Preparation and Characterization of Semi-aromatic Polyester Amide by One-pot Method

XIAO Liwen, LIU Tao, CHENG Kan, NIU Fangfang, ZHU Jianghao, XIA Yumin, WANG Xueli, HE Yong

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Plastics Science and Technology ›› 2025, Vol. 53 ›› Issue (01) : 22-27. DOI: 10.15925/j.cnki.issn1005-3360.2025.01.004
Theory and Research

Preparation and Characterization of Semi-aromatic Polyester Amide by One-pot Method

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Abstract

In order to develop highly hygroscopic modified polyester fibers, 6-amino-1-hexanol and terephthalic acid (PTA) were used as monomers, and titanium tetra-n-butoxide was used as a melt polymerization catalyst. The high molecular weight semi-aromatic polyester amides P6T6T and P6T were synthesized by a two-step feeding one-pot method and a one-step feeding one-pot method, respectively. The chemical structures, thermal properties, crystallization properties and hydrophilic properties of P6T6T and P6T were evaluated. The results showed that the different feeding methods led to certain differences in the structure and properties of P6T6T and P6T. The melting points of P6T6T and P6T were 220 ℃ and 217 ℃ respectively, the glass transition temperatures were 88 ℃ and 85 ℃ respectively, the 5% weight loss thermal decomposition temperatures were 380 ℃ and 375 ℃ respectively, and the saturated water absorption rates were 2.72% and 3.49% (about 3 to 4 times that of PET) respectively. The results indicate that both P6T6T and P6T have excellent thermal and hydrophilic properties, which are not only suitable for engineering plastics, but also have the potential to be developed into highly hygroscopic fibers.

Key words

Semi-aromatic polyesteramide / 6-amino-1-hexanol / Melt polymerization / Hydrophilicity

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XIAO Liwen , LIU Tao , CHENG Kan , et al . Preparation and Characterization of Semi-aromatic Polyester Amide by One-pot Method. Plastics Science and Technology. 2025, 53(01): 22-27 https://doi.org/10.15925/j.cnki.issn1005-3360.2025.01.004

