Research Progress in Preparation of Spherical Ethoxylated Magnesium Carriers

GAQ Jing-jie, CHEN Zi-qi, REN He-gang

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Plastics Science and Technology ›› 2024, Vol. 52 ›› Issue (12) : 135-139. DOI: 10.15925/j.cnki.issn1005-3360.2024.12.026
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Research Progress in Preparation of Spherical Ethoxylated Magnesium Carriers

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Abstract

The carrier of ethoxylmagnesium [Mg(OEt)2] is characterized by a simple preparation process, adjustable particle size and high sphericity. The Mg(OEt)2 carrier Ziegler-Natta catalyst has many advantages, such as high activity, good hydrogen regulation sensitivity, good stereoregulation and strong copolymerization ability, which has been an important part of polyolefin catalyst research. In this paper, the preparation methods, preparation mechanism and factors affecting the preparation of Mg(OEt)2 spherical carrier in recent decades were reviewed. The effects of feeding mode, feeding ratio and reaction temperature and main raw material on the morphology and particle size distribution of Mg(OEt)2 were emphatically introduced, and the development trend of industrial Mg(OEt)2 carrier in preparation process optimization and development in the future was prospected in order to improve the competitiveness of polyolefin catalysts in China.

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Ethoxylated magnesium / Carrier / Catalyst / Polyolefin

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GAQ Jing-jie , CHEN Zi-qi , REN He-gang. Research Progress in Preparation of Spherical Ethoxylated Magnesium Carriers. Plastics Science and Technology. 2024, 52(12): 135-139 https://doi.org/10.15925/j.cnki.issn1005-3360.2024.12.026

