
人类活动对木里冻土区水文环境影响的多元同位素示踪
邢剑伟, 李小倩, 周爱国, 庞守吉, 李鑫, 余迎祥
人类活动对木里冻土区水文环境影响的多元同位素示踪
Multi-Isotope Tracing of the Impact of Human Activities on the Hydrological Environment in the Muli Permafrost Region
为查明人类活动对木里冻土区水文环境造成的影响,选取高寒冻土区人类活动最为显著的木里煤田聚乎更矿区,以区内大通河支流水系河水为研究对象,基于水化学组成空间特征,利用氢、氧、碳、氮、硫、锶等多元同位素开展示踪研究.研究表明:(1)冻结层上水是河水的主要补给来源,煤矿开采、天然气水合物钻探等人类活动破坏原有冻土结构,增加了冻结层上水对河水的贡献比例;(2)河水中主要溶解性营养物质(SO4 2-、NO3 -和DOC)浓度的增加源于人类活动的影响:硫氧同位素揭示了大规模的煤矿露天开采促进还原硫氧化,是导致冻结层上水和河水中SO4 2-升高的主要原因;氮氧同位素表明河水中高浓度的NO3 -来源于散养式放牧的牲畜粪便;DOC主要来源于高寒草甸植物降解产生的土壤有机质,人类活动影响下增加了DOC和DIC的输出,增强了源区河水中的微生物活动;(3)除H2CO3风化碳酸盐岩外,受人类活动煤矿开采影响下硫酸参与的碳酸盐岩和硅酸盐岩岩石风化作用增强,进而影响着区域岩石风化的碳汇作用.研究成果为认识人类活动影响下高寒冻土区水文环境的演化提供研究思路,为高寒冻土区生态环境保护提供科学依据.
In order to find out the impact of human activities on the hydrological environment of Muli permafrost area,Juhugeng mining area of Muli Coalfield with the most significant human activities in the alpine permafrost area was selected,and the river water of Datong River tributary system in the area was taken as the research object. Based on the spatial characteristics of hydrochemical composition,the research was carried out by using multiple isotopes such as hydrogen,oxygen,carbon,nitrogen,sulfur and strontium. The results show that:(1) The supra-permafrost water is the main supply source of the river water. Human activities such as coal mining and natural gas hydrate drilling destroy the original frozen soil structure and increase the contribution proportion of the supra-permafrost water to river water;(2) The increase of the concentration of main dissolved nutrients (SO4 2-, NO3 - and DOC) in river water is due to the influence of human activities:sulfur and oxygen isotopes reveal that large-scale open-pit mining in coal mine promotes reduced sulfur oxidation,which is the main reason for the increase of SO4 2- in the supra-permafrost water and river water;Nitrogen and oxygen isotopes show that the high concentration of NO3 - in the river comes from livestock manure of free range grazing;DOC mainly comes from soil organic matter produced by plant degradation in alpine meadow,and there are strong microbial activities in the river water in the source area;(3) Except for H2CO3 weathering carbonate rocks,the weathering of carbonate rock and silicate rock participated by sulfuric acid is enhanced under the influence of human activities and coal mining,which further affects the carbon sink of regional rock weathering. The research results provide research ideas for understanding the evolution of hydrological environment in Alpine permafrost area under the influence of human activities,and provide scientific basis for ecological environment protection in Alpine permafrost area.
木里冻土区 / 煤矿开采 / 天然气水合物钻探 / 同位素 / 环境效应 / 水文地质
Muli permafrost region / coal mining / gas hydrate drilling / isotopes / Human activities / hydrogeology
P64
Berner, R. A., 2003. The Long-Term Carbon Cycle, Fossil Fuels and Atmospheric Composition. Nature, 426(6964): 323-326. https://doi.org/10.1038/nature02131
|
Berner, R. A., Lasaga, A. C., Garrels, R. M., 1983. The Carbonate-Silicate Geochemical Cycle and Its Effect on Atmospheric Carbon Dioxide over the Past 100 Million Years. American Journal of Science, 283(7): 641-683. https://doi.org/10.2475/ajs.283.7.641
|
Cai, Q.F., 2020. Analysis and Evaluation of the Influence of Coal Mining on Shallow Groundwater System (Dissertation). North China University of Water Resources and Electric Power, Zhengzhou (in Chinese with English abstract).
|
Chang, J., Ye, R. Z., Wang, G. X., 2018. Review: Progress in Permafrost Hydrogeology in China. Hydrogeology Journal, 26(5): 1387-1399. https://doi.org/10.1007/s10040-018-1802-6
|
Chen, J.J., Guo, J., Xu,S.S., et al., 2020. Preliminary Study on DOC and DIC Mass Concentrations and Isotopic Compositions of Water in Miyun Reservoir Basin in Beijing in Summer. Environmental Science,41(11):4905-4913 (in Chinese with English abstract).
