Research on Toughening Modification of PLA/ABS

CHEN Ting, CAO Chang-lin, WANG Yang-tao, ZHANG Qing-hai, WANG Xiao-jun, LU Xin

PDF(2965 KB)
PDF(2965 KB)
Plastics Science and Technology ›› 2024, Vol. 52 ›› Issue (11) : 37-42. DOI: 10.15925/j.cnki.issn1005-3360.2024.11.007
Theory and Research

Research on Toughening Modification of PLA/ABS

Author information +
History +

Abstract

By utilizing four different types of typical compatibilizers and dicumyl peroxide (DCP), toughening modification was performed on the blend system of polylactic acid/acrylonitrile-butadiene-styrene copolymer (PLA/ABS). The compatibility and crystallization properties of the blend system were characterized and tested through mechanical property tests, scanning electron microscopy (SEM), and differential scanning calorimetry (DSC). The results showed that the addition of compatibilizers could form a better dispersed "sea-island" phase structure in the blend system, with the tensile strength and impact strength increasing by up to 18.23% and 21.98%, respectively, although the crystallization capability decreased. With the addition of both compatibilizers and DCP, the phase structure of the blend system transformed into coexisting "sea-island" and "sea-sea" phases, with the maximum increases in tensile strength and impact strength of 47.99% and 86.64%, respectively. The compatibilizers and DCP synergistically enhanced the toughening effect on the blend system and improved its crystallization capability.

Key words

PLA / ABS / Synergistic compatibility

Cite this article

Download Citations
CHEN Ting , CAO Chang-lin , WANG Yang-tao , et al . Research on Toughening Modification of PLA/ABS. Plastics Science and Technology. 2024, 52(11): 37-42 https://doi.org/10.15925/j.cnki.issn1005-3360.2024.11.007