References

List( Publishing order | Descend order by publishing year | Descend order by cited within ) Chart analysis
1
任合刚,韦德帅,王登飞,等.有机载体催化剂催化乙烯聚合研究[C]//第十五届全国工业催化技术及应用年会论文集.丹东:全国工业催化信息站,工业催化杂志社,2018.
本文引用 [2]
2
邹盛欧.茂金属催化剂的开发及应用[J].塑料科技,1997(4):45-50.
本文引用 [1]
3
周兵.高结晶聚丙烯HC9012M的开发[J].塑料科技,2009,37(12):42-45.
本文引用 [1]
4
苟清强,俸艳芸,杨红旭,等.载体对乙烯淤浆聚合用Ziegler-Natta催化剂的影响[J].合成树脂及塑料,2016,33(2):10-13.
5
王巍.乙氧基镁催化剂粉末粒度及粒度分布测定的研究[J].辽宁化工,2007(5):325-326, 342.
6
高金龙,张眉,王勇,等.载体活化方式对高性能聚丙烯催化剂性能的影响研究[J].合成材料老化与应用,2024,53(1):42-44.
7
郎旭东,周奇龙,徐秀东,等.烷氧基镁载体及其制备聚烯烃催化剂的研究进展[J].石油化工,2022,51(8):976-981.
本文引用 [3]
8
BEHROUZI F M, NEMATI K A, SHAKERI A. Modified mesoporous magnesium ethoxide with spherical morphology for polypropylene Ziegler-Natta catalyst: Preparation and characterization[J]. Journal of Inorganic and Organometallic Polymers and Materials, 2020, 30(7): 2582-2590.
本文引用 [1]
9
LAN Z, LU Y C. Tailoring morphology and bulk density of magnesium ethoxide particles by adding n-hexane and silicone oil[J]. Particuology, 2020, 53: 168-174.
本文引用 [1]
10
KHERADMAND A, ABADI A R S, KHORASHEH F, et al. Preparation and study of bi-supported Ziegler-Natta catalyst with nano graphene oxide and magnesium ethoxide supports for polymerization of polyethylene[J]. Polymer Science Series B, 2016, 58(3): 271-277.
本文引用 [2]
11
FUNAKO T, CHAMMINGKWAN P, TANIIKE T, et al. Alternation of pore architecture of Ziegler-Natta catalysts through modification of magnesium ethoxide: Alternation of pore architecture of Ziegler-Natta catalysts[J]. Macromolecular Reaction Engineering, 2015, 9(4): 325-332.
12
CHAMMINGKWAN P, TERANO M, TANIIKE T. High-throughput synthesis of support materials for olefin polymerization catalyst[J]. ACS Combinatorial Science, 2017,19(5): 331-342.
13
TANIIKE T, FUNAKO T, TERANO M. Multilateral characterization for industrial Ziegler-Natta catalysts toward elucidation of structure performance relationship[J]. Journal of Catalysis, 2014, 311: 33-40.
本文引用 [1]
14
梁云,杨阳,李颖,等.烯烃聚合用烷氧基镁负载型催化剂研究进展[J].合成树脂及塑料,2021,38(3):53-58.
本文引用 [2]
15
NOMURA H, KURIHARA S, HIGUCHI K. Synthesis of spherical magnesium alcoholate having narrow paticle size distribution: JPH0374341(A)[P].1991-03-28.
本文引用 [1]
16
UDOO H, TOMAASU Y, KURAUSUUDEIITAA K, et al. Preparation of spherical particle of magnesium alkoxide: JPH0687773(A)[P]. 1994-03-29.
本文引用 [1]
17
ROBAATO C J, DANIERU P J J, JIYON K C. Magnesium alkoxide alkanol solution for preparation of catalyst, its preparation and production of solid spherical particle for preparation of catalyst from same: JPH0641220(A)[P]. 1994-02-15.
本文引用 [1]
18
JIYON K S, YAKOBU K B. Manufacture of spherical magnesium alkoxide particle: JPH62051633(A)[P]. 1987-03-06.
本文引用 [1]
19
谭忠,徐秀东,严立安,等.烷氧基镁固体颗粒的制造方法:CN101906017A[P].2010-12-08.
本文引用 [1]
20
徐秀东,谭忠,毛炳权.二烷氧基镁制备技术的进展[J].化工新型材料,2010,38(9):45-49.
21
杨阳,梁云,郭子芳,等.聚乙烯催化剂用烷氧基镁载体的研究进展[J].石油化工,2021,50(3):280-284.
22
TANASE S, KATAYAMA K, INASAWA S, et al. Particle growth of magnesium alkoxide as a carrier material for polypropylene polymerization catalyst[J]. Applied Catalysis A: General, 2008, 350: 197-206.
本文引用 [1]
23
许景琦,刘海涛,高明智.Ziegler-Natta催化剂载体的研究进展[J].合成树脂及塑料,2020,37(4):85-90.
24
朴准励,张豪植,安振圭.烯烃聚合催化剂用球形载体的制备方法:CN101027327A[P].2007-08-29.
25
朴准励,张豪植,金上热,等.用于丙烯聚合的催化剂和使用该催化剂的丙烯聚合方法:CN101056894A[P].2007-10-17.