References

List( Publishing order | Descend order by publishing year | Descend order by cited within ) Chart analysis
1
虞小三,王鸣义.亲水改性聚酯纤维的生产技术现状及市场前景[J].合成纤维工业,2020,43(1):60-66.
本文引用 [1]
2
KETEMA A, WORKU A. Review on intermolecular forces between dyes used for polyester dyeing and polyester fiber[J]. Journal of Chemistry, 2020, 2020: 6628404.
3
陈彬霞,周泽航,卢灿辉.等离子体辐照亲水改性再生聚酯纤维及其结构演变[J].高分子材料科学与工程,2022,38(1):43-49, 56.
本文引用 [1]
4
王新,王进美,周娅楠.涤纶表面亲水改性研究进展[J].合成纤维,2021,50(7):27-30.
本文引用 [1]
5
YAN Y, GOONEIE A, YE H, et al. Morphology and crystallization of biobased polyamide 56 blended with polyethylene terephthalate[J]. Macromolecular Materials and Engineering, 2018, 303(9): 1800214.
6
王晨,李圣军,孙燕琳,等.PET共聚改性研究进展[J].合成纤维,2024,53(5):1-8.
7
刘荣利,樊国栋.乳酸基聚酯酰胺聚合物的合成及表征研究[J].塑料科技,2014,42(1):88-92.
8
张腾飞,石禄丹,胡红梅,等.生物基聚酰胺56低聚物改性聚酯的合成及其表征[J].纺织学报,2019,40(6):1-7.
9
李建武,江振林,王朝生,等.多元醇改性亲水共聚酯纤维的结构与性能[J].东华大学学报:自然科学版,2017,43(3):335-340, 351.
10
于海龙,纪晓寰,方彦雯,等.PET聚酯表面改性技术应用进展[J].聚酯工业,2021,34(6):1-8.
11
亓晓杰,孙莉娜,廖海洋,等.超柔软高吸湿改性聚对苯二甲酸乙二醇酯纤维的制备及其性能[J].纺织学报,2023,44(9):27-34.
本文引用 [1]
12
杨明霞,陈行,邹岸格.超仿棉仪纶混纺纱的性能对比分析[J].纺织科学与工程学报,2018,35(3):5-8.
本文引用 [1]
13
QI M Y, ZHENG L C, LI C C, et al. The yellowing mechanism of polyesteramide based on poly(ethylene terephthalate) and polyamide 6[J]. Journal of Applied Polymer Science, 2021, 138(10): 49986.
14
HAN S Y, WU J. Recent advances of poly(ester amide)s-based biomaterials[J]. Biomacromolecules, 2022, 23(5): 1892-1919.
本文引用 [1]
15
RANGANATHAN P, CHEN C W, RWEI S P, et al. Methods of synthesis, characterization and biomedical applications of biodegradable poly(ester amide)s—A review[J]. Polymer Degradation and Stability, 2020, 181: 109323.
本文引用 [1]
16
WINNACKER M, RIEGER B. Poly(ester amide)s: Recent insights into synthesis, stability and biomedical applications[J]. Polymer Chemistry, 2016, 7(46): 7039-7046.
17
DIRAUF M, MULJAJEW I, WEBER C, et al. Recent advances in degradable synthetic polymers for biomedical applications—Beyond polyesters[J]. Progress in Polymer Science, 2022, 129: 101547.
18
刘诗乐,李陈郭,赵京波,等.基于己内酰胺和乙醇胺的聚酯酰胺合成及表征[J].高分子学报,2012(1):33-40.
19
高晗,徐军,胡欣,等.聚酯酰胺的合成[J].化学进展,2018,30(11):1634-1645.
本文引用 [1]
20
GAO H W, LIU H H, HE J M, et al. Synthesis and properties of poly(ethylene terephthalate) modified with a small amount of 1,10-decanediamine and hydrogen bonds[J]. Journal of Materials Science, 2021, 56(7): 4922-4939.
本文引用 [3]
21
何廷伟,毛磊,高远博,等.一种新型交替结构的聚酯酰胺合成与性能表征[J].塑料工业,2020,48(12):12-16, 74.
本文引用 [1]
22
KLUGE M, RENNHOFER H, LICHTENEGGER H C, et al. Poly(ester amide)s from poly(alkylene succinate)s and rapid crystallizing amido diols: Synthesis, thermal properties and crystallization behavior[J]. European Polymer Journal, 2020, 129: 109622.
23
黄超群,徐少轶,赵京波,等.由对苯二甲酰胺二醇合成聚酯酰胺及其扩链反应的研究[J].高分子学报,2010(2):237-244.
24
祝爱兰.聚酯酰胺的应用及合成研究[J].聚酯工业,2014,27(1):6-9, 17.
本文引用 [1]
25
KLONOS P A, KLUGE M, ROBERT T, et al. Molecular dynamics, crystallization and hydration study of poly(propylene succinate) based poly(ester amide)s[J]. Polymer, 2020, 186: 122056.
本文引用 [1]
26
KLUGE M, BIKIARIS D N, ROBERT T. Enhancing the properties of poly(propylene succinate) by the incorporation of crystallizable symmetrical amido diols[J]. European Polymer Journal, 2019, 120: 109195.
27
NGUYEN T H N, BALLIGAND F, BORMANN A, et al. Synthesis of new biobased linear poly(ester amide)s [J]. European Polymer Journal, 2019, 121: 109314.
28
HE T W, LIU T, HUANG J Y, et al. Correction to: Synthesis of alternating semi-aromatic poly(ester amide)s and the amide transesterification[J]. Journal of Polymer Research 2022, 29(4): 132.
29
FEY T, HOELSCHER M, KEUL H, et al. Alternating poly(ester amide)s from succinic anhydride and α,ω-amino alcohols: Synthesis and thermal characterization[J]. Polymer International, 2003, 52(10): 1625-1632.
本文引用 [1]
30
DONELLI I, TADDEI P, SMET P F, et al. Enzymatic surface modification and functionalization of PET: A water contact angle, FTIR, and fluorescence spectroscopy study[J]. Biotechnology and Bioengineering, 2009, 103(5): 845-856.
本文引用 [1]

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