PDF(5770 KB)
燕山地区中‒新元古界烃源岩地球化学特征及油源对比
孙中良, 陈媛, 李志明, 申宝剑, 祝庆敏, 贾梦瑶, 吴琰
PDF(5770 KB)
PDF(5770 KB)
燕山地区中‒新元古界烃源岩地球化学特征及油源对比
Geochemical Characteristics of the Meso-Neoproterozoic Source Rocks and Oil-Source Correlations in the Yanshan Area
,
燕山地区中‒新元古界的油气富集情况一直以来都是学者们关注的热点.运用总有机碳（TOC）测试、热解、气相色谱（GC）、气相色谱质谱（GC-MS）等方法，对其有机地球化学特征，特别是生物标志化合物、有机质来源和沉积环境进行了详细的讨论，对比油苗/沥青与烃源岩中生物标志化合物组成特征，识别燕山地区中‒新元古界地层中的主力烃源岩.研究得出，下马岭组、洪水庄组烃源岩有机碳含量高，生烃潜力大，热演化程度适中，为好‒极好的烃源岩，铁岭组烃源岩为差‒中等烃源岩，高于庄组烃源岩热演化程度过高，已不能判断烃源岩类型.根据研究区的生物标志化合物特征，可以将其划分为两类，其中洪水庄组、铁岭组及下马岭组为第Ⅰ类烃源岩，以无环类异戊二烯姥鲛烷（Pr）和植烷（Ph）的相对含量极低，具有一定丰度的C20规则三环萜烷（C20TT）和C19TT以及特殊的13α（正烷基）‒三环萜烷系列化合物，富含四环萜烷（C24TeT）、降新藿烷（Ts和C29Ts）和重排藿烷（C30Dia），缺失甾烷化合物为特征，揭示了第Ⅰ类烃源岩具有较高的热演化程度，缺氧的沉积环境以及特殊的成烃生物.高于庄组为第Ⅱ类烃源岩，以高丰度的C23~C25TT以及规则藿烷，普遍存在C27~C29规则甾烷，低丰度的C24四环萜、降新藿烷和重排藿烷，未检测到补身烷和13α（正烷基）‒三环萜系列化合物为特征，呈现出典型海相碳酸盐岩沉积环境下的原油特征以及指示了较为多样的生物来源.油源对比表明，第Ⅰ类油苗/沥青主要来源于洪水庄组烃源岩，而第Ⅱ类沥青砂岩的有机地球化学组成特征和高于庄组烃源岩十分相似.
The enrichmentof Meso-Neoproterozoic oil and gas in Yanshan area has been the hot topic focused on by scholars. Total Organic Carbon (TOC) test, pyrolysis, gas chromatography (GC), gas chromatography-mass spectrometry (GC-MS) and other methods are applied in this paper to discuss organic geochemical characteristics of samples. Especially, the biomarker compounds, organic matter sources and sedimentary environment are discussed in detail. The geochemical and biomarker characteristics of oil seepage/asphalt and source rocks are compared to identify the major source rocks of Meso-Neoproterozoic strata in Yanshan Region. The results show that the source rocks of the Xiamaling and Hongshuizhuang formations, featured with high content of organic carbons, great hydrocarbon generation potential and moderate degree of thermal evolution, are good and supreme source rocks.The source rocks of Tieling Formation are poor-medium source rocks, and the degree of thermal evolution of Gaoyuzhuang Formation is excessively high to determine the type of source rocks. According to the characteristics of biomarkers in the researched area, the source rocks are divided into two categories. Wherein, the source rocks of Hongshuizhuang, Tieling and Xiamaling Formations are classified into Category I. The relative contents of acyclic isoprene pristane (Pr) and phytane (Ph) are very low,with certain abundance of regular C20 tricyclic terpane (C20TT), C19TT and special 13α (n-alkyl) - tricyclic terpanes, rich in tetracyclic terpane (C24TeT), norneohopane (Ts and C29Ts) and rearranged hopanes (C30Dia), and are characterized by the absence of sterane compound.Revealing moderate degree of thermal evolution, anoxic sedimentary environment and a special hydrocarbon generating organism of Category I source rocks. Gaoyuzhuang Formation, provided with Category Ⅱsource rocks, is characterized with high abundance of C23‒C25TT and regular hopane, common C27‒C29 regular steranes, low abundance of C24 tetracyclic terpane, norneohopane and rearranged hopane, and no drimane and 13α (n-alkyl)-featured with tricyclic terpene serial compound is detected, showing the characteristics of crude oil in typical marine carbonate sedimentary environment and indicating various biological sources. The oil and source rock correlation shows that Category I oil seepage/asphalt mainly originates from the source rocks of Hongshuizhuang Formation, while the organic geochemical composition characteristics of CategoryⅡasphalt sandstone are extremely similar to the source rocks of Gaoyuzhuang Formation.