References

1
KERVRAN M, VAGNER C, COCHEZ M, et al. Thermal degradation of polylactic acid (PLA)/polyhydroxybutyrate (PHB) blends: A systematic review[J]. Polymer Degradation and Stability, 2022, DOI: 10.1016/j.polymdegradstab.2022.109995.
2
LI Y J, SHIMIZU H. Improvement in toughness of poly(L-lactide) (PLLA) through reactive blending with acrylonitrile-butadiene-styrene copolymer (ABS): Morphology and properties[J]. European Polymer Journal, 2009(45): 738-746.
3
CARRASCO F, SANTANA O O, CAILLOUX J, et al. Thermal degradation of poly(lactic acid) and acrylonitrilebutadiene-styrene bioblends: Elucidation of reaction mechanisms[J]. Thermochimica Acta, 2017, 654: 157-167.
4
RAMANJANEYULU B, VENKATACHALAPATHI N, PRASANTHI G. Thermal and mechanical properties of PLA/ABS/TCS polymer blend composites[J]. Journal of the Institution Engineers (India): Series C, 2021, 102: 799-806.
5
LI Y, SHIMIZU H. Improvement in toughness of poly (L-lactide) (PLLA) through reactive blending with acrylonitrilebutadiene-styrene copolymer (ABS): Morphology and properties [J]. European Polymer Journal, 2009, 45(3): 738-746.
6
JO M Y, RYU Y J, KO J H, et al. Effects of compatibilizers on the mechanical properties of ABS/PLA composites[J]. Journal of Applied Polymer Science, 2012, DOI: 10.1002/APP.36732.
7
杨丽双,陈向文.ABS/PLA合金的制备及力学性能研究[J].塑料科技,2016,44(11):63-67.
8
JO M Y, RYU Y J, KO J H, et al. Effects of compatibilizers on the mechanical properties of ABS/PLA composites[J]. Journal of Applied Polymer Science, 2012, 125: E231-E238.
9
SUN S L, ZHANG M Y, ZHANG H X, et al. Polylactide toughening with epoxy-functionalized grafted acrylonitrile-butadiene-styrene particles[J]. Journal of Applied Polymer Science, 2011, 122: 2992-2999.
10
DE MATOS COSTA A R, BARRETO LUNA C B, PEREIRA DO NASCIMENTO E, et al. Tailoring PLA/ABS blends compatibilized with SEBS-g-MA through annealing heat treatment[J]. Polymers, 2023, DOI: 10.3390/polym15163434.
11
李连明,刘洋,邹俊.相容剂增容改性对ABS/PLA合金及其结构性能的研究[J].塑料工业,2019(47):142-145.
12
马丽,丁井鲜,余圣,等.PLA/ABS复合材料的制备与性能研究[J].塑料科技,2022,50(3):9-12.
13
贾仕奎,王忠,朱艳,等.原位增强PLA/PBS合金的微观形态及力学性能研究[J].塑料工业,2016(44):32-36.
14
周庭,胡晶莹,周涛,等.过氧化物对PBS/PLA共混物反应性增容研究[J].塑料工业,2012(4):96-98, 114.
15
陈宁,汪文俊,单鹏嘉,等.DCP对生物基单体原位聚合增韧聚乳酸效果的影响[J].包装工程,2020(41):51-59.
16
SEMBA T, KITAGAWA K, ISHIAKU U S, et al. Effect of compounding procedure on mechanical properties and dispersed phase morphology of poly(lactic acid)/polycaprolactone blends containing peroxide[J]. Journal of Applied Polymer Science, 2007, 103(2): 1066-1074.
17
曹宏伟,杨荣,李锦春.过氧化二异丙苯硫化制备增强耐热聚乳酸[J].高分子材料科学与工程,2021(37):58-65.
18
CHOE I J, LEE J H, YU J H, et al. Mechanical properties of acrylonitrile-butadiene-styrene copolymer/poly(L-lactic acid) blends and their composites[J]. Journal of Applied Polymer Science, 2014, DOI: 10.1002/app.40329.
19
LIU G C, HE Y S, ZENG J B, et al. Fully biobased and supertough polylactide-based thermoplastic vulcanizates fabricated by peroxide-induced dynamic vulcanization and interfacial compatibilization[J]. Biomacromolecules, 2014, DOI: 10.1021/bm5012739.
20
赵振伦.ABS动态硫化改性技术研究[D].天津:天津科技大学,2012.
21
YUAN D S, CHEN Z H, XU C H, et al. Fully biobased shape memory material based on novel cocontinuous structure in poly(lactic acid)/natural rubber TPVs fabricated via peroxide-induced dynamic vulcanization and in situ interfacial compatibilization[J]. ACS Sustainable Chemistry Engineering, 2015, 3: 2856-2865.
22
WU N J, ZHANG H, FU G L. Super-tough poly(lactide) thermoplastic vulcanizates based on modified natural rubber[J].ACS Sustainable Chemistry and Engineering, 2017, 5: 78-84.
23
HUANG J M, MOU W J, WANG W T, et al. Influence of DCP content on the toughness and morphology of fully biobased ternary PLA/NR-PMMA/NR TPVs with co-continuous phase structure[J]. Polymer-Plastics Technology and Materials, 2019, 59(6): 674-684.
24
FANG C, LU X, QU J P. Preparation and properties of biodegradable poly (lactic acid)/ethylene butyl acrylate glycidyl methacrylate blends via novel vane extruder[J]. Plastics, Rubber and Composites, 2019,48(8): 364-373.
25
BAI H W, XIU H, GAO J, et al. Tailoring impact toughness of poly(L-lactide)/poly(ε-caprolactone) (PLLA/PCL) blends by controlling crystallization of PLLA matrix[J]. ACS Applied Materials Interfaces, 2012, 4(2): 897-905.
26
OYAMA H T. Super-tough poly(lactic acid) materials: Reactive blending with ethylene copolymer[J]. Polymer 2009, 50(3): 747-751.

Comments

PDF(2965 KB)

Accesses

Citation

Detail

Sections
Recommended

/