improve the quality of domestic UHMWPE fibers, optimize existing fiber production technologies, and propose suggestions for future development directions, the article systematically introduces the principles and current status of UHMWPE fiber preparation both domestically and internationally. It also provides a summary and analysis of the cutting-edge technologies in different preparation methods and briefly elaborates on the dissolution mechanism of UHMWPE in solvents, in combination with the characteristics of UHMWPE spinning solvents.

Key words

Ultra-high molecular weight polyethylene fibers / Gel spinning / Hyperthermal stretching / Solvent

Cite this article

Download Citations
HUANG Wei , DING Jinyou , CHEN Gonglin , et al . Research Progress on Preparation Technology of Ultra-high Molecular Weight Polyethylene Fibers. Plastics Science and Technology. 2025, 53(03): 161-167 https://doi.org/10.15925/j.cnki.issn1005-3360.2025.03.029

References

1
叶卓然,罗靓,潘海燕,等.超高分子量聚乙烯纤维及其复合材料的研究现状与分析[J].复合材料学报,2022,39(9):4286-4309.
2
张博.超高分子量聚乙烯纤维概述[J].广州化工,2010,38(4):28-29.
3
任意.超高分子量聚乙烯纤维性能及应用概述[J].广州化工,2010,38(8):87-88.
4
毛云增,蔡正国,杨曙光,等.超高分子质量聚乙烯纤维研究进展[J].中国材料进展,2012,31(10):37-42, 20.
5
王双,王庆昭,陈勇,等.超高分子量聚乙烯熔体流动性改性研究进展[J].工程塑料应用,2014,42(10):113-117.
6
OHTA T. Review on processing ultra high tenacity fibers from flexible polymer[J]. Polymer Engineering and Science, 1983, 23: 697-703
7
PERTERLIN A. Molecular mechanism of plastic deformation of polyethylene[J]. Journal of Polymer Science Part C: Polumer Symposia, 1967, 18(1): 123-132.
8
PERTERLIN A. Molecular model of drawing polyethylene and polypropylrnr[J]. Journal of materials Science, 1976, 6(6): 490-508.
9
SOUTHERN J H, PORTER R S. Polyethylene crystallized under the orientation and pressure of a pressure capillary viscometer[J]. Journal of Macromolecular Science, Part B: Physics, 1970, 4(3): 34-36, 56.
10
CAPACCIO G, WARD I M. Preparation of ultra-high modulus linear polyethylene; effect of molecular weight and molecular weight distribution on drawing behavior and mechanical properties[J].Polymer, 1974, 15(4): 233-238.
11
GRISWOLD P D, ZACHARIADES A E, POTRTER R S. Solid state coextrusion: A new technique for ultradrawing thermoplastics illustrated with high density polyethylene[J]. Polymer Engineering & Science, 1978, 18(11): 861-863.
12
HILL M J, BARBAM P J, KELLER A. On the hairdressing of Shish-Kebabs[J]. Colloid&Polymer Science, 1980, 258(9): 1023-1037.
13
SMOOK J, TORF J C, VANHUTTEN P F, et al. Ultra-high strength polyethylene by hot drawing of surface growth fibers[J]. Polymer Bulletin, 1980, 2(5): 293-300.
14
BARHM P J, KELLER A. Some observations on the production of polyethylenefibers by the surface growth mothod[J]. Journal and Materials Science, 1980, 15(9): 2229-2235.
15
WU W, BLACK W B. High-Stength Polyethylene[J]. Polym Eng Sci, 1979, 19: 1163-1169.
16
WU W, SIMPSON P G, BLACK W B. Morphology and tensile property relations of high-strength/high-modulus polyethylene fiber[J]. Journal of Polymer Science Part B: Polymer Pyhsics, 1980, 18(4): 751-765.
17
CAPACCIO G, CROMPTON T A, WARD I M. Drawing behavior of linear polyethelene.II.Effect of draw temperature and molecular weight on draw eatio and modulus[J]. Journal of Polymer Science Part B: Polymer Pyhsics, 1980, 18(2): 301-309
18
SAVITSKY A V, GORSHKOVA I A, FROLOVA I L,et al. The model of polymer orientation strengthening and production of ultra-high-strength fibers[J]. Polymer Bulletin, 1984, 12(3): 195-202.