燕山地区 / 中‒新元古界 / 烃源岩特征 / 生物标志化合物 / 油‒源对比 / 地球化学 / 油气地质
Yanshan area / Meso-Neoproterozoic / characteristics of source rocks / biomarker compound / oil-source correlation / geochemistry / petroleum geology
P618.13
|
Al-Arouri, K. R., McKirdy, D. M., Boreham, C. J., 1998. Oil-Source Correlations as a Tool in Identifying the Petroleum Systems of the Southern Taroom Trough, Australia. Organic Geochemistry, 29(1-3): 713-734. https://doi.org/10.1016/S0146-6380(98)00132-6
|
|
Alexander, R., Kagi, R. I., Noble, R., et al., 1984. Identification of Some Bicyclic Alkanes in Petroleum. Organic Geochemistry, 6: 63-72. https://doi.org/10.1016/ 0146-6380(84)90027-5
|
|
Aquino Neto, F. R., Restle, A., Connan, J., et al., 1982. Novel Tricyclic Terpanes (C19, C20) in Sediments and Petroleums. Tetrahedron Letters, 23(19): 2027-2030. https://doi.org/10.1016/S0040-4039(00)87251-2
|
|
Armanios, C., Alexander, R., Kagi, R. I., 1992. High Diahopane and Neohopane Abundances in a Biodegraded Crude Oil from the Barrow Sub-Basin of Western Australia. Organic Geochemistry, 18(5): 641-645. https://doi.org/10.1016/0146-6380(92)90089-G
|
|
Bendoraitis, J. G., Brown, B. L., Hepner, L. S., 1962. Isoprenoid Hydrocarbons in Petroleum. Isolation of 2, 6, 10, 14-Tetramethylpentadecane by High Temperature Gas-Liquid Chromatography. Analytical Chemistry, 34(1): 49-53. https://doi.org/10.1021/ac60181a011
|
|
Brooks, J. D., Gould, K., Smith, J. W., 1969. Isoprenoid Hydrocarbons in Coal and Petroleum. Nature, 222(5190): 257-259. https://doi.org/10.1038/222257a0
|
|
Chen, J. F., Sun, S. L., 2004. Geochemical Characteristics and Genesis of the Organic Rich Strata of the Neoproterozoic Xiamaling Formation in North China. Natural Gas Geoscience, 15(2): 110-114 (in Chinese with English abstract).
|
|
Chen, P. J., 1985. Comment on Several Topics in the Geochemistry Carbonate Source Rock. Petroleum Geology & Experiment, 7(1): 3-12 (in Chinese with English abstract).
|
|
Chen, Z. H., Zha, M., Jin, Q., et al., 2011. Distribution of Sterane Maturity Parameters in a Lacustrine Basin and Their Control Factors: A Case Study from the Dongying Sag, East China. Petroleum Science, 8(3): 290-301. https://doi.org/10.1007/s12182-011-0146-9
|
|
Cheng, K. M., Jin, W. M., He, Z. H., et al., 1991. Application of Sesquiterpanes to the Study of Oil-Gas Source-The Gas-Rock Correlation in the Qiongdongnan Basin. Journal of Southeast Asian Earth Sciences, 5(1-4): 189-195. https://doi.org/10.1016/0743-9547(91)90025-S
|
|
De Grande, S. M. B., Aquino Neto, F. R., Mello, M. R., 1993. Extended Tricyclic Terpanes in Sediments and Petroleums. Organic Geochemistry, 20(7): 1039-1047. https://doi.org/10.1016/0146-6380(93)90112-O
|
|
Dickas, A.B., 1986. Word Wide Distribution of Precambrian Hydrocarbon Deposits. Geoscience Wisconsin, 11(9): 8-13.
