Effect of Low Molecular Weight SAN on Fluidity and Mechanical Properties of PMMA

ZHU Congshan, ZHONG Cheng

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Plastics Science and Technology ›› 2025, Vol. 53 ›› Issue (02) : 78-81. DOI: 10.15925/j.cnki.issn1005-3360.2025.02.014
Processing and Application

Effect of Low Molecular Weight SAN on Fluidity and Mechanical Properties of PMMA

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Abstract

The study aims to investigate the effects of two different low molecular weight styrene-acrylonitrile copolymer(SAN) resins on the flow properties, mechanical performance, compatibility, transparency, and thermal stability of poly(methyl methacrylate) (PMMA). Various properties of the system were evaluated using a differential scanning calorimeter, a melt flow rate tester, an electronic universal tensile testing machine, and a Vicat heat deflection tester. The results indicate that the PMMA system with the addition of a portion of low molecular weight SAN resin exhibits only one glass transition temperature, suggesting good compatibility of the system. The incorporation of low molecular weight SAN resin can enhance the melt flowability of PMMA by more than 50%, but with minimal impact on transparency and thermal stability of the material.

Key words

Poly(methyl methacrylate) (PMMA) / Styrene-acrylonitrile copolymer (SAN) resin / Fluidity / Mechanical properties / Compatibility

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ZHU Congshan , ZHONG Cheng. Effect of Low Molecular Weight SAN on Fluidity and Mechanical Properties of PMMA. Plastics Science and Technology. 2025, 53(02): 78-81 https://doi.org/10.15925/j.cnki.issn1005-3360.2025.02.014

References

1
钱伯章.Rohm公司在中国扩大PMMA模塑复合材料生产[J].合成材料老化与应用,2022,51(2):166.
2
刘翱,黄荣奎,孟涛.改良PMMA/ASA合金材料在汽车外饰件上的应用[J].上海汽车,2021(8):56-62.
3
赵炳雄,黄技,陈志明.有机玻璃材料在海洋工程结构物的应用现状与发展趋势综述[J].机电工程技术,2023,52(9):25-30.
4
张琳,陈晓峰.PMMA有机玻璃在汽车侧三角窗上的应用研究[J].上海汽车,2013(11):56-59.
5
李文龙,郭涛.车用ASA材料的应用和研究进展[J].合成材料老化与应用,2022,51(2):88-90.
6
董鑫,刘哲,董万庆,等.ABS/PMMA合金制备及性能[J].化工科技,2019,27(3):61-64.
7
陈丹,任亮,兰苗宇,等.PMMA/SAN/ABS共混物的结构与性能研究[J].塑料工业,2015,43(2):27-30.
8
游新明,吴跃焕,王唐晶,等.高光白色耐刮擦耐候免喷漆PMMA+ASA材料的制备及性能研究[J].上海塑料,2023,51(1):54-59.
9
陶永亮,黄登懿,陈曦.PMMA/ASA合金材料在汽车零件中的应用[J].上海塑料,2020(1):41-45.
10
XU Y, QIN J X, SHEN J B, et al. Scratch behavior and mechanical properties of alternating multi-layered PMMA/PC materials[J]. Wear, 2021, 486/487: 204069.
11
邹永昆,余彪,郭森,等.高光泽抗划伤聚碳酸酯/聚甲基丙烯酸甲酯复合材料的制备与性能研究[J].化工新型材料,2020,48(12):77-80.
12
BUBMANN T, SEIDEL A, RUCKDASCHEL H, et al. Transparent PC/PMMA blends with enhanced mechanical properties via reactive compounding of functionalized polymers[J]. Polymers (Basel), 2021, 14(1): 55-60.
13
DARO A, ZABEAU F, DAVID C. Degradation of polymer blends—Ⅲ. Radiolysis of blends of poly(methyl methacrylate) with styrene-acrylonitrile copolymers[J]. European Polymer Journal, 1989, 25(1): 71-74.
14
董文飞,张万喜.裂解型聚合物的辐射改性机理及方法[J].高分子材料科学与工程,2000(6):18-23.
15
王国成,尚晓艳,蒋涛,等.提高PMMA塑料光纤芯材耐热性的方法[J].胶体与聚合物,2006(2):37-38.
16
HOLLAND B J, HAY J N. The effect of polymerisation conditions on the kinetics and mechanisms of thermal degradation of PMMA[J]. Polymer Degradation and Stability, 2002, 77(3): 435-439.
17
FERRIOL M, GENTILHOMME A, COCHEZ M, et al. Thermal degradation of poly(methyl methacrylate) (PMMA): Modelling of DTG and TG curves[J]. Polymer Degradation and Stability, 2003, 79(2): 271-281.
18
曹春雷,谭志勇,葛彦侠,等.PMMA、PS和SAN的热稳定性比较研究[J].中国塑料,2007(8):20-23.
19
洪重奎,金敏善,黄英超,等.不同组成ABS对ABS/PMMA合金性能的影响[J].中国塑料,2003(7)3.
20
FOWLER M E, BARLOW J W, PAUL D R. Kinetics of adhesion development at PMMA-SAN interfaces[J]. Polymer, 1987, 28(12): 2145-2150.
21
SUESS M, KRESSLER J, KAMMER H W. The miscibility window of poly(methylmethacrylate)/poly(styrene-co-acrylonitrile) blends[J]. Polymer, 1987, 28(6): 957-960.
22
KUMARASWAMY G N, RANGANATHAIAH C, URS M V D, et al. Miscibility and phase separation in SAN/PMMA blends investigated by positron lifetime measurements[J]. European Polymer Journal, 2006, 42(10): 2655-2666.
23
KOZŁOWSKI S, LIPIŃSKA M, SLOUF M, et al. The implication of PMMA molecular weight on compatibility of SAN/PMMA blends containing GO-g-PMMA hybrid compatibilizers[J]. Materials Today Communications, 2023, 37: 107393.
24
CAMERON N, COWIE J M G, FERGUSON R, et al. Transition from miscibility to immiscibility in blends of poly(methyl methacrylate) and styrene-acrylonitrile copolymers with varying copolymer composition: A DSC study[J]. European Polymer Journal, 2002, 38(3): 597-605.
25
彭懋.PMMA/SAN共混物相分离及聚合物水凝胶非均匀聚合的光散射/折射研究[D]:杭州:浙江大学,2001.
26
ZHENG Q, DU M, YANG B B, et al. Relationship between dynamic rheological behavior and phase separation of poly(methyl methacrylate)/poly(styrene-co-acrylonitrile) blends[J]. Polymer, 2001, 42(13): 5743-5747.
27
王邦达,强晓莲.PMMA/SAN共混物相分离温度的确定:几种流变学方法的比较[J].塑料科技,2014,42(6):40-43.
28
ZHONG J, ZHANG X, YU X, et al. Selective distribution of silica grafted with crosslinked poly(methyl methacrylate) in poly(methyl methacrylate)/poly (styrene-co-acrylonitrile) blend[J]. Polymer, 2023, 282: 126154.
29
ILCIKOVA M, GALEZIEWSKA M, KOLARIK R, et al. Influence of PMMA brushes grafted from GO on rheological properties of PMMA/SAN immiscible blend in shear and elongation flow[J]. Polymer, 2023, 279: 126015.
30
ZHANG X, ZHANG H, ZUO M, et al. Effects of selective distribution and migration of poly(methyl methacrylate)-grafted nanoclays on the phase behavior of poly(methyl methacrylate)/poly(styrene-co-acrylonitrile) blends[J]. Polymer, 2022, 252: 124965.

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