19
原添博文,白本博彬,八木和雄,等.牵拉绳索:CN88106629.X[P].1988-09-07.
20
河野安男,伊藤雄一,八木和雄.高分子量聚乙烯模塑成形的分子取向制及其制备方法:CN90107707.0[P].1990-09-11.
21
SMITH P, LEMSTRA P J. Ultra-high-stength polyethelene filaments by solution spinning/drawing[J]. Journal of Materials Science, 1980, 15(2): 505-514.
22
KALB B, PENNINGS A J. Maximum strength and drawing mechanism of hot drawn high molecular weight polyethylene[J]. Journal of Materials Science, 1980, 15(10): 2584-2590.
23
SMOOK J, PENNINGS A J. Preparation of ultra-high strength polyethylene fibers by gel-spinning/hot-drawing at high spinning rate[J]. Polymer Bulletin, 1983, 9(1): 75-80.
24
宋超,黄友光,孙艳朋.超高分子量聚乙烯纤维的制备工艺及发展概况[J].山东化工,2018,47(18):39-40.
25
杨年慈,顾白,张安秋 等.超高分子量聚乙烯的溶解研究[J].合成纤维工业,1990,13(6):27-33.
26
赵国樑.超高分子量聚乙烯纤维制备与应用技术进展[J].北京服装学院学报:自然科学版,2019,39(2):95-102.
27
杨年慈.超高分子量聚乙烯纤维 第三讲 超高分子量聚乙烯的溶解和冻胶纺丝[J].合成纤维工业,1991,14(4):50-56.
28
刘辅庭.超高强聚乙烯纤维Dyneema[J].合成纤维,2007(8):26-28.
29
大田康雄,刘辅庭.超高强度聚乙烯纤维Dyneema[J].合成纤维,2011,40(12):43-47.
30
李涛.国内外超高分子质量聚乙烯纤维的开发应用进展[J].合成纤维,2007(8):26-28.
31
SUN Y S, ZHANG X H, ZHANG Y, et al. Research on the molecular entanglement and disentanglement in the dry spinning process of UHMWPE/decalin solution[J]. Journal of Applied Polymer Science, 2006, 102(2): 864-875.
32
LEEM, CHOIMW, JEONGHM, et al. The effect of temperature and gel concentration on the rheological properties of ultra high molecular weight polyethylene (UHMWPE) in decalin[J]. Journal of Polymer Engineering, 2010, 30: 549.
33
JIAN T, SHYU W D, LIN Y T, et al. Spinning and drawing properties of ultrahigh-molecular-weight polyethylene fibers prepared at varying concentrations and temperatures[J]. Polymer Engineering & Science, 2003, 43: 1765-1777.
34
JO W H, KWON I H, SEOUL C, et al. Sol-gel transition and crystallization kinetics of ultra-high molecular weight polyethylene/decalin solution[J]. Polymer Engineering and Science, 1989, 29: 1569-1573.
35
SUN Y S, WANG Q R, LI X J, et al. Investigation on dry spinning process of ultrahigh molecular weight polyethylene/decalin solution[J]. Journal of Applied Polymer Science, 2005, 98: 474-483.
36
YEH J T, LIN Y T, JIANG H B, et al. Drawing properties of ultrahigh molecular weight polyethylene fibers prepared at varying formation temperatures[J]. Journal of Applied Polymer Science, 2003, 91: 1559-1570.
37
WANG X W, ZHENG H, SUN Y F, et al. Study on structures and properties of ultra-hot drawing UHMWPE fibers fabricated via dry spinning method[J]. Journal of Polymer Engineering, 2018, 38: 863-870.
38
HUSS-HANSEN M K, HEDLUND E, DAVYDOK A, et al. Local structure mapping of gel-spun ultrahigh-molecular-weight polyethylene fibers[J]. Polymer, 2022, 239: 124420.
39
BERGER L, KAUSCH H H, PLUMMER C J G, et al. Structure and deformation mechanisms in UHMWPE-fibres[J]. Polymer, 2003, 44: 5877-5884.
40
SAKAI Y, MIYASAKA K. Development of fibrillar texture during simultaneous biaxial drawing of ultra-high-molecular-weight polyethylene dried gels[J]. Polymer, 1990, 31: 51-57.
41
HENRY C K, PALMESE G R, ALVAREZ N J,et al. The evolution of crystalline structures during gel spinning of ultra-high molecular weight polyethylene fibers[J]. Soft Matter, 2018, 14: 8974-8985.
42
OHTA Y, MURASE H, HASHI T,Et al. Effects of spinning conditions on the mechanical properties of ultrahigh-molecular-weight polyethylene fibers[J]. Journal of Polymer Science Part B: Polymer Physics, 2005, 43: 2639-2652.
43