本文引用 [1]
26
张豪植,杨春柄.聚合和共聚烯烃的方法:CN101421316A[P].2009-04-29.
27
棚濑省二朗,贞岛孝典,船桥英雄,等.镁化合物、烯烃聚合用固体催化剂成分、烯聚合用催化剂以及聚烯烃的制备方法:CN1656050A[P].2005-08-10.
本文引用 [3]
28
棚濑省二朗,贞岛孝典,薮内伸浩,等.烯烃聚合用固体催化剂成分、烯烃聚合用催化剂及烯烃聚合物的制造方法:CN1653092A[P].2005-08-10.
29
薮乃内伸浩,贞岛孝典.烯烃聚合用催化剂和制备烯烃聚合物的方法:CN1735632A[P].2006-02-15.
本文引用 [2]
30
棚濑省二朗,贞岛孝典.烯烃聚合用固体催化剂成分、烯烃聚合用催化剂及烯烃聚合物的制备方法:CN1575304A[P].2005-02-02.
本文引用 [4]
31
任合刚,张瑞,白鹏,等.MgCl2-SiO2复合载体型Ziegler-Natta乙烯催化剂[J].合成树脂及塑料,2011,40(7):732-736.
本文引用 [1]
32
赵海英,王喆,李伟,等.一种复合载体丙烯聚合催化剂的研究[J].高分子通报,2005,15(1):77-81.
33
张磊,王世波,周俊领,等.高活性高氢调性能乙烯聚合用Ziegler-Natta催化剂[J].石油化工,2016,45(8):936-939.
本文引用 [1]
34
伞晓广,李三,魏桂君,等.以镁粉为原料的高效载体催化剂[J].合成树脂及塑料,2006,23(2):16-23.
本文引用 [1]
35
赵晓君.大颗粒乙氧基镁的制备方法研究[J]当代化工研究,2018(3):153-154.
本文引用 [1]
36
程璐.烷氧基镁载体负载型Ziegler-Natta催化剂的制备和催化乙烯聚合的研[D].北京:北京化工大学,2014.
本文引用 [2]
37
HIDEO F, AKINOBU S, AKIRA T, et al. Catalyst component for olefin polymerization and process for producing polyolefins: US5556820A[P]. 1996-09-17.
本文引用 [1]
38
SHOHJIRO T, NOBUHIRO Y, TAKEHITO K, et al. Magnesium compound, catalyst for olefin polymerization, and method for producing olefin polymer: WO2005102973[P]. 2005-04-19.
本文引用 [2]
39
义建军,高克京,黄启谷,等.用于烯烃聚合催化剂的烷氧基镁载体的制备:CN105713116A[P].2016-06-09.
40
韩晓昱,徐人威,王雄,等.一种球形烷氧基镁颗粒及其制备方法:CN111100218A[P].2020-05-05.
本文引用 [1]
41
王帆.电池隔膜专用料特高分子量聚乙烯及其高效ziegler-Natta催化剂的研究[D].北京:北京化工大学,2018.
本文引用 [1]
42
BEPPU A, KOBAYASHI H. Production of spherical fine particulate magnesium ethylate: JPH0873388(A)[P].1996-03-19.
43
JOSEPH J, SINGH S C, GUPTA V K. Morphology controlled magnesium ethoxide:Influence of reaction parameters and magnesium characteristics[J]. Particulate Science and Technology, 2009, 27(6): 528-541.
本文引用 [2]
44
王立才,李伟,郑国彤,等.一种乙氧基镁改性载体及其制备的齐格勒纳塔催化剂:CN106749779A[P].2019-06-28.
本文引用 [1]
45
李化毅,王如秀,李倩,等.一种球形二乙氧基镁的制备方法:CN112299984[P].2021-02-02.
本文引用 [2]
46
WADA T, FUNAKO T, CHAMMINGKWAN P, et al. Structure-performance relationship of Mg(OEt)2-based Ziegler-Natta catalysts[J]. Journal of Catalysis, 2020, 389: 525-532.
本文引用 [3]
47
HONGMANEE G, CHAMMINGKWAN P, TANIIKE T, et al. Probing into morphology evolution of magnesium ethoxide particles as precursor of Ziegler-Natta catalysts[J]. Polyolefins Journal, 2016, 3(1): 47-57.
本文引用 [1]
48
张宁波,郭子芳,梁云,等.烷氧基镁载体结构与性能的影响因素[J].石油化工,2023,52(3):317-324.
本文引用 [2]
49
TOSHIAKI F, PATCHANEE C, TOSHIAKI T, et al. Addition of a second alcohol in magnesium ethoxide synthesis as a way to vary the pore architecture of Ziegler-Natta catalysts[J]. Polyolefins Journal, 2015, 2(2): 65-71.
本文引用 [2]
50
CHAMMINGKWAN P, WANNABORWORN M, MAI L, et al. Particle engineering of magnesium ethoxide-based Ziegler-Natta catalyst through post-modification of magnesium ethoxide[J]. Applied Catalysis A: General, 2021, DOI: 10.1016/j.apcata.2021.118337.
本文引用 [2]
51
KIM E I, LEE Y J, JUNG H C, et al. Method of preparation of spherical support for olefin polymerization catalyst: WO2009084799[P]. 2009-07-09.
本文引用 [1]
52
徐群,张广斌,孙东风.聚乙烯催化剂及其制备方法:CN101220113A[P].2008-07-16.
本文引用 [1]
53
金银一,金钟式,李泳周,等.用于烯烃聚合催化剂的二烷氧基镁载体的生产方法,烯烃聚合催化剂生产方法及烯烃聚合法:CN101891846A[P].2010-11-24.
本文引用 [1]
54
王伟.以Mg(OEt)2为前体的聚丙烯催化剂的制备研究[D].大连:大连理工大学,2012.
本文引用 [1]
55
高天翔.以Mg(OEt)2为载体前体丙烯气相聚合催化剂的研制[D].大连:大连理工大学,2014.
本文引用 [1]

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