Study on Preparation and Properties of PVC/Zinc Stannate Composites

HE Jin, WANG Zhen-wu, LUO Qiong-lin, LIU Bo-han, OUYANG Yue-jun, SHU You

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Plastics Science and Technology ›› 2024, Vol. 52 ›› Issue (12) : 85-88. DOI: 10.15925/j.cnki.issn1005-3360.2024.12.016
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Study on Preparation and Properties of PVC/Zinc Stannate Composites

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Abstract

Two kinds of PVC/Zn2SnO4 composites were prepared by melt blending extrusion method using two kinds of zinc stannate (Zn2SnO4) with different particle sizes as flame retardant with calcium-zinc stabilizers and dioctyl phthalate for modification of polyvinyl chloride (PVC) materials. The mechanical properties, flame retardancy and anti-voltage breakdown performance of composites were investigated by a tensile tester, a limiting oxygen index (LOI) tester and a voltage breakdown tester. The results showed that the tensile strength and LOI of the composites increased as the increase of Zn2SnO4-1 and Zn2SnO4-2 adding amount. The elongation at break of the composites first increased and then decreased as the increase of Zn2SnO4-2 adding amount, which reached the maximum value when the adding amount of Zn2SnO4-2 was 2 phr. The LOI, tensile strength and voltage breakdown strength of the PVC/Zn2SnO4-2 composites were higher than that of PVC/Zn2SnO4-1 composites.

Key words

Zinc stannate / Flame retardancy / PVC

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HE Jin , WANG Zhen-wu , LUO Qiong-lin , et al . Study on Preparation and Properties of PVC/Zinc Stannate Composites. Plastics Science and Technology. 2024, 52(12): 85-88 https://doi.org/10.15925/j.cnki.issn1005-3360.2024.12.016

References

1
SUN H W, LUO Z, YU J, et al. Study on modifying the compression set of plasticized poly (vinyl chloride) by epoxy resin and post-heat treatment[J]. Journal of Polymer Research, 2012, 19: 1135-1142.
2
李佳宇.电线电缆用聚氯乙烯复合材料的阻燃性能和力学性能研究[J].塑料科技,2023,51(11):65-68.
3
徐瑶,沈文涛,许苗军.Mo-MOF对软质PVC材料的阻燃及抑烟性能[J].塑料,2024,53(1):18-22.
4
邓克文,彭鹤松,吴维冰,等.超细氢氧化镁在硬质PVC阻燃板材中的应用[J].工程塑料应用,2022,50(6):149-153, 158.
5
曾书航,裴丰,郭忠,等.氢氧化镁阻燃剂的制备及其在塑料领域中的应用研究进展[J].塑料科技,2023,51(6):107-111.
6
严兵.高阻燃聚氯乙烯电缆料的制备及应用研究[D].苏州:苏州大学,2015.
7
李健.纳米羟基锡酸钙的合成及其在聚氯乙烯中的阻燃性能研究[D].保定:河北大学,2023.
8
杜育峰.阻燃PVC复合材料的制备及其性能表征[D].兰州:西北师范大学,2023.
9
高伟杰.阻燃聚氯乙烯研究进展及在工程中的应用[J].合成材料老化与应用,2019,48(5):132-136.
10
张乐.阻燃、低烟软质聚氯乙烯的制备与性能研究[D].北京:北京化工大学,2015.
11
马万里,薛泓林.改性聚氯乙烯电缆材料防火性能和防腐蚀性能的研究[J].塑料科技,2020,48(10):29-32.
12
杨文才,岳英龙,郑乃涛.空心玻璃微珠对PVC复合材料保温性能的影响[J].塑料科技,2022,50(4):28-31.
13
胥晶,吴木根,陈昕航,等.绝缘性塑料材料在电气电缆的应用研究[J].塑料科技,2022,50(3):109-112.
14
张彩.阻燃绝缘型PVC塑料的热学性能和力学性能分析[J].塑料科技,2023,51(6):29-32.
15
孙英娟,宋京朔,刘岩辉.粉煤灰/三氧化二锑对软质聚氯乙烯阻燃消烟作用研究[J].塑料科技,2022,50(1):40-44.
16
孙英娟,岳丽娜,张晓茜,等.炼铁矿渣在聚氯乙烯阻燃消烟中的作用[J].塑料,2019,48(2):27-31.
17
赵胜利,黄金田.三氧化二锑的表面改性及其在软质PVC中的应用研究[J].塑料科技,2014,42(1):124-127.
18
张杰,白仁斗,李伟.锡系化合物在高分子材料中的阻燃抑烟研究进展[J].云南化工,2023,50(11):16-19.
19
薛正言.羟基锡酸盐、锡酸盐的结合能、键解离能与其在PVC中阻燃性能的相关性研究[D].保定:河北大学,2023.
20
印鑫.钙锌稳定剂P1129-1替代逆酯硫醇锡在PVC工业管中的应用[J].塑料助剂,2022(2):5-8, 32.
21
胡伟东,赵贺,焦运红,等.羟基锡酸钴在软质聚氯乙烯中的高效阻燃消烟作用[J].复合材料学报,2019,36(9):2067-2075.
22
CHENG L Y, WU W H, MENG W H, et al. Application of metallic phytates to poly(vinyl chloride) as efficient biobased phosphorous flame retardants[J]. Journal of Applied polymer Science, 2018, DOI: 10.1002/app.46601.
23
胡伟东,赵贺,焦运红,等.羟基锡酸钴在软质聚氯乙烯中的高效阻燃消烟作用[J].复合材料学报,2019,36(9):2067-2075.
24
甄凤.阻燃耐高温PVC管材的制备及其应用研究[J].塑料科技,2023,51(3):59-62.
25
蒋巍,李金凤,张晓岩.阻燃涤纶织物和毛织物及其混纺试样的性能研究[J].毛纺科技,2021,49(4):37-40.

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