|
Du, M.Y., Kawashima,S., Yonemura,S., et al., 2004. Mutual Influence between Human Activities and Climate Change in the Tibetan Plateau during Recent Years. Global and Planetary Change, 41(3/4): 241-249. https://doi.org/10.1016/j.gloplacha.2004.01.010
|
Frey, K. E., McClelland, J. W., 2009. Impacts of Permafrost Degradation on Arctic River Biogeochemistry. Hydrological Processes, 23(1): 169-182. https://doi.org/10.1002/hyp.7196
|
He, D.S., Zhang, P.H., Ming, C.D., et al., 2020. Sources of Soluble Organic Matter in Quaternary Sediments and Its Relationship with Natural Gas Hydrate in Muli Permafrost Area, South Qilian Basin. Geological Bulletin of China,39(7):1062-1071 (in Chinese with English abstract).
|
He,F.,Liu,R.P.,Xu,Y.N.,et al.,2018. Monitoring and Evaluation of Mine Geological Environment in Muli Coal Mine Area Based on Remote Sensing. Geological Bulletin of China,37(12):2251-2259 (in Chinese with English abstract).
|
Hong, Y.T.,Zhang, H.B.,Zhu, Y.X.,et al.,1992. Sulfur Isotope Composition of Coal in China and Sulfur Isotope Fractionation during Coal Burning. Science in China (Series B, Chemistry, Life Sciences and Geosciences),(8):868-873 (in Chinese).
|
Hu, Y.L., 2019. Impacts of the Groundwater Flow Path on the Patterns of Dissolved Organic Carbon Export in the Cold Alpine Area (Dissertation). China University of Geosciences, Wuhan (in Chinese with English abstract).
|
Li, X. Q., Liu, Y. D., Zhou, A. G., et al., 2014. Sulfur and Oxygen Isotope Compositions of Dissolved Sulfate in the Yangtze River during High Water Period and Its Sulfate Source Tracing. Earth Science, 39(11): 1647-1654, 1692 (in Chinese with English abstract).
|
Li, Y.F., 2016. The Analysis of the Stable Carbon and Nitrogen Isotopes in the Process of Soil-Grass-Livestock-Human Material Circulation on Qinghai-Tibet Plateau Alpine Pastoral Area (Dissertation). Lanzhou University, Lanzhou (in Chinese with English abstract).
|
Liu, Y.G., 2013. Using Hydrochemical and Isotope Traces Analying to Delineate Hydrologic Process in Cold Alpine Watershed in Rainy Season (Dissertation). China University of Geosciences,Wuhan (in Chinese with English abstract).
|
Luo, L. H., Ma, W., Zhuang, Y. L., et al., 2018. The Impacts of Climate Change and Human Activities on Alpine Vegetation and Permafrost in the Qinghai-Tibet Engineering Corridor. Ecological Indicators, 93: 24-35. https://doi.org/10.1016/j.ecolind.2018.04.067
|
Ma, K., 2019. Water Chemistry and Sulfur-Oxygen Isotopes Geochemistry Characteristics of Xijiang River (Dissertation). China University of Geosciences, Beijing (in Chinese with English abstract).
|
Mao, N., Liu,G.M.,Li,L.S.,et al., 2021. Methane Fluxes and Their Relationships with Methane-Related Microbes in Permafrost Regions of the Qilian Mountains. Earth Science, 47(2): 556-567 (in Chinese with English abstract).
|
Nian,Y.,Ma,Y.S.,Li,S.X.,et al.,2019. Effects of Summer Grazing on Vegetation and Soil Stoichiometry of Alpine Marsh Meadow in the Upper Reaches of Datong River. Chinese Qinghai Journal of Animal and Veterinary Sciences,49(1):14-18, 6 (in Chinese with English abstract).
|
Olefeldt, D., Persson, A., Turetsky, M. R., 2014. Influence of the Permafrost Boundary on Dissolved Organic Matter Characteristics in Rivers within the Boreal and Taiga Plains of Western Canada. Environmental Research Letters, 9(3): 035005. https://doi.org/10.1088/1748-9326/9/3/035005
|
Olefeldt, D., Roulet, N. T., 2012. Effects of Permafrost and Hydrology on the Composition and Transport of Dissolved Organic Carbon in a Subarctic Peatland Complex. Journal of Geophysical Research: Biogeosciences, 117(G1): https://doi.org/10.1029/2011jg001819
|
Pang, S.J., Su, X., He, H., et al., 2013. Geological Controlling Factors of Gas Hydrate Occurrence in Qilian Mountain Permafrost, China. Earth Science Frontiers, 20(1): 223-239 (in Chinese with English abstract).
|
Pu, J. B., Yuan, D. X., Zhang, C., et al., 2012. Identifying the Sources of Solutes in Karst Groundwater in Chongqing, China: A Combined Sulfate and Strontium Isotope Approach. Acta Geologica Sinica-English Edition, 86(4): 980-992. https://doi.org/10.1111/j.1755-6724.2012.00722.x
|
Qiu, D.S., Zhuang, D.F., Hu, Y.F., et al., 2004. Estimation of Carbon Sink Capacity Caused by Rock Weathering in China. Earth Science, 29(2): 177-182, 190 (in Chinese with English abstract).
