高钙酿酒沼渣制备生物炭吸附剂及其土壤改良性能

贾晓凤, 梁家伟, 刘艳奇, 买文宁, 代吉华

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PDF(7982 KB)
地球科学 ›› 2024, Vol. 49 ›› Issue (06) : 2227-2241. DOI: 10.3799/dqkx.2022.507

高钙酿酒沼渣制备生物炭吸附剂及其土壤改良性能

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Utilization of High Calcium Biogas Residue for Biochar Adsorbent Preparation and Its Soil Improvement Properties

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摘要

为解决酿酒沼渣的资源化问题,采用热解法制备沼渣生物炭,通过批量吸附试验和盆栽试验考察其吸附性能和土壤改良性能.结果表明:700 ℃下限氧热解1.5 h所制备的高钙沼渣生物炭,初始pH为10时,吸附量最大,投加10 g·L-1的沼渣生物炭对实际废水COD、NH4 +-N和TP的去除率分别可达45.29%、56.10%和86.33%,吸附符合拟一阶动力学模型和Langmuir等温吸附,属于物理吸附.吸附后生物炭表面C、N、P、O元素含量显著增加,出现新的N-H、P=O基团.当投加5%的吸附后生物炭时,土壤中速效磷、速效钾及有机质的含量均显著提高,小白菜生长得到促进.本研究探索了“一处理两用”的策略,为酿酒沼渣处置和资源回收提供了一种本土方法.

Abstract

In order to solve the problem of resource utilization of brewing biogas residue, the biochar prepared by brewing biogas residue was added into garden soil. A batch incubation and absorption experiments were carried out with the amended soils to study the improvement of biochar addition on adsorption availability and soil physicochemical properties. Results show that: the high calcium biochar prepared by oxygen limited pyrolysis method at 700 ℃ for 1.5 h behaved best with initial pH 10, the removal rates of COD, NH4 +-N and TP in actual wastewater by adding 10 g·L-1 biogas biochar can reach 45.29%, 56.10% and 86.33%, respectively. Langmuir isothermal model and pseudo-first-order kinetic equation were more consistent with its adsorption characteristics, indicating the physical adsorption were the main adsorption modes. The contents of C, N, P and O elements on the biochar surface increased significantly with new N-H and P=O groups generated after the adsorption. The available phosphorus, available potassium and organic matter in soil were significantly increased with 5% of adsorbed biochar added which could promote the growth of Chinese cabbage well. This study explored a ‘one treatment but two uses’ approach, which provides an application prospect for the disposal and resource recovery of biogas residue.

关键词

酿酒沼渣 / 生物炭 / 吸附剂 / 废水处理 / 土壤改良.

Key words

brewing biogas residue / biochar / adsorbents / wastewater treatment / soil conditioners

中图分类号

X797

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贾晓凤 , 梁家伟 , 刘艳奇 , . 高钙酿酒沼渣制备生物炭吸附剂及其土壤改良性能. 地球科学. 2024, 49(06): 2227-2241 https://doi.org/10.3799/dqkx.2022.507
Jia Xiaofeng, Liang Jiawei, Liu Yanqi, et al. Utilization of High Calcium Biogas Residue for Biochar Adsorbent Preparation and Its Soil Improvement Properties[J]. Earth Science. 2024, 49(06): 2227-2241 https://doi.org/10.3799/dqkx.2022.507

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基金

国家自然科学基金面上项目(52370088)
河南省科技公关项目(222102320152;222102320054)
河南省自然科学基金项目(232300420098)

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