|
|
Feenstra, R. C., Hanson, G. H., 1997. Foreign Direct Investment and Relative Wages: Evidence from Mexico’s Maquiladoras. Journal of International Economics, 42(3-4): 371-393. https://doi.org/10.1016/S0022-1996(96)01475-4
|
|
Fu, J.M., Liu, D.H., 1982. Some Characteristics of the Evolution of Organic Matter in Carbonate Formations. Acta Petrolei Sinica, 3(1): 1-9, 95 (in Chinese with English abstract).
|
|
Gao, Y.B., Hao, S.S., Lu,X.J., et al., 1991. Study on Oil Source of the Middle-Upper Proterozoic Layer in Yanshan Area. Journal of the University of Petroleum, China, 15(1): 1-8 (in Chinese with English abstract).
|
|
Hallmann, C., Schwark, L., Grice, K., 2008. Community Dynamics of Anaerobic Bacteria in Deep Petroleum Reservoirs. Nature Geoscience, 1(9): 588-591. https://doi.org/10.1038/ngeo260
|
|
Huang, W.Y., Meinschein, W.G., 1979. Sterols as Ecological Indicators. Geochimica et Cosmochimica Acta, 43: 739-745.
|
|
Hunt, J. M., 1972. Distribution of Carbon in the Crust of the Earth. AAPG Bulletin, 56(11): 2273-2277.
|
|
Jin, X., Zhang, Z. H., Wu, J., et al., 2019. Origin and Geochemical Implication of Relatively High Abundance of 17α (H)-Diahopane in Yabulai Basin, Northwest China. Marine and Petroleum Geology, 99: 429-442. https://doi.org/10.1016/j.marpetgeo.2018.10.048
|
|
Kashirtsev, V. A., Gaiduk, V. V., Chalaya, O. N., et al., 2012. Geochemistry of Biomarkers and Catagenesis of Organic Matter of Cretaceous and Cenozoic Deposits in the Indigirka-Zyryanka Basin (Northeastern Yakutia). Russian Geology and Geophysics, 53(8): 787-797. https://doi.org/10.1016/j.rgg.2012.06.006
|
|
Lei, C., Yin, S.Y., Ye, J.R., et al., 2021. Geochemical Characteristics and Hydrocarbon Generation History of Paleocene Source Rocks in Jiaojiang Sag, East China Sea Basin. Earth Science, 46(10): 3575-3587 (in Chinese with English abstract).
|
|
Liu, B.Q., Fang, J., 1989. On Petroleum Source and Maturation Characteristics of the Organic Matter of Cambrian and middle-Upper Proterozoic in Kuancheng Region of Northern Hebei Province. Petroleum Geology & Expeximent, 11(1): 16-32 (in Chinese with English abstract).
|
|
Liu, B.Q., Qin, J.Z., Li, X., 2000. Analysis of Middle-Upper Proterozoic Source Rocks, Oil Seedlings and Oil Sources in Northern Hebei Depression. Marine Origin Petroleun Geology, 5(S1): 35-46 (in Chinese with English abstract).
|
|
Logan, G. A., Calver, C. R., Gorjan, P., et al., 1999. Terminal Proterozoic Mid-Shelf Benthic Microbial Mats in the Centralian Superbasin and Their Environmental Significance. Geochimica et Cosmochimica Acta, 63(9): 1345-1358. https://doi.org/10.1016/S0016-7037(99)00033-2
|
|
Luo, B.J., Wang, Y.X., Meng, Q.X., et al., 1991. Geochemisty of Bicyclic Alkanes in Sediments, Coal and Crude Oils. Science in China (Series B), 34(3): 363-376.