SUN J, BOONE M, DUNBAR J, WEEDON G. Apparatus and method to extract material from a running length of fiber: US, PCT/US86/00755[P]. 1987-09-11.
44
IZOD T P, HACKER S M, BOSE A. Method for removal of spinning solvent from spun fiber: US, 5230854[P]. 1993-07-27.
45
PENNINGS A J, ROUKEMAM, VAN DER VEEN A, et al. Further studies on the high-speed gel-spinning of ultra-high molecular weight polyethylene[J]. Polymer Bulletin, 1990, 23: 353-359.
46
PENNINGS A J, VAN DER HOOFT R J, POSTEMA A R,et al. High-speed gel-spinning of ultra-high molecular weight polyethylene[J]. Polymer Bulletin, 1986, 16: 167-174.
47
WANG H Q, LIU R, YU J R, et al. Effect of gel-spun solution concentration on the structure and properties of UHMWPE monofilaments with coarse denier[J]. Fibers and Polymers,2022, 23: 1807-1816.
48
PENNING J P, DE VRIES A A, PENNING A J,et al. The effect of fibre diameter on the drawing behaviour of gel-spun ultra-high molecular weight polyethylene fibres[J]. Polymer Bulletin, 1993, 31: 243-248.
49
AN M F, LV Y, XU H J, et al. Effect of gel solution concentration on the structure and properties of gel-spun ultrahigh molecular weight polyethylene fibers[J]. Industrial & Engineering Chemistry Research, 2016, 55: 8357-8363.
50
ZHANG Y F, XIAO C F, JIA G X, et al. Study on gel-spinning process of ultra-high molecular weight polyethylene[J]. Journal of Applied Polymer Science, 1999, 74: 670-675.
51
XIAO M M, YU J R, ZHU J J, et al. Effect of UHMWPE concentration on the extracting, drawing, and crystallizing properties of gel fibers[J]. Case Studies in Construction Materials, 2011 46: 5690-5697.
52
杨年慈,顾白,黄景红,等.萃取干燥处理对UHMW-PE冻胶丝拉伸性能的影响[J].中国纺织大学学报,1993(1):94-100.
53
刘兆峰,陈自力,于翠华,等.超高分子量聚乙烯冻胶纤维萃取干燥工艺的研究[J].合成纤维工业,1993,16(2):25-30.
54
PAKHOMOV P M, KHIZHNYAK S D, MEZHEUMOV I N, et al. Fabrication of high-strength fibers from ultrahigh-molecular-weight polyethylene[J]. Russian Journal of General Chemistry, 2017, 87: 1337-1350.
55
AN M F, XU H J, LV Y, et al. An in situ small-angle X-ray scattering study of the structural effects of temperature and draw ratio of the hot-drawing process on ultra-high molecular weight polyethylene fibers[J]. RSC Advances, 2016, 6: 51125-51134.
56
AN M F, XU H J, LV Y, et al. Structural difference of gel-spun ultra-high molecular weight polyethylene fibers affected by cold drawing process[J]. Fibers and Polymers, 2017, 18: 549-554.
57
CHEN L, DENG B, LI X K, et al. Structural evolution of UHMWPE gel fibers as high degree plasticized system during stretching: An in-situ wide and small angle X-ray scattering study[J]. Polymer, 2022, 255: 125149.
58
XIAO C F, ZHANG Y, AN S, et al. Investigation on the thermal behaviors and mechanical properties of ultrahigh molecular weight polyethylene (UHMW-PE) fibers[J]. Journal of Applied Polymer Science, 1996, 59: 931-935.
59
MCDANIEL P B, DEITZEL JOSEPH M, GILLESPIE JOHN W, et al. Structural hierarchy and surface morphology of highly drawn ultra high molecular weight polyethylene fibers studied by atomic force microscopy and wide angle X-ray diffraction[J]. Polymer, 2015, 69: 148-158.
60
XIAO C F, ZHANG Y F, AN S L, et al. Structural changes of gel drawn, ultra-high molecular weight polyethylene fibers with kerosene as a solvent[J]. Polymer Engineering & Science, 2000, 40: 238-246.
61
YU L X, BAO J N, WANG G Q, et al. Structure and properties of gel-spun ultra-high molecular weight polyethylene fibers obtained from industrial production line[J/OL]. Journal of Applied Polymer Science, 2021, 138,
