
Preparation and Performance Study of PLA Composite Films Doped with PEI-functionalized Hollow Mesoporous Silica
XIN Yu, JI Jiaqi, WANG Li, HOU Jingkui, SONG Lixin, WANG Yuanxia, LI Xianliang
Preparation and Performance Study of PLA Composite Films Doped with PEI-functionalized Hollow Mesoporous Silica
Polylactic acid (PLA) is a biodegradable polymer with good biocompatibility and biodegradability, but its poor ductility, poor air tightness and other shortcomings limit its application scope. Therefore, polyethyleneimine (PEI) modified dendritic hollow mesoporous silica microspheres (PEI-HMSN) were prepared and doped into PLA matrix by solution pouring method to prepare a composite film (PLA/PEI-HMSN). The effects of thermal, optical and hydrophobic properties of composite films were studied in detail. The results showed that PEI-HMSN can be uniformly dispersed in PLA matrix, and the elongation at break and tensile strength of PLA/PEI-HMSN composite film were improved. The hydrophobicity of PLA/PEI-HMSN composite film was improved. The PEI modified HMSN can improve the performance of PLA film, which provides an experimental basis for the application of PLA in packaging field.
PLA / Silica dioxide / Hollow structure / Polyethyleneimine / Composite film
1 |
宋志勇,马艺宁,姚倩儒,等.SiO2含量与粒径对PLA/SiO2复合膜性能的影响[J].包装工程,2021,42(21):120-126.
|
2 |
张丽媛,韦存茜,杨建平.可降解塑料在食品相关产品方面的应用及质量安全要求[J].食品安全质量检测学报,2020,11(7):2303-2308.
|
3 |
王鑫,石敏,余晓磊,等.聚己二酸对苯二甲酸丁二酯(PBAT)共混改性聚乳酸(PLA)高性能全生物降解复合材料研究进展[J].材料导报,2019,33(11):1897-1909.
|
4 |
方建波,翟光群,陈肖博,等.聚乳酸/纳米SiO2复合材料的非等温冷结晶行为[J].塑料科技,2014,42(11):91-95.
|
5 |
|
6 |
何小芳,周会鸽,刘源,等.纳米二氧化硅改性聚丙烯复合材料研究进展[J].中国塑料,2012,26(9):11-16.
|
7 |
陈廷.纳米二氧化硅改性聚乳酸/剑麻纤维复合材料的制备及表征[J].塑料科技,2020,48(11):33-36.
|
8 |
邓国宏,余立新,郝继华,等.聚乙烯醇/二氧化硅共混膜的制备及耐温、耐溶剂性能研究[J].高分子材料科学与工程,2001(6):122-125.
|
9 |
范丹丹,张凤姣,王旭巍,等.聚乙烯醇-SiO2/聚酯无纺布膜的制备及性能研究[J].水处理技术,2021,47(3):73-77.
|
10 |
WAY C,
|
11 |
|
12 |
|
13 |
|
14 |
|
15 |
|
16 |
|
17 |
|
18 |
|
19 |
|
20 |
|
21 |
|
22 |
|
23 |
|
24 |
|
25 |
|
26 |
|
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