
The Curing Behavior of Epoxy Resin/Wormwood Powder Antibacterial Composites Studied by DSC
WANG Shuai, LIANG Jia-yu, QI Rong-rong
The Curing Behavior of Epoxy Resin/Wormwood Powder Antibacterial Composites Studied by DSC
Wormwood powder (WP) was used to perform antibacterial modification on traditional thermosetting plastic epoxy resin (EP) to prepare EP with antibacterial function, so as to solve the problems of shortening life span and hygiene caused by bacterial erosion of EP. The dynamics of curing process of antibacterial EP was studied, so as to understand the influence of WP on its curing behavior. It lays a theoretical foundation for selecting reasonable processing conditions. The curing behavior of EP/WP was studied by DSC. The results showed that the antibacterial rate of the composites increased with the addition of WP. When the addition of WP was 20%, the antibacterial rate of the composites against Escherichia coli and Staphylococcus aureus reached 100%. The curing activation energy E a of pure EP was 74.80 kJ/mol, EP/20%WP was 68.17 kJ/mol, indicating that the addition of WP promoted the curing of EP and reduced its curing activation energy. Through theoretical model analysis, it was found that the curing behavior of EP with WP was consistent with the autocatalytic mechanism.
Wormwood powder / Epoxy resin / Curing behavior / Non-isothermal and isothermal DSC
1 |
杜兴,何天亮,张飞燕,等.PBAT/高岭土/艾草抗菌可降解薄膜的制备及性能[J].塑料科技,2022,50(2):59-62.
|
2 |
闫宗莹,倪雨涛,廖宝宝,等.PE/艾草提取物抗菌薄膜制备及性能[J].工程塑料应用,2021,49(4):48-52.
|
3 |
柳洋,牛健行,李玉瑶,等.艾草/聚丙烯腈纳米纤维复合材料的制备及其超亲水、长久抗菌性能[J].复合材料学报,2022,39(5):2258-2268.
|
4 |
孙丽娟,封严.艾草在纺织领域的应用研究现状[J].产业用纺织品,2021,39(1):16-19.
|
5 |
崔凤烨,钱晓明,王立晶,等.艾草黏胶纤维的制备及性能[J].上海纺织科技,2020,48(7):26-28, 46.
|
6 |
|
7 |
王硕.海洋生物质增强E51型环氧树脂及其固化动力学研究[D].哈尔滨:哈尔滨工程大学,2020.
|
8 |
李设桥,周红军.环氧树脂/纳米二氧化钛的等温固化动力学[J].仲恺农业工程学院学报,2012,25(2):30-33.
|
9 |
中华人民共和国国家质量监督检验检疫总局,中国国家标准化管理委员会.纳米无机材料抗菌性能检测方法:GB/T 21510—2008[M].北京:中国标准出版社,2008.
|
10 |
郑昆,钟肖飞,张华.艾叶挥发油类成分及其药理作用的研究进展[J].中国实验方剂学杂志,2020,26(18):224-234.
|
11 |
刘光荣,翟春涛,金敏蓉,等.天然抗菌剂对5种致病菌的抑制作用研究[J].中国真菌学杂志,2020,15(2):88-92.
|
12 |
|
13 |
简梨娜,宋学丽,郭江涛,等.艾草的化学成分及临床应用[J].化学工程师,2021,35(7):58-62.
|
14 |
赵雪婷,刘翔宇,周琳贇,等.液体型咪唑衍生物对环氧树脂固化行为的影响[J].工程塑料应用,2022,50(4):143-149.
|
15 |
李爱,崔华楠,余清,等.环氧树脂灌封料的固化动力学及固化工艺[J].高分子材料科学与工程,2021,37(4):105-112, 120.
|
16 |
缪桦.溴化环氧树脂/酚类固化剂的研究[D].西安:西北工业大学,2006.
|
17 |
李恒,王德海,钱夏庆.非等温DSC法研究环氧树脂体系固化动力学[J].固体火箭技术,2013,36(2):266-269, 284.
|
18 |
|
19 |
|
20 |
|
21 |
|
22 |
|
23 |
|
24 |
|
25 |
|
26 |
孙文兵,张超灿.等温DSC法研究聚酰胺与环氧树脂的固化动力学[J].武汉理工大学学报,2009,31(6):28-31.
|
27 |
|
28 |
|
/
〈 |
|
〉 |