62
ZHANG Q, WANG Q Z, CHEN Y, et al. Structure evolution of ultra high molecular weight polyethylene montmorillonite nanocomposite fibers prepared by melt spinning[J]. Journal of Applied Polymer Science, 2013, 130: 3930-3936.
63
QIN S X, JIN T C, ZHANG H B, et al. Optimization of hot drawing process of ultra-high molecular weight polyethylene monofilament prepared by melt spinning[J/OL]. Journal of Applied Polymer Science, 2022,
64
WANG F, LIU L C, XUE P, et al. Crystal structure evolution of UHMWPE/HDPE blend fibers prepared by melt spinning[J]. Polymers, 2017, 9: 96.
65
WANG F, LIU L C, XUE P, et al. The influence of formation temperatures on the crystal structure and mechanical properties of ultrahigh-molecular-weight polyethylene/high-density polyethylene-blend fibers prepared by melt spinning[J]. Journal of Industrial Textiles, 2019, 49: 1011-1035.
66
CHAUDHURI K, PODDAR S, POL H, et al. The effect of processing conditions on the rheological properties of blends of ultra high molecular weight polyethylene with high-density polyethylene[J]. Polymer Engineering & Science, 2018, 59: 821-829.
67
TINÇER T, COŞKUN M. Melt blending of ultra high molecular weight and high density polyethylene: The effect of mixing rate on thermal, mechanical, and morphological properties[J]. Polymer Engineering & Science, 1993, 33: 1243-1250.
68
KYU T, VADHAR P. Cocrystallization and miscibility studies of blends of ultrahigh molecular weight polyethylene with conventional polyethylenes[J]. Journal of Applied Polymer Science,1986, 32: 5575-5584.
69
YANG H Q, HUI L, ZHANG J J, et al. Effect of entangled state of nascent UHMWPE on structural and mechanical properties of HDPE/UHMWPE blends[J]. Journal of Applied Polymer Science, 2017, DOI:10.1002/app.44728.
70
TAM T Y T, AMINUDDIN N, YOUNG J A. Melt spinning blends of UHMWPE and HDPE and fibers made therefrom: US, 8057897[P]. 2011-11-15.
71
TAM T Y T, AMINUDDIN N, YOUNG J A. Melt spinning blends of UHMWPE and HDPE and fibers made therefrom: US, 8426510[P]. 2013-04-23.
72
RONCA S, ROMANO D, FORTE G, et al. Improving the performance of a catalytic system for the synthesis of ultra high molecular weight polyethylene with a reduced number of entanglements[J]. Advances in Polymer Technology, 2012, 31: 193-204.
73
ROMANO D, ANDABLO-REYES E A, RONCA S, et al. Effect of a cocatalyst modifier in the synthesis of ultrahigh molecular weight polyethylene having reduced number of entanglements[J]. Journal of Polymer Science Part A: Polymer Chemistry, 2013, 51: 1630-1635.
74
RASTOGI S, YAO Y F, RASTOGI S, et al. Unprecedented high-modulus high-strength tapes and films of ultrahigh molecular weight polyethylene via solvent-free route[J]. Macromolecules, 2011, 44: 5558-5568.
75
REIN D M, COHE Y, RONEN A, et al. Electrospinning of ultrahigh-molecular-weight polyethylene nanofibers[J]. Journal of Polymer Science Part B: Polymer Physics, 2007, 45: 766-773.
76
SMOOK J, PENNINGS A J. Suspension spinning of ultra-high molecular weight polyethylene[J]. Polymer Bulletin, 1983, 10: 291-297.
77
XIA L, XI P, CHENG B W, et al. A comparative study of UHMWPE fibers prepared by flash-spinning and gel-spinning[J]. Materials Letters, 2015, 147: 79-81.
78
WYATT T, GAINEY T, FAN X D, et al. Direct drawing of gel fibers enabled by twist-gel spinning process[J]. Polymer, 2015, 55: 1389-1395.

Comments

PDF(680 KB)

Accesses

Citation

Detail

Sections
Recommended

/