|
|
Luo, G. M., Hallmann, C., Xie, S. C., et al., 2015. Comparative Microbial Diversity and Redox Environments of Black Shale and Stromatolite Facies in the Mesoproterozoic Xiamaling Formation. Geochimica et Cosmochimica Acta, 151: 150-167. https://doi.org/10.1016/j.gca.2014.12.022
|
|
Moldowan, J. M., Fago, F. J., Carlson, R. M. K., et al., 1991. Rearranged Hopanes in Sediments and Petroleum. Geochimica et Cosmochimica Acta, 55(11): 3333-3353. https://doi.org/10.1016/0016-7037(91)90492-N
|
|
Nytoft, H. P., Lutnæs, B. F., Johansen, J. E., 2006. 28-Nor-Spergulanes, a Novel Series of Rearranged Hopanes. Organic Geochemistry, 37(7): 772-786. https://doi.org/10.1016/j.orggeochem.2006.03.005
|
|
Ou, G.X., Li, L.Q., 2006. Study on the Origin and Accumulation Stage of Hydrocarbon Distributed in the Middle-Upper Proterozoic System in the Liaoxi-Jibei Depression. Bulletin of Mineralogy, Petrology and Geochemistry, 25(1): 87-91 (in Chinese with English abstract).
|
|
Ourisson, G., Albrecht, P., Rohmer, M., 1984. The Microbial Origin of Fossil Fuels. Scientific American, 251(2): 44-51. https://doi.org/10.1038/scientificamerican0884-44
|
|
Peter, K.F., Cassa, M.R., 1994. Applied Source Rock Geochemistry. In: Magoon, L. B., Dow, W. G., eds., The Petroleum System-from Source to Trap. AAPG Memoir, 60: 93-120.
|
|
Philp, R. P., Gilbert, T. D., 1986. Biomarker Distributions in Australian Oils Predominantly Derived from Terrigenous Source Material. Organic Geochemistry, 10(1-3): 73-84. https://doi.org/10.1016/0146-6380(86)90010-0
|
|
Pratt, L. M., Summons, R. E., Hieshima, G. B., 1991. Sterane and Triterpane Biomarkers in the Precambrian Nonesuch Formation, North American Midcontinent Rift. Geochimica et Cosmochimica Acta, 55(3): 911-916. https://doi.org/10.1016/0016-7037(91)90351-5
|
|
Ruble, T. E., Talbert, S. J., Claypool, A. L., et al., 2019. Origin and Occurrence of Unusually High 17α-Diahopanes in the Waltman Shale, Wind River Basin, Wyoming. In: Usa 29th International Meeting on Organic Geochemistry. Gothenburg, Sweden. https://doi.org/10.3997/2214-4609.201902978
|
|
Shi, Z.S., He, S., Yang, D.Q., 2005. A Study of Source Rock Thermal Evolution Modeling of Hetaoyuan Formation in Dongzhuang Sag of Nanyang Oilfield. Geological Science and Technology Information, 24(2): 85-89, 96 (in Chinese with English abstract).
|
|
Simoneit, B. R. T., Grimalt, J. O., Wang, T. G., et al., 1986. Cyclic Terpenoids of Contemporary Resinous Plant Detritus and of Fossil Woods, Ambers and Coals. Organic Geochemistry, 10(4/5/6): 877-889. https://doi.org/10.1016/S0146-6380(86)80025-0
|
|
Song, D. F., Chen, Y., Wang, T. G., et al., 2021. Organic Geochemical Compositions of Mesoproterozoic Source Rocks in the Yanliao Rift, Northern China. Marine and Petroleum Geology, 123: 104740. https://doi.org/10.1016/j.marpetgeo.2020.104740
|
|
Sun, S., Wang, T.G., 2016. Meso-Neoproterozoic Geology and Oil and Gas Resources in Eastern China. Science Press, Beijing (in Chinese with English abstract).
|
|
Tissot, B. P., Welte, D. H., 1984. Petroleum Formation and Occurrence. Sringer-Verlag Berlin Heidelberg, New York, 339-374.
|
|
Trindade, L., Brassell, S. C., Neto, E. S., 1992. Petroleum Migration and Mixing in the Potiguar Basin, Brazil. AAPG Bulletin, 76(12): 1903-1924. https://doi.org/10.1306/BDFF8B14-1718-11D7-8645000102C1865D
|
|
Wang, T.G., 1980. Primacy of Sinian Suberathem Oil Seedlings in Yanshan Area and Its Petroleum Geological Significance. Petroleum Expoloration and Development, 7(2): 34-52 (in Chinese with English abstract).