|
Spence, J., Telmer, K., 2005. The Role of Sulfur in Chemical Weathering and Atmospheric CO2 Fluxes: Evidence from Major Ions, δ13CDIC, and δ34SSO4 in Rivers of the Canadian Cordillera. Geochimica et Cosmochimica Acta, 69(23): 5441-5458. https://doi.org/10.1016/j.gca.2005.07.011
|
Stock, B. C., Jackson, A. L., Ward, E. J., et al., 2018. Analyzing Mixing Systems Using a New Generation of Bayesian Tracer Mixing Models. PeerJ, 6: e5096. https://doi.org/10.7717/peerj.5096
|
Tuttle, M. L. W., Breit, G. N., Cozzarelli, I. M., 2009. Processes Affecting δ34S and δ18O Values of Dissolved Sulfate in Alluvium along the Canadian River, Central Oklahoma, USA. Chemical Geology, 265(3-4): 455-467. https://doi.org/10.1016/j.chemgeo.2009.05.009
|
van Stempvoort, D.R., Krouse, H.R., 1994. Controls of δ18O in Sulfate: Review of Experimental Data and Application to Specific Environments. Environmental Science, 133268872. https:// doi.org/10.1021/BK-1994-0550.CH029
|
Wang, H.F., 2017. Study on Evaluation of Hydrogeological Conditions and Water Resources of Qinghai Muli Region (Dissertation). Xi’an University of Science and Technology,Xi’an (in Chinese with English abstract).
|
Wang, P.K., Zhu, Y.H., Lu, Z.Q., et al., 2011. Gas Hydrate in the Qilian Mountain Permafrost and Its Distribution Characteristics. Geological Bulletin of China, 30(12): 1839-1850 (in Chinese with English abstract).
|
Wang, P.K., Zhu, Y.H., Lu, Z.Q., et al., 2019. Research Progress of Gas Hydrates in the Qilian Mountain Permafrost, Qinghai, Northwest China: Review. Scientia Sinica (Physica, Mechanica & Astronomica), 49(3): 76-95 (in Chinese with English abstract).
|
Wang, T., 2010. Gas Hydrate Resource Potential and Its Exploration and Development Prospect of the Muli Coalfield in the Northeast Tibetan Plateau. Energy Exploration & Exploitation, 28(3): 147-157. https://doi.org/10.1260/0144-5987.28.3.147
|
Wang, X. Q., Chen, R. S., Liu, G. H., et al., 2019. Response of Low Flows under Climate Warming in High-Altitude Permafrost Regions in Western China. Hydrological Processes, 33(1): 66-75. https://doi.org/10.1002/hyp.13311
|
Wang,Z.X.,2020. Study on the Evolution Mechanism of Regional Groundwater Circulation under the Condition of Plateau Permafrost Degradation (Dissertation). Chinese Academy of Geological Sciences, Beijing (in Chinese with English abstract).
|
Wang, Z. X., Li, X. Q., Hou, X. W., 2021. Hydrogeochemistry of River Water in the Upper Reaches of the Datong River Basin, China: Implications of Anthropogenic Inputs and Chemical Weathering. Acta Geologica Sinica-English Edition, 95(3): 962-975. https://doi.org/10.1111/1755-6724.14525
|
Ye, R.Z.,2019. Effect of Active Layer Freeze-Thaw Process in Permafrost Region on Supra-Permafrost Groundwater Dynamic of the Qinghai-Tibet Plateau Heartland (Dissertation). Lanzhou University, Lanzhou (in Chinese with English abstract).
|
Yue, H., 2011. Coal Resource Prediction Area Delimitation and Resource Potential Evaluation in Muri Coalfield, Qinghai Province. Coal Geology of China, 23(12): 11-14, 29.
|
Zhong, L., Ma, Y. M., Xue, Y. K., et al., 2019. Climate Change Trends and Impacts on Vegetation Greening over the Tibetan Plateau. Journal of Geophysical Research: Atmospheres, 124(14): 7540-7552. https://doi.org/10.1029/2019jd030481
|
Zhu, Y.H., Zhang, Y.Q., Wen, H.J., 2011. An Overview of the Scientific Drilling Project of Gas Hydrate in Qilian Mountain Permafrost, Northwestern China. Geological Bulletin of China, 30(12): 1816-1822 (in Chinese with English abstract).
|
Zou, S., Zhang, D., Li, X.Q., et al., 2021. Sources and Pollution Pathways of Deep Groundwater Sulfate Underneath the Piedmont Plain in the North Henan Province. Earth Science, 47(2): 700-716 (in Chinese with English abstract).
|
/
〈 |
|
〉 |