
Study on Preparation of SA/PVA Composite Hydrogel and Adsorption of Co2+ and MB
WU Shu-ming, LIANG Wen-xia, WU Jia-bin
Study on Preparation of SA/PVA Composite Hydrogel and Adsorption of Co2+ and MB
Using sodium alginate (SA), polyvinyl alcohol (PVA) as raw materials, acrylic acid (AA) as monomer to synthesize SA/PVA-g-AA hydrogel, the functional group structure and micromorphology of the hydrogel material were characterized. Using Co2+/MB as the adsorption object, the effects of pH, initial mass concentration, hydrogel addition on the adsorption of hydrogel performance were investigated, and the adsorption dynamics were explored. The results show that SA/PVA-g-AA hydrogel is a porous surface area of 120.896 7 m2/g and an average adsorption pore diameter of 8.069 08 nm which is beneficial to the adsorption of Co2+and MB. The composite hydrogel has a fast adsorption rate for Co2+/MB, and can reach adsorption equilibrium within 60 min, which is consistent with the quasi-second-order kinetic model. The maximum removal rates of Co2+ and MB reaches 95.01%and 98.78%, respectively, when the pH value is 3 and 7, the hydrogel dosage is 0.15 g, and the initial mass concentration is 100 mg/L.
Sodium alginate / PVA / Composite hydrogel / Co2+ / MB / Dynamics
1 |
曹如楼,杨卫民,丁玉梅,等.静电纺丝纳米纤维在水体重金属及染料吸附中的研究进展[J].塑料科技,2018,46(11):112-117.
|
2 |
|
3 |
侯芳,郑伟.聚苯胺/聚苯乙烯复合材料的制备及对Pb2+吸附性能的研究[J].塑料科技,2021,49(5):48-52.
|
4 |
|
5 |
赵亭,张剑.磁性壳聚糖/氧化石墨烯复合材料对钴(Ⅱ)吸附性能研究[J].冶金分析,2022,42(5):48-54.
|
6 |
姜侠,王冠,刘振华,等.改性活性炭对亚甲基蓝的吸附性能及机理[J].水处理技术,2020,46(6):76-82.
|
7 |
|
8 |
韩思贤,刘维平.g-C3N4/MnO2@PANI光催化阴极的产电性能及其对废水中铜的回收效果[J].化工环保,2022,42(5):579-586.
|
9 |
刘顺强,解明江,郭学锋,等.混晶海胆状TiO2空心球多级结构的制备及其对亚甲基蓝的光催化降解[J].无机化学学报,2020,36(2):317-323.
|
10 |
|
11 |
|
12 |
马莹,王恬,张恒.氧化石墨烯吸附亚甲基蓝的分子动力学模拟[J].高等学校化学学报,2019,40(12):2534-2541.
|
13 |
任南琪,周显娇,郭婉茜.染料废水处理技术研究进展[J].化工学报,2013,64(1):84-94.
|
14 |
|
15 |
张雅静,王向鹏,庞丽平.吸水树脂在染料吸附领域应用进展[J].塑料科技,2022,50(6):119-123.
|
16 |
张晓玉,张政,徐奥.改性木质素基水凝胶的制备及其对Cr(Ⅵ)和甲基橙的吸附研究[J].化学与生物工程,2023,40(5):16-24.
|
17 |
|
18 |
|
19 |
|
20 |
钱建瑛,丁振中,杨涛,等.废弃虾壳制备改性甲壳素凝胶球及其对金属离子的吸附性能[J].生物质化学工程,2016,50(6):37-42.
|
21 |
罗文强.羧甲基壳聚糖吸附剂对钴离子的吸附特性研究[D].广州:华东理工大学,2018.
|
22 |
|
23 |
孙将皓,邵彦峥,魏春艳,等.海藻酸钠/改性氧化石墨烯微孔气凝胶纤维制备与吸附性能[J].纺织学报,2023,44(4):24-31.
|
24 |
林建明,唐群委,吴季怀.高强度PAM/PVA互穿网络水凝胶的合成[J].华侨大学学报:自然科学版,2010,31(1):41-48.
|
25 |
|
26 |
吴淑茗,彭瑞,翁自平,等.海藻酸钠/硅藻土复合凝胶对Ni(Ⅱ)、Cd(Ⅱ)的吸附机制[J].塑料科技,2023,51(4):16-20.
|
27 |
冯华伟.海藻酸钠基双网络复合水凝胶的制备及吸附性能研究[D].淮南:安徽理工大学,2020.
|
28 |
车春波,谷芳,李俊生,等.玉米秸秆纤维素/丙烯酸水凝胶的制备及其吸附性能研究[J].化工新型材料,2023,51(3):242-246.
|
29 |
|
30 |
吴淑茗,刘钰成,吴佳斌,等.玉米淀粉/羧甲基纤维素生物复合凝胶的制备及吸附行为研究[J].塑料科技,2023,51(3):73-78.
|
31 |
毛立娟,王孝平,高原,等.氮气吸附BET法测定纳米材料比表面积的比对实验[J].现代测量与实验室管理,2010,18(5):3-5.
|
32 |
张文良,夏延致,桂由刚,等.海藻酸钠/羧甲基纤维素多孔气凝胶吸附阳离子染料性能的研究[J].材料科学,2019,9(1):104-114.
|
33 |
|
/
〈 |
|
〉 |