|
|
Wang, T.G., 1990. A New Tricyclic Terpenane Series Biomarker in the Upper Proterozoic Bituminous Sandstone in the Eastern Yanshan Mountains. Science in China, Ser. B, 20(10): 1077-1085 (in Chinese with English abstract)
|
|
Wang, T.G., Han, K.Y., 2011. On Meso-Neoproterozoic Primary Petroleum Resources. Acta Petrolei Sinica, 32(1): 1-7 (in Chinese with English abstract).
|
|
Wang, T.G., Zhong, N. N., Wang, C.J., et al., 2016. Source Beds and Oil Entrapment-Alteration Histories of Fossil-Oil-Reservoirs in the Xiamaling Formation Basal Sandstone, Jibei Depression. Petroleum Science Bulletin, 1(1): 24-37 (in Chinese with English abstract).
|
|
Wang, Z., Yang, C., Fingas, M., et al., 2005. Characterization, Weathering, and Application of Sesquiterpanes to Source Identification of Spilled Lighter Petroleum Products. Environmental Science & Technology, 39(22): 8700-8707. https://doi.org/8700-8707.10.1021/es051371o
|
|
Weston, R.J., Philp, R.P., Sheppard, C.M, et al., 1989. Sesquiterpanes, Diterpanes and Other Higher Terpanes in Oils from the Taranaki Basin of New Zealand. Organic Geochemistry, 14(4): 405-421. https://doi.org/10.1016/0146-6380(89)90006-5
|
|
Wu, X. Q., Chen, Y. B., Liu, Q. Y., et al., 2019. Molecular Geochemical Characteristics of Source Rocks in the 5th Member of Upper Triassic Xujiahe Formation, Xinchang Gas Field, West Sichuan Depression. Earth Science, 44(3): 859-871 (in Chinese with English abstract).
|
|
Xiao, H., Li, M. J., Wang, T. G., et al., 2021a. Four Series of Rearranged Hopanes in the Mesoproterozoic Sediments. Chemical Geology, 573: 120210. https://doi.org/10.1016/j.chemgeo.2021.120210
|
|
Xiao, H., Wang, T. G., Li, M. J., et al., 2021b. Extended Series of Tricyclic Terpanes in the Mesoproterozoic Sediments. Organic Geochemistry, 156: 104245. https://doi.org/10.1016/j.orggeochem.2021.104245
|
|
Yan, Y.Z., Liu, Z.L., 1998. On the Relationship between Biocommunities and Palaeoenvironments in Changcheng Period of the Yanshan Basin, North China. Acta Micropalaeontologica Sinica, 15(3): 249-266 (in Chinese with English abstract).
|
|
Yang, F., Wang, Q., Hao, F., et al., 2021. Biomarker Characteristics of Lower Sub-Member of the First Member of the Shahejie Formation and Its Accumulation Contribution in Raoyang Depression, Jizhong Sub-Basin. Earth Science, 46(1): 172-185 (in Chinese with English abstract).
|
|
Zhang, C.G., Xiong, J.H., 1979. Discussion on Oil and Gas Generation in Sinian Suberathem in the Western Section of Yanshan Mountain. Journal of China University of Petroleum (Edition of Natural Science), 3(1): 88-102, 140 (in Chinese with English abstract)
|
|
Zhang, M., 2005. Study on the Mesoproterozoic Hydrocarbon Migration and Accumulation Periods in Western Liaoning and Northern Hebei Region. China University of Geosciences, Beijing (in Chinese with English abstract).
|
|
Zhang, M., Ou, G.X., Li, L.Q., et al., 2009. Study on Reservoir Fluid and the History of Hydrocarbon Migration and Accumulation in the Middle-Upper Proterozoic System in the West Liaoning-North Hebei Area. Bulletin of Mineralogy, Petrology and Geochemistry, 28(1): 19-23 (in Chinese with English abstract).
|
|
Zhang, S.C., Zhang, B.M., Bian, L.Z., et al., 2007. Oil Shale of Xiamaling Formation Accumulated by Red Algae more than 800 Million Years ago. Science in China (Series D: Earth Sciences), 37(5): 636-643 (in Chinese with English abstract).
|
/
| 〈 |
|
〉 |
